• Title/Summary/Keyword: Co oxide

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Effect of Er2O3 Content on Nonlinear Properties and Impulse Clamping Characteristics of Pr/Co/Cr/Al Co-doped Zinc Oxide Ceramics

  • Nahm, Choon-Woo
    • Journal of the Korean Ceramic Society
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    • v.51 no.6
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    • pp.612-617
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    • 2014
  • The microstructure, nonlinear properties, and impulse clamping characteristics of Pr/Co/Cr/Al co-doped zinc oxide ceramics were investigated with various contents of $Er_2O_3$. Increasing $Er_2O_3$ content increased the density of the sintered pellets from 5.69 to $5.83g/cm^3$, and decreased the average grain size from 10.6 to $6.5{\mu}m$. With increased $Er_2O_3$ content, the breakdown field increased from 2318 to 4205 V/cm, and the nonlinear coefficient increased from 19.4 to 40.2. The clamp characteristics were improved with the increase of the content of $Er_2O_3$. The varistors doped with 2.0 mol% exhibited the best clamp characteristics, in which the clamp voltage ratio was 1.40-1.73 at 1-50 A in an impulse current.

Electrochemical characteristics of Co/PVA composite electrode for supercapacitor (수퍼커패시터용 Co/PVA복합전극의 전기화학적특성)

  • ;;Takeo OHSAKA
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.577-580
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    • 2001
  • Very fine cobalt oxide ambigel powder were prepared using a unique solution chemistry associated with the sol-gel process. The mesoporous structure of the initial gel is maintained by removing fluid under conditions where the capillary forces that result extraction are either low or no existent, are either low or nonexistent. Controling both the pore and solid architecture on the nanoscale offers a strategy for the design of supercapacitor. But $CoO_{x}$ have the low voltage, so we experiment using CO/PVA composite electrode.

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Analysis of Sticking Coefficient in BSCCO Superconductor Thin Film Fabricated by Co-deposition (공증착법으로 제작한 BSCCO 초전도 박막의 부착계수 해석)

  • 안인순;천민우;박용필
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.300-303
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    • 2001
  • BSCCO thin films are fabricated via a co-deposition process by an ion beam sputtering with an ultra-low growth rate, and sticking coefficients of the respective elements are evaluated. The sticking coefficient of Bi element exhibits a characteristic temperature dependence : almost a constant value of 0.49 below 730$^{\circ}C$ and decreases linearly with temperature over 730$^{\circ}C$. This temperature dependence can be elucidated from the evaporation and sublimation rates of bismuth oxide, Bi$_2$O$_3$, from the film surface. It is considered that the liquid phase of the bismuth oxide plays an important role in the Bi 2212 phase formation in the co-deposition process.

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Nitric Oxide Production and Elastase Inhibitory Activities of Extract and Its Fraction from Phellodendri Cortex (황백추출물 및 분획물의 Nitric Oxide 생성 억제 효과 및 Elastase 억제 효과)

  • Um, Ji Na;Min, Jin Woo;Joo, Kwang Sik;Kang, Hee Cheol
    • Korean Journal of Medicinal Crop Science
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    • v.25 no.1
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    • pp.22-28
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    • 2017
  • Background: To date, the anti-wrinkle efficacy of phellodendri cortex has not been defined. In this study, we investigated the nitric oxide (NO) production and elastase inhibitory activities of 80% methanol extract of Phellodendri cortex and its ethyl acetate fraction. Methods and Results: We prepared 80% methanol extract, and its fractions from phellodendri cortex. The treatment of RAW 264.7 cell with $25{\mu}g/m{\ell}$ 80% methanol extract and ethyl acetate fraction resulted in no toxicity. We conducted assays of nitric oxide (NO) production and elastase inhibition. In the NO production assay, the ethyl acetate fraction showed an inhibitory effect approximately 17 times stronger than the 80% methanol extract. In elastase inhibitory assay, the ethyl acetate fraction also showed a stronger effect than the 80% methanol extract. In order to standardize the extract and fraction, we used TLC to separate the extract and observed the plate under UV light. We confirmed that the known pharmacological ingredients berberine, and palmatine in the 80% methanol extract and the ethyl acetate fraction. Conclusions: These results indicated that phellodendri cortex extract and its ethyl acetate fraction produced strong inhibitory effect on elastase and NO production.

The CO2 Absorption of Synthetic Amine using the Ethylene Oxide-Ammonia Reaction (에폭사이드와 암모니아의 반응을 이용한 합성아민의 이산화탄소 흡수연구)

  • CHOI, JEONGHO;YOON, YEOIL;PARK, SUNGYOUL;BAEK, ILHYUN;NAM, SUNGCHAN
    • Journal of Hydrogen and New Energy
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    • v.28 no.5
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    • pp.561-569
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    • 2017
  • In this study, a synthetic amine made using the ethylene oxide-ammonia reaction was used as an absorbent to remove carbon dioxide. Existing absorbents were used in a mix in order to improve performance; however, because the ethylene oxide-ammonia reaction generates primary, secondary, and tertiary amines simultaneously, it has the merit that separate mixing of the absorbents was not needed. The performance of carbon dioxide absorption with the synthetic amine was compared to that of MEA. As a result of an experiment, it was determined that the $CO_2$ loading was 1.15 times better than that of MEA (a commonly used amine), while the cyclic capacity was 2.28 times higher. Because the heat of reaction was 1.10 times lower than for MEA, the synthetic amine showed superior performance in terms of absorption and regeneration.

