• Journal of the Korean Magnetics Society
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• v.23 no.6
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• pp.188-192
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• 2013

The magnetic interaction effect on the magnetic activation volume and area of electrodeposited CoPt magnetic films was investigated. The dipolar interaction was predominant interaction mechanism for all samples. And the interaction strength was increased with decreasing current density and increased with increasing sample thickness. Although the activation volumes of the samples fabricated at low current density were larger than those of the high current density samples, the sample thickness seemed to have little influence on the variation of activation volume. But it was found that the activation area was apparently affected by the magnetic interaction strength as well as the current density.

• Bulletin of the Korean Chemical Society
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• v.35 no.1
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• pp.57-61
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• 2014

In this study, carbon aerogel (CA) was synthesized using a soft-template method, and the optimum conditions for the adsorption of carbon dioxide ($CO_2$) by the carbon aerogel were evaluated by controlling the activation temperature. KOH was used as the activation agent at a KOH/CA activation ratio of 4:1. Three types of activated CAs were synthesized at activation temperatures of $800^{\circ}C$(CA-K-800), $900^{\circ}C$(CA-K-900), and $1000^{\circ}C$(CA-K-1000), and their surface and pore characteristics along with the $CO_2$ adsorption characteristics were examined. The results showed that with the increase in activation temperature from 800 to $900^{\circ}C$, the total pore volume and specific surface area sharply increased from 1.2165 to $1.2500cm^3/g$ and 1281 to $1526m^2/g$, respectively. However, the values for both these parameters decreased at temperatures above $1000^{\circ}C$. The best $CO_2$ adsorption capacity of 10.9 wt % was obtained for the CA-K-900 sample at 298 K and 1 bar. This result highlights the importance of the structural and textural characteristics of the carbon aerogel, prepared at different activation temperatures on $CO_2$ adsorption behaviors.

• Journal of Magnetics
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• v.5 no.2
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• pp.35-39
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• 2000

The correlation between the activation volumes of wall-motion and nucleation processes in Co/Pd multilayers has been investigated. Each activation volume was estimated from the field dependence of the wall-motion speed and the nucleation rate, respectively, based on time-resolved domain patterns grabbed by a MOKE microscope system. Both the activation volumes are changed in the same manner around $0.2\sim1.1\times10^{-17}cm^3$ with changes in the multilayered structure. Interestingly, the correlation between the activation volumes is sensitive to the multilayered structure; the wall-motion activation volume is smaller than the nucleation activation volume for a sample having a smaller number of repeats and a thinner Co-layer thickness, and vice versa. The correlation is closely related with the contrasting reversal modes; the process having the smaller activation volume dominates.

• Carbon letters
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• v.15 no.1
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• pp.71-76
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• 2014

Activated carbon nanofibers (ACNF) were prepared from polyacrylonitrile (PAN)-based nanofibers using $CO_2$ activation methods with varying activation process times. The surface and structural characteristics of the ACNF were observed by scanning electron microscopy and X-ray diffraction, respectively. $N_2$ adsorption isotherm characteristics at 77 K were confirmed by Brunauer-Emmett-Teller and Dubinin-Radushkevich equations. As experimental results, many holes or cavernous structures were found on the fiber surfaces after the $CO_2$ activation as confirmed by scanning electron microscopy analysis. Specific surface areas and pore volumes of the prepared ACNFs were enhanced within a range of 10 to 30 min of activation times. Performance of the porous PAN-based nanofibers as an electrode for electrical double layer capacitors was evaluated in terms of the activation conditions.

• Korean Journal of Materials Research
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• v.26 no.9
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• pp.460-467
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• 2016

Activated carbons (ACs) have been used as EDLC (electric double-layer capacitor) electrode materials due to their high specific area, stability, and ecological advantages. In order to prepare ACs with high density and crystallinity, coal tar pitch (CTP) was activated by $K_2CO_3$ and the textural and electrochemical properties of the obtained ACs were investigated. Although the CTP ACs formed by $K_2CO_3$ activation had much smaller specific surface area and pore volume than did the CTP ACs formed by KOH activation, their volumetric specific capacitance (F/cc) levels as electrode materials for EDLC were comparable due to their higher density and micro-crystallinity. Structural characterization and EDLC-electrode performance were studied with different activation conditions of $CTP/K_2CO_3$ ratio, activation temperature, and activation period.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.3
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• pp.223-229
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• 2017

When concrete is exposed to neutron rays for a long time, the concrete tends to become activated. If activated, it is classified as middle or low level radioactive waste. However, the great amount of the activated concrete is hard to dispose. In this study, low-activation cement was developed for decreasing the activated waste from shielding concrete around nuclear reactor. Furthermore, the manufactured low-activation was analyzed with activation nuclide Eu, Co. The low-activation cement showed great advantage for low-activation with detecting none of Eu and 3.75ppm of Co while ordinary portland cement showed 0.4~0.9ppm of Eu, 5.5~19.8ppm of Co content. As the results of physical properties of the low-activation cement, it is similar to type 1 ordinary portland cement and accords with type 4 low heat portland cement. Meanwhile, as for the chemical properties of the cement, it accords wite type 1 and 4 at the same time.

• Carbon letters
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• v.1 no.2
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• pp.69-75
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• 2000

Naphtha cracking bottom oil was reformed with heat treatment and then spun at $310^{\circ}C$. These pitch-based carbon fibers were carbonized at $1000^{\circ}C$ after oxidation at $280^{\circ}C$, for 90 min. These fibers were chemically activated with molar ratio of KOH/CF (1 : 1) at different temperatures ($250{\sim}900^{\circ}C$) for 1 hr. The process of activation was characterized with DTA, TGA, BET surface area and pore size distribution. The activation of fibers by KOH was performed by several process. One is the reduction process that carbon fiber was reacted with $K_2O$ produced from dehydration process above $400^{\circ}C$. The other is the process that $K_2CO_3$ was directly reacted with carbon fiber. At $800^{\circ}C$, the activation was performed by catalyzed mechanism that $K_2O$ was obtained from the reaction of metal potassium with $CO_2$, then was changed to $K_2CO_3$. At $870^{\circ}C$, the activation was also observed that activation mechanism was promoted by metal catalyst with $CO_2$ from decomposition of $K_2CO_3$. The specific surface area of prepared activated carbon fibers was dependent on the activation mechanism. The specific surface area was in the range of $1519{\sim}2000\;cm^3/g$ and was the largest prepared at $870^{\circ}C$. The pores developed were mostly micropores which was very narrow and uniform. The total pore volume was $0.58{\sim}0.77\;cm^3/g$.

• Carbon letters
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• v.9 no.4
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• pp.298-302
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• 2008

Carbon blacks could be used as the filler for the electromagnetic interference (EMI) shielding. The poly vinyl alcohol (PVA) and polyvinylidene fluoride (PVDF) were used as the matrix for the carbon black fillers. Porous carbon blacks were prepared by $CO_2$ activation. The activation was performed by treating the carbon blacks in $CO_2$ to different degrees of burnoff. During the activation, the enlargement of pore diameters, and development of microporous and mesoporous structures were introduced in the carbon blacks, resulting in an increase of extremely large specific surface areas. The porosity of carbon blacks was an increasing function of the degree of burn-off. The surface area increased from $80\;m^2/g$ to $1142\;m^2/g$ and the total pore volume increased from $0.14073\;cc{\cdot}g^{-1}$ to $0.9343\;cc{\cdot}g^{-1}$. Also, the C=O functional group characterized by aldehydes, ketones, carboxylic acids and esters was enhanced during the activation process. The EMI shielding effectiveness (SE) of raw N330 carbon blacks filled with PVA was about 1 dB and those of the activated carbon blacks increased to the values between 6 and 9 dB. The EMI SE of raw N330 carbon blacks filled with PVDF was about 7 dB and the EMI SE increased to the range from 11 to 15 dB by the activation.

• Transactions on Electrical and Electronic Materials
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• v.15 no.2
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• pp.81-86
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• 2014

The process parameter in optimized KOH alkali activation of soft carbon series coke material in high purity was set with DOE experiments design. The activated carbon was produced by performing the activation process based on the set process parameters. The specific surface area was measured and pore size was analyzed by $N_2$ absorption method for the produced activated carbon. The surface functional group was analyzed by Boehm method and metal impurities were analyzed by XRF method. The specific surface area was increased over 2,000 $m^2/g$ as the mixing ratio of activation agent increased. The micro pores in $5{\sim}15{\AA}$ and surface functional group under 0.4 meq/g were obtained. The contents of the metal impurity in activated carbon which is the factor for reducing the electrochemical characteristics was reduced less than 100 ppm through the cleansing process optimization. The electrochemical characteristics of activated carbon in 38.5 F/g and 26.6 F/cc were checked through the impedance measuring with cyclic voltammetry scan rate in 50~300 mV/s and frequency in 10 mHz ~100 kHz. The activated carbon was made in the optimized activation process conditions of activation time in 40 minutes, mixing ratio of activation agent in 4.5 : 1.0 and heat treatment temperature over $650^{\circ}C$.

• Transactions of the Korean hydrogen and new energy society
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• v.4 no.1
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• pp.11-19
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• 1993

The kinetic studies of the hydrogen induced amorphization in $ErCo_2$ Laves phase is observed by the internal standard method using X-ray diffraction intensities. The activation energy and rate constant exponent for the amorphization in $ErCo_2$ are found to be 26 kcal/mole and 0.78, respectively. From these results, it is believed that the mechanism of the hydrogen induced amorphization in $ErCo_2$ is related to the motion of Co atoms. Though there are many similar physical properties between $ErCo_2$ and $ErNi_2$, the activation energy for the amorphizatin in $ErCo_2$ is larger than that in $ErNi_2$ and the amorphization rate in $ErCo_2$ is slower. It is suggested that these differences of activation energy for the hydrogen induced amorphization and the amorphization rate between $ErCo_2$ and $ErNi_2$ is due to the occurence of structural change on forming crystalline hydride.