• 제목/요약/키워드: Co depletion layer

검색결과 27건 처리시간 0.02초

IGZO 박막의 CO2 가스 반응에 대한 안정성 (Stability of Gas Response Characteristics of IGZO)

  • 오 데레
    • 반도체디스플레이기술학회지
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    • 제17권3호
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    • pp.17-20
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    • 2018
  • IGZO thin films were prepared on n-type Si substrates to research the interface characteristics between IGZO and substrate. After the annealing processes, the depletion layer was formed at the interface to make a Schottky contact owing to the electron-hall fair recombination. The carrier density was decreased by the effect of depletion layer and the hall mobility decreased during the deposition processes. But the annealing effect of depletion layer increased the hall mobility because of the increment of potential barrier and the extension of depletion layer. It was confirmed that it is useful to observe the depletion effect and Schottky contact's properties by complementary using the Hall measurement and I-V measurement.

열간 압축법으로 제조된 Cr2AlC 화합물의 900-1200℃, 50시간 동안의 대기중 산화 (Oxidation of Hot Pressed Cr2AlC Compounds at 900-1200℃ for Up to 50 Hours in Air)

  • 이동복
    • 한국표면공학회지
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    • 제44권4호
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    • pp.125-130
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    • 2011
  • $Cr_2AlC$ compounds were synthesized by hot pressing, and oxidized between 900 and $1200^{\circ}C$ in air for up to 50 hours. They oxidized to a thin $Al_2O_3$ layer containing a small amount of $Cr_2O_3$with the liberation of carbon as CO or $CO_2$ gases. The consumption of Al to form the $Al_2O_3$ layer led to the depletion of Al and enrichment of Cr just below the $Al_2O_3$ layer, resulting in the formation of an underlying $Cr_7C_3$ layer. As the oxidation temperature and time increased, the $Cr_7C_3$ oxide layer and the underlying $Cr_7C_3$ layer thickened. The oxidation resistance of $Cr_2AlC$ was generally good due to the formation of the $Al_2O_3$ barrier layer.

기후변화관련(氣候變化關聯) 국제환경협약체제하(國際環境協約體制下)의 무역규제조항(貿易規制條項) (The Trade Regulation in the Multilateral Environmental Agreements on Climate Change)

  • 정예모
    • 무역상무연구
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    • 제14권
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    • pp.349-370
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    • 2000
  • The environmental problems such as global climate change, global waming, ozone depletion, environmental pollution have been caused by the rapid economic growth, increasing in use of fossil fuels for industrialization and scientific technology development. Especially human activities are significantly altering the atomosphere's composition and its radiative properties. To Stabilize greenhouse gas concentrations in the atmosphere at a level that would prevent dangerous anthropogenic interference with the climate system, the international community adopted the UN Framework Convention on Climate Change in 1992 and Kyoto protocol in 1997. Also to protect ozone layer the international community adopted the Vienna Convention for the Protection of the Ozone Layer in 1985, and the Montreal Protocol on Substances that Deplete the Ozone Layer in 1987. To achieve global environmental objectives, some multilateral environmental agreements includes trade regulation. For example, Montreal Protocol includes the provisions to regulate the world trade of the sudstances which might destroy ozone layer. However Kyoto Protocol has no provisions to regulate trade and is not in force yet. Although there is no trade regulation article in Kyoto Protocol, the international world trade will be influenced by limitation and reduction of CO2 and strengthening the CO2 emission standard for import good. For example Korean car industy agreed with EU to reduce CO2 emission from new passenger car and Korean Semiconductor industry agreed with WSC(World Semiconductor Council) to reduce PFCs in 1999.

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$In_2O_3$ 박막위에 증착된 초박막 촉매가 CO의 검출 감도에 미치는 영향 (Effect of Ultra-thin Catalyst Deposited upon $In_2O_3$ Thin Film on CO Sensitivity)

  • 이혜정;송재훈;권순남;김태송;김광주;정형진;최원국
    • 센서학회지
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    • 제9권6호
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    • pp.430-439
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    • 2000
  • CO 가스 감지를 위한 두께 500-600 nm $In_2O_3$를 기저 물질로한 박막센서를 rf magnetron 방법을 이용하여 제작하였다. CO가스에 대한 감도 향상 및 -CH가 포함된 탄화수소 가스들과의 선택성을 높이기 위해 전이 금속인 Cobalt 촉매를 rf sputtering을 이용하여 초박막 형태로 0.7-2.8 nm 까지 두께를 조절하여 증착하고 $500^{\circ}C$ 열처리 후 가스 감도 특성을 조사하였다. CO에 대한 감도는 Co 두께 2.1 nm, 작동온도 $350^{\circ}C$에서 가장 우수하였고, $350^{\circ}C{\sim}400^{\circ}C$, Co (1.4 nm) 에서 $C_3H_8$에 대한 감도가 우수함을 알 수 있었다. 광전자 분석법 (x-ray photoelectron spectroscopy;XPS)을 통하여 초박막 Co가 표면이 $Co_2O_3$가 덮어진 CoO 형태로 존재함을 알 수 있었고, $(n-type)In_2O_3$-(p-type)CoO의 p-n junction 이 형성되었음을 확인하였다. 이러한 p-n junction type 가스센서에는 접합 경계면에서 형성된 전하 공핍층 (depletion layer)의 두께 변화에 따른 저항 변화에 의해 환원성 가스에 대한 감응 기구 (sensing mechanism)를 설명할 수 있었다.