Effects of Ta addition in Co-sputtering Process for Ta-doped Indium Tin Oxide Thin Film Transistors

  • Park, Si-Nae;Son, Dae-Ho;Kim, Dae-Hwan;Gang, Jin-Gyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.334-334
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    • 2012
  • Transparent oxide semiconductors have recently attracted much attention as channel layer materials due to advantageous electrical and optical characteristics such as high mobility, high stability, and good transparency. In addition, transparent oxide semiconductor can be fabricated at low temperature with a low production cost and it permits highly uniform devices such as large area displays. A variety of thin film transistors (TFTs) have been studied including ZnO, InZnO, and InGaZnO as the channel layer. Recently, there are many studies for substitution of Ga in InGaZnO TFTs due to their problem, such as stability of devices. In this work, new quaternary compound materials, tantalum-indium-tin oxide (TaInSnO) thin films were fabricated by using co-sputtering and used for the active channel layer in thin film transistors (TFTs). We deposited TaInSnO films in a mixed gas (O2+Ar) atmosphere by co-sputtering from Ta and ITO targets, respectively. The electric characteristics of TaInSnO TFTs and thin films were investigated according to the RF power applied to the $Ta_2O_5$ target. The addition of Ta elements could suppress the formation of oxygen vacancies because of the stronger oxidation tendency of Ta relative to that of In or Sn. Therefore the free carrier density decreased with increasing RF power of $Ta_2O_5$ in TaInSnO thin film. The optimized characteristics of TaInSnO TFT showed an on/off current ratio of $1.4{\times}108$, a threshold voltage of 2.91 V, a field-effect mobility of 2.37 cm2/Vs, and a subthreshold swing of 0.48 V/dec.

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Synthesis of nano Cerium(IV) oxide from recycled Ce precusor (재생 세륨 전구체로부터 나노산화세륨(IV)합성)

  • Kang, Tae-Hee;Koo, Sang-Man;Jung, Choong-Ho;Hwang, Kwang-Taek;Kang, Woo-Kyu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.2
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    • pp.101-107
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    • 2013
  • Cerium compounds such as Cerium hydroxide ($Ce(OH)_3$), Cerium chloride ($CeCl_3{\cdot}nH_2O$), Cerium carbonate hydrate ($Ce_2(CO_3)_3{\cdot}8H_2O$), Cerium oxide ($CeO_2$) were synthesized using recycled Ce precursor. Cerium(IV) oxide of nanoparticles were obtained by Ultra-sonication. Cerium-sodium- sulfate compound was synthesized through acid-leaching and addition of sodium sulfate from 99 wt% purity of Ce precursor as a starting material that was recycled from the waste polishing slurry. Moreover Cerium hydroxide was obtained from Cerium-sodium-sulfate compound by adding to sodium hydroxide solution. Then Cerium chloride was synthesized by adding of hydrochloric acid to Cerium hydroxide. Needle-shaped Cerium carbonate hydrate was synthesized in the continuous process and Cerium(IV) oxide with 30~40 nm size was subsequently obtained by the calcinations and dispersion.

A Study on the Removal Characteristics of a Radioactively Contaminated Oxide Film from the irradiated Stainless Steel Surface using Short Pulsed Laser Ablation (초단 펄스레이저 어블레이션에 의한 스테인리스강 표면의 오염산화막 제거 특성)

  • Kim, Geun-Woo;Yoon, Sung-Sik;Kim, Ki-Chul;Lee, Myung-Won;Kang, Myungchang
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.19 no.10
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    • pp.105-110
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    • 2020
  • Radioactive Oxides are formed on the surface of the primary equipment in a nuclear power plant. In order to remove the oxide film that is formed on the surfaces of the equipment, chemical and physical decontamination technologies are used. The disadvantage of traditional technologies is that they produce secondary radioactive wastes. Therefore, in this study, the short-pulsed laser eco-friendly technology was used in order to reduce production of the secondary radioactive wastes. They were also used to minimize the damages that were caused on the base material and to remove the contaminated oxide film. The study was carried out using a Stainless steel 304 specimen that was coated with nickel-ferrite particles. Further, the laser source was selected with two different wavelengths. Furthermore, the depth of the coating layer was analyzed using a 3D laser microscope by changing the laser ablation conditions. Based on the analysis, the optimal conditions of ablation were determined using a 1064nm short-pulsed laser ablation technique in order to remove the radioactively contaminated oxide film from the irradiated stainless steel surface.

The effect of UV-C irradiation and EDTA on the uptake of Co2+ by antimony oxide in the presence and absence of competing cations Ca2+ and Ni2+

  • Malinen, Leena;Repo, Eveliina;Harjula, Risto;Huittinen, Nina
    • Nuclear Engineering and Technology
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    • v.54 no.2
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    • pp.627-636
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    • 2022
  • In nuclear power plants and other nuclear facilities the removal of cobalt from radioactive liquid waste is needed to reduce the radioactivity concentration in effluents. In liquid wastes containing strong organic complexing agents such as EDTA cobalt removal can be problematic due to the high stability of the Co-EDTA complex. In this study, the removal of cobalt from NaNO3 solutions using antimony oxide (Sb2O3) synthesized from potassium hexahydroxoantimonate was investigated in the absence and presence of EDTA. The uptake studies on the ion exchange material were conducted both in the dark (absence of UV-light) and under UV-C irradiation. Ca2+ or Ni2+ were included in the experiments as competing cations to test the selectivity of the ion exchanger. Results show that UV-C irradiation noticeably enhances the cobalt sorption efficiency on the antimony oxide. It was shown that nickel decreased the sorption of cobalt to a higher extent than calcium. Finally, the sorption data collected for Co2+ on antimony oxide was modeled using six different isotherm models. The Sips model was found to be the most suitable model to describe the sorption process. The Dubinin-Radushkevich model was further used to calculate the adsorption energy, which was found to be 6.2 kJ mol-1.