• 제목/요약/키워드: Co-22%Cr

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A Study on Coagulation Process using Zirconium Silicate as a Coagulation-aid (지르코늄 실리케이트를 응집보조제로 이용한 응집공정에 관한 연구)

  • Cho, Jae-Seung;Yoon, Tai-Il;Jeon, Yu-Jae;Cho, Kyung-Chul
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.3
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    • pp.203-207
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    • 2009
  • The concern of seriousness and harmful effects of environmental pollution is rising by the various water pollutions, appearances of new micro-noxious substances and increase of sustainable pollutants. The method is suggested that can effectively increase the removal of organic substances and several pollutants using a coagulation process. The experiment for characteristics of $ZrSiO_4$ (zirconium silicate) as a coagulation-aid was carried out for application to coagulation process with domestic wastewater and lake water, and the removal rate of the organic substances depending on a dosage was evaluated by PDA (Photometric Dispersion Analyzer) in this study. Zeta-potential of zirconium silicate solution was -32.22 mv at pH 7 and the lower negative(-) charge was detected in the more acidic conditions. Absorbance on $UV_{254}$ presented higher when zirconium silicate was added than in a domestic wastewater itself. Besides, the results by PDA experiment represented that injection of zirconium silicate could promote growing of floc. Tests for coagulation process were conducted by three ways which are pre-injection, co-injection and post-injection of zirconium silicate with alum. Accordingly, removal efficiency of organic substances increased over 15% in co-injection than in using of alum as a sole reagent. When a 20 mg/L of alum was used with a 10 mg/L of zirconium silicate, the removal efficiency was high up to 90%. Removal efficiency of $COD_{Cr}$ was improved more than 15% in case of dosage of coagulant either PAC (Poly aluminium chloride) or PACS (Poly aluminium chloride Silicate) together with zirconium silicate. As a result, the removal efficiency of $COD_{Cr}$ were 5~10% higher in a co-injection of zirconium silicate with a coagulant than a pre-injection and a post-injection but it of soluble substances was lower in a co-injection.

Characteristics of LSC coated Metallic Interconnect for Solid Oxide Fuel Cell (LSC가 코팅된 고체산화물 연료전지용 금속연결재의 특성 연구)

  • Pyo, Seong-Soo;Lee, Seung-Bok;Lim, Tak-Hyoung;Park, Seok-Joo;Song, Rak-Hyun;Shin, Dong-Ryul
    • Korean Chemical Engineering Research
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    • v.48 no.2
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    • pp.172-177
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    • 2010
  • This study reports the high-temperature oxidation kinetics, ASR(area specific resistance), and interfacial microstructure of metallic interconnects coated with conductive oxides in oxidation atmosphere at $800^{\circ}C$, The conductive material LSC($La_{0.8}Sr_{0.2}CoO_3$, prepared by Solid State Reaction) was coated on the Crofer22APU. The contact behavior of coating layer/metal substrate was increased by sandblast. The electrical conductivity of the LSC coated Crpfer22APU was measured by a DC two probe four wire method for 4000hr, in air at $800^{\circ}C$. Microstructure and composition of the coated layer interface were investigated by SEM/EDS. These results show that a coated LSC layer prevents the formation and growth of oxide scale such as $Cr_2O_3$ and enhances the long-term stability and electrical performance of metallic interconnects for SOFCs.