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Development of the Assessment Framework for the Environmental Impacts in Construction

  • Tahoon Hong;Changwoon Ji;Kwangbok Jeong;Joowan Park
    • 국제학술발표논문집
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    • The 5th International Conference on Construction Engineering and Project Management
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    • pp.196-203
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    • 2013
  • Environmental problems like global warming have now become important issues that should be considered in all industries, including construction. In South Korea, many studies have been conducted to achieve the government's goals of reduction in environmental impacts. However, the research on buildings has only focused on CO2 emission as a research target despite the fact that other environmental impacts resulting from ozone depletion and acidification should also be considered, in addition to global warming. In this regard, this study attempted to propose assessment criteria and methods to evaluate the environmental performance of the structures from various aspects. The environmental impact category can be divided into global impacts, regional impacts, and local impacts. First, global impacts include global warming, ozone layer depletion, and abiotic resource depletion, while regional impacts include acidification, eutrophication, and photochemical oxidation. In addition, noise and vibration occurring in the building construction phase are defined as local impacts. The evaluation methods on the eight environmental impacts will be proposed after analyzing existing studies, and the methods representing each environmental load as monetary value will be presented. The methods presented in this study will present benefits that can be obtained through green buildings with a clear quantitative assessment on structures. Ultimately, it is expected that if the effects of green buildings are clearly presented through the findings of this study, the greening of structures will be actively expanded.

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폐타이어 고무 재활용 공정의 전과정평가 연구 (Life Cycle Assessment(LCA) of Rubber Recycling Process in Waste Tire)

  • 안중우;김진국
    • 자원리싸이클링
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    • 제27권1호
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    • pp.74-83
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    • 2018
  • 본 연구에서는 폐타이어를 재활용하여 고무를 회수하는 폐 고무 재활용 기술에 대한 전과정평가를 실시하였다. 환경 영향은 지구온난화, 자원고갈, 산성화, 부영양화, 광화학적산화물생성, 오존층파괴의 6가지 범주로 나누어 평가하였다. 폐타이어 1ton을 재활용할 때, 지구온난화는 1.77E+02 kg $CO_2-eq.$, 자원고갈은 1.23E+00 kg Sb-eq., 산성화는 5.92E-01 kg $SO_2-eq.$, 부영양화는 1.23E-01 kg $PO{_4}^{3-}eq.$, 광화학적산화물생성은 3.42E-01 kg $C_2H_4-eq.$, 오존층파괴영향은 1.87E-04 kg CFC11-eq.로 환경영향이 나타났다. 전체 환경영향범주에 있어 고무 컴파운딩 공정에서 사용되는 카본, 연화제, 전기가 가장 큰 영향을 미치기 때문에 카본과 연화제의 대체나 사용량 감축 방안이 요구된다. 또한, 에너지 효율을 개선 및 환경영향이 낮은 에너지원으로 변경, 신재생에너지를 적용하는 방안 등을 고려해 보아야 한다.

전자빔 코팅 및 플라즈마 용사에 의한 안정화지르코니아/CoNiCrAlY 계면의 산화거동 (Oxidation Behavior at the Interface between E-beam Coated $ZrO_{2}$-7wt.%$Y_{2}O}_{3}$and Plasma Sprayed CoNiCrAlY)

  • 최원섭;김영도;전형탁;김현태;윤국한;홍경태;박종구;박원식
    • 한국재료학회지
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    • 제8권6호
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    • pp.538-544
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    • 1998
  • 열차폐코팅층의 박리는 세라믹/금속접합층 계면에서 취성이 큰 스피텔의 생성, 금속과 세라믹의 열팽창계수의 차이, 세라믹층의 상변태, 코팅층의 잔류응력에 기인한다. 본 연구에서는 인코넬 713C에 전자빔 코팅 및 플라즈마 용사법으로 코팅된 안정화지르코니아/CoNiCrAIY 계면의 산화거동을 조사하기 위하여 $900^{\circ}C$에서 등온산화시험동안 생성되는 산화막층과 스피넬 생성 거동을 관찰, 분석하였다. 코팅 직후 코팅층에 고르게 분포하고 있는 Co,Ni,Cr,AI,Zr의 원소들이 산화시간에 따라 확산하여 산화반응을 하였다. 초기 20시간의 산화기시간에 안정화지르코니아/CoNiCrAIY 계면에 주요 성분이 $\alpha$-$AI_2O_3$인 산화막층이 생성되었고, CoNiCrAIY층에는 AI의 외부확산으로 인한 AI 결핍지역이 생성되었다. 산화시험동안 $\alpha$-AI2O층이 임계두께까지 성장한 후에 산화막층의 성장속도는 감소하였고, 안정화지르코니아/산화막층 계면에 스피넬, $Cr_2O_3$, $CO_2CrO_4$의 형성으로 인한 크랙이 관찰되었다.

