• Title/Summary/Keyword: Co depletion layer

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Stability of Gas Response Characteristics of IGZO (IGZO 박막의 CO2 가스 반응에 대한 안정성)

  • Oh, Teresa
    • Journal of the Semiconductor & Display Technology
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    • v.17 no.3
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    • pp.17-20
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    • 2018
  • IGZO thin films were prepared on n-type Si substrates to research the interface characteristics between IGZO and substrate. After the annealing processes, the depletion layer was formed at the interface to make a Schottky contact owing to the electron-hall fair recombination. The carrier density was decreased by the effect of depletion layer and the hall mobility decreased during the deposition processes. But the annealing effect of depletion layer increased the hall mobility because of the increment of potential barrier and the extension of depletion layer. It was confirmed that it is useful to observe the depletion effect and Schottky contact's properties by complementary using the Hall measurement and I-V measurement.

Oxidation of Hot