mCR1aa Medium를 이용한 소 복제수정란 배양 및 융합방법에 따른 발육율 비교

  • 김현주;양병철;임기순;오성종
    • Proceedings of the KSAR Conference
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    • 2001.03a
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    • pp.63-63
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    • 2001
  • 본 실험은 소에서 체외수정란과 복제수정란을 modified CRlaa (mCRlaa) medium에서 각각 배양하였을 때 배반포단계까지 발육율을 비교하였다. 체외성숙은 TCM-199 medium에 10 %의 Fetal Bovine Serum (FBS)를 첨가한 배양액에서 실시하였고 이를 이용해 체외수정과 복제를 시행하였다. 체외성숙란과 복제수정란의 배반포까지 발육율은 각각 22.5 %, 19.4 %이었다. 복제수정란을 생산하기 위해서는 제핵을 실시한 난자내로 공여핵를 도입하는 과정이 필요한 데 할구보다 체세포를 이용하는 경우 융합율이 저하되는 것으로 보고되고 있다. 따라서 본 연구에서는 공여핵을 제공하는 체세포와 수핵란간에 융합을 기존에 많이 사용한 chamber와 비교해 Needle을 사용했을 때 복제수정란의 발육율간의 차이를 서로 비교하였다. Ear skin cell을 이용해 핵이식을 실시한 다음 Zimmerman cell fusion medium에서 융합하였다 융합된 핵이식란은 5 % $CO_2$, 5 % $O_2$, 90 % Na, 38.5$^{\circ}C$ 조건에서 배반포까지 배양하였다. Chamber와 Needle을 사용한 경우 융합율은 각각 46.1 %, 70.4 %, 분할율은 62.6 %, 76.4 %로 Needle의 경우가 유의적으로 높았다.

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Non Linear Finite Element Analyses of Ceramic/Ceramic Pairs of Total Hip Replacements Using High Trauma-Like Loads (고응력 외상에의한 고관절용 세라믹/세라믹 쌍의 비선형 유한요소법 분석)

  • Karyo, Daniel;Lee, Su-Wan
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2005.11a
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    • pp.179-180
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    • 2005
  • Non linear finite element analyses were performed in various configurations of stem-ball head. High stresses were found for the cases when the stem tended to penetrate less into the ball head. An upgraded design of the cone may improve the loading of the ball head to resist trauma-like loading more effectively than manipulating the ball diameter. When the surgeon needs to use small ball heads (i.e. 22 mm), the use of zirconia seems to be appropriate also. After simulating a trauma like loading of the materials, it was found that the deepness of the cone to locate the stem is of major importance for the performance of the device. Further work, considering more sizes for the cone design should be performed in order to determine an optimal depth for the cone in relation to the diameter of the ball head. Also the simulation of contacts pairs including polyethylene and CoCr is important for further research.

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Pregnancy and Survival Rate of In Vitro Fertilized Bovine Embryos Frozen for Direct Transfer (직접이식을 위한 소 체외 수정란의 동결 융해후 생존성 및 수태율에 미치는 영향)

  • 오성종;양보석;이명식;백광수;성환후;정진관;임경순
    • Korean Journal of Animal Reproduction
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    • v.19 no.1
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    • pp.49-54
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    • 1995
  • This experiments were carried out to investigate the viabilities and the pregnancy rate of frozen-thawed IVF bovine embryos in various media, cryoprotectants and age of embryos produced. Hanwoo oocyte were collected in size of 2~7mm follicles, matured for 20~22hrs at 38.5$^{\circ}C$ in 5% CO2 incubator and then in vitro fertilized with Hanwoo semen. Blastocysts or more developed embryos at Day 7, 8 and 9 were frozen in 1.5 or 1.8M ethylene glycol. Viability of frozen thawed IVF embryos were identified the reformation of blastocoele after thawing and culture for 24~48 hours at 38.5$^{\circ}C$ in 5% CO2 incubator. Production rate of Hanwoo IVF embryos in TCM 199 and CR1aa ws 21.3%(39/183) and 28.1%(41/146), respectively. The viability of frozen thawed IVF embryos was higher rate in 1.8M ethylene glycol and Day 7 embryos than that in 1.5M and Day 8.53 cows out of 100 Hanwoo receipients transfered IVF embryos were pregnant and twin production rate was 26.3%.

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Sliding Wear Behavior of Plasma Sprayed Zirconia Coatingagainst Silicon Carbide Ceramic Ball

  • Le Thuong Hien;Chae Young-Hun;Kim Seock Sam;Kim Bupmin;Yoon Sang-bo
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2004.11a
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    • pp.66-74
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    • 2004
  • The sliding wear behavior of $ZrO_2-22wt\%MgO\;(MZ)\;and\;ZrO_2-8wt\%Y_2O_3\;(YZ)$ deposited on a casting aluminum alloy with bond layer (NiCrCoAlY) by plasma spray against an SiC ball was investigated under dry test conditions at room temperature. At all load conditions, the wear mechanisms of the MZ and the YZ coatings were almost the same. The wear mechanisms involved the forming of a smooth film by material transferred on the sliding surface and pullout. The wear rate of the MZ coating was less than that of the YZ coating. With an increase normal load the wear rate of the studied coatings increased. The SEM was used to examine the sliding surfaces and elucidate likely wear mechanisms. The EDX analysis of the worn surface indicated that material transfer was occurred from the SiC ball to the disk. It was suggested that the material transfer played an important role in the wear performance.

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Development of Alloy with High Strength and Damping Capacity for High-Performance of Precision Devices by Vibration Control (진동제어에 의한 정밀기기의 고성능화를 위한 고강도 및 고감쇠능 합금개발)

  • Kana, Chang-Yong;Kim, Ik-Su
    • Journal of Ocean Engineering and Technology
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    • v.22 no.6
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    • pp.46-51
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    • 2008
  • The effect of the addition of Co and N and subzero treatment on tensile strength and damping capacity was investigated in Fe-Cr-Mn alloy. Austenite was transformed into martensite by cold rollins increasing the degree of cold rollins led to an increase in the volume fraction of martensite. The damping capacity linearly increased with increasing volume fraction of ${\varepsilon}$ martensite in cold rolled specimens and subzero treated specimens after cold rolling. The volume fraction of ${\varepsilon}$ martensite, tensile strength and damping capacity was also increased by the addition of Co, while this treatment decreased the elongation. However, the volume fraction of ${\varepsilon}$ martensite, elongation and damping capacity were reduced by the addition of N, although the tensile strength increased. Tensile strength and damping capacity werealso increased by subzero treatment, while elongation decreased.

A RADIOGRAPHIC STUDY ON THE MANDIBULAR CONDYLE POSITION IN KOREAN MALOCCLUSION (부정교합자의 하악과두 위치에 관한 방사선적 연구)

  • Kang, Jeoung-Hee;Kim, Sang-Cheol
    • The korean journal of orthodontics
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    • v.22 no.1
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    • pp.109-121
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    • 1992
  • Temporomandibular joint is a major structure to play an important role in the function & stability of the occlusion as well as the stomatognathic system. Therefore, the TMJ is the structure that requires the complete analysis for diagnosing and planning treatment of pathologic changes by TMJ dysfunction and malocclusion. So, in this study, to evaluate TMJ situation in Korean malocclusion, based on the previous accomplishments, students of the dental college of Won-Kwang Univ. are surveyed and selected in terms of Angle's classification of malocclusion, whose TMJ radiographs were taken in the centric occlusion and centric relation. In each maiocclusion groups, the mean and standard deviation of anterior, posterior and superior joint space of the right, left and both side in CO & CR are evaluated and also those of the fossa height and the articular eminence angle of the right, left and both sides are evaluated. The obtained results were as follows: 1. In the correlation coefficient between the malocclusion groups, no other items except the posterior joint space of the right side in CR between in class I and class III are significant. 2. In the correlation coefficient between the right and left side, the each joint space in class I malocclusion group and class II malocclusion group are significant. 3. In the change of each joint space during the transmit from CO to CR, there is a tendency of increasing anterior joint space and decreasing posterior, superior joint spaces in class I, II malocclusion and increasing superior joint space and decreasing anterior, posterior joint space in class III malocclusion, which is significant in the correlation coefficient, but not significant in the T-test. 4. In each malocclusion group, the correlation coefficient between the posterior joint space and the superior joint space in C.R is highly significant. 5. The fossa height of class II malocclusion group is lesser than that of class I or class III, which is not significant in T-test. 6. In the correlation coefficient between Rt. and Lt. side in the fossa height, it is not significant in class I and class III group, but significant in class II malocclusion group. 7. The articular eminence angle of class II malocclusion group is larger then that of class I or class III groups, which is fairly significant. 8. In the correlation coefficient between Rt. and Lt. side in the articular eminence angle, it is significant in each malocclusion group.

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Concentration of metallic elements in surface sediments at a waste disposal site in the Yellow Sea (황해 폐기물 투기해역(서해병) 표층 퇴적물의 금속원소 분포)

  • Koh, Hyuk-Joon;Choi, Young-Chan;Park, Sung-Eun;Cha, Hyung-Kee;Chang, Dae-Soo;Lee, Chung-Il;Yoon, Han-Sam
    • Journal of Environmental Science International
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    • v.22 no.7
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    • pp.787-799
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    • 2013
  • The aim of this study was to investigate the accumulation of metallic elements and the control effect of marine pollution caused by ocean dumping in the sediments at a waste disposal area in the Yellow Sea. In July 2009, concentrations of organic matter and metallic elements (Al, Fe, As, Cd, Cr, Co, Hg, Ni, Mn, Pb, and Zn) were measured in surface sediments at the site. The ignition loss (IL) in the surface sediments showed a mean value of 15.4%, about 1.5 times higher than the mean value of the sediments in the coastal areas of Korea. The chemical oxygen demand (COD) at some disposal sites exceeded 20 mg $O_2/g{\cdot}dry$, which signifies the initial concentration of marine sediment pollutants in Japan. The disposal sites contain higher concentrations of Cr, Cu and Zn than the sediments of bays and estuaries that might be contaminated. The magnitude of both metal enrichment factors (EF) and adverse biological effects suggest that pollution with Cr and Ni occurred due to the dumping of waste in the study area. In addition, the geoaccumulation index (Igeo) showed that the surface sediments were moderately contaminated. By the mid-2000s, when the amount of waste dumped at this site was the highest, the concentration of metallic elements was higher than ever recorded. On the other hand, in 2008-09, the need for environmental management was relatively low compare with the peak. As a result, the quality of marine sediment has been enhanced, considering the effect of waste reduction and natural dilution in the disposal area.

Fabrication and Mechanical Properties of STS316L Porous Metal for Vacuum Injection Mold (진공사출금형용 STS316L 금속 다공체 제조 및 기계적 특성)

  • Kim, Se Hoon;Kim, Sang Min;Noh, Sang Ho;Kim, Jin Pyeong;Shin, Jae Hyuck;Sung, Si-Young;Jin, Jin Kwang;Kim, Taean
    • Journal of Powder Materials
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    • v.22 no.3
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    • pp.197-202
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    • 2015
  • In this study, porous stainless steel (STS316L) sintered body was fabricated by powder metallurgy method and its properties such as porosity, compressive yield strength, hardness, and permeability were evaluated. 67.5Fe-17Cr- 13Ni-2.5Mo (wt%) powder was produced by a water atomization. The atomized powder was classified into size with under $45{\mu}m$ and over $180{\mu}m$, and then they were compacted with various pressures and sintered at $1210^{\circ}C$ for 1 h in a vacuum atmosphere. The porosities of sintered bodies could be obtained in range of 20~53% by controlling the compaction pressure. Compressive yield strength and hardness were achieved up to 268 MPa and 94 Shore D, respectively. Air permeability was obtained up to $79l/min{\cdot}cm^2$. As a result, mechanical properties and air permeability of the optimized porous body having a porosity of 25~40% were very superior to that of Al alloy.