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슈퍼웰포인트공법에 의한 고진공배수 압밀탈수에 대한 시공사례 (Research for a cases of overseas constructions and domestic tentative execution about high vacuum dewatering and consolidation/dehydration by Super Well point method)

  • 신창범;김대활;시게요시 다카하시;이광열
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2008년도 추계 학술발표회
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    • pp.581-590
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    • 2008
  • A SWP method is a revolutionary dewatering method. The conventional dewatering method, deep-well method, had ever occurred a civil appeal caused by the well depletion in compliance with the reduction of the groundwater level over a wider area considerably by the deep-well pumping from homogeneous sand-layer ground for a dry-work, while pump groung excavation working in Sendai city, Japan 10 years ago. it'd developed with the problematic proposal to find the new method which can lower the groundwater level only within the sheet pile without any reduction of groundwater outside of the sheet pile and until currently steady improvement came. It's been confirmed with plenty of executional results that there was almost no decreasing of water-level from surroundings, over so many construction-sites including vertical shafts which completely does not enter into non-water permeable layer and pumping ground etc. The SWP method in this time has been introducing initially and carried into a the execution tentatively at a construction-site and made a various result get through the execution.

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Development of the Assessment Framework for the Environmental Impacts in Construction

  • Hong, Tahoon;Ji, Changwoon;Jeong, Kwangbok;Park, Joowan
    • Journal of Construction Engineering and Project Management
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    • 제3권3호
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    • pp.1-9
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    • 2013
  • Environmental problems like global warming have now become important issues that should be considered in all industries, including construction. In South Korea, many studies have been conducted to achieve the government's goals of reduction in environmental impacts. However, the research on buildings has only focused on CO2 emission as a research target despite the fact that other environmental impacts resulting from ozone depletion and acidification should also be considered, in addition to global warming. In this regard, this study attempted to propose assessment criteria and methods to evaluate the environmental performance of the structures from various aspects. The environmental impact category can be divided into global impacts, regional impacts, and local impacts. First, global impacts include global warming, ozone layer depletion, and abiotic resource depletion, while regional impacts include acidification, eutrophication, and photochemical oxidation. In addition, noise and vibration occurring in the building construction phase are defined as local impacts. The evaluation methods on the eight environmental impacts will be proposed after analyzing existing studies, and the methods representing each environmental load as monetary value will be presented. The methods presented in this study will present benefits that can be obtained through green buildings with a clear quantitative assessment on structures. Ultimately, it is expected that if the effects of green buildings are clearly presented through the findings of this study, the greening of structures will be actively expanded.

An Estimation of the New Production in the Southern East Sea Using Helium Isotopes

  • Kim, Kyung-Ryul;Hahm, Do-Shik
    • Journal of the korean society of oceanography
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    • 제36권1호
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    • pp.19-26
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    • 2001
  • The biological pump is one of the important pumping mechanisms absorbing CO$_2$ from the atmosphere into the ocean and can be quantified by estimating new production. New production in the open ocean mostly depends on the supply of nitrate from the water below the mixed layer. While nitrate is affected by many biological processes, the helium isotope ($^3$He) is inert and has very simple physical properties. Using the $^3$He flux and the relation between $^3$He and NO${_3}\;{^-}$- within the thermocline, the nitrate flux supporting new production was estimated in the southern East Sea. The average ${\delta}^3$He within the mixed layer was -14$%_o$ and -l5.4$%_o$ in the winter and autumn, respectively. Through the year excess $^3$He occurs in the mixed layer except for a slight depletion of -17$%_o$ in summer. The $^3$He flux of 13$%_o$md$^{-1}$ associated with the concentration gradient at the air-sea interface was calculated from the product of the piston velocity and the excess $^3$He. Tritium decay within the mixed layer could support only 2$%_o$md$^{-1}$ of the flux. Thus, the remaining 11$%_o$md^{-1}$ could be attributed to the flux of tritiugenic $^3$He from the water below the mixed layer. Nitrate and $^3$He were positively correlated within the thermocline layer with the slope of 0.21 ${\mu}$mol kg$^{-1}$ $%_o\;^{-1}$. The annual nitrate flux estimated from the upward flux of $^3$He and the NO$_{3}\;{^-}$-$^3$He relation was 0.8${\pm}$0.2 mol(N) m$^{-2}$yr$^{-1}$. This flux corresponds to an annual new production of 64 g(C) m$^{-2}$yr$^{-1}$, which is consistent with that in the north-west Pacific.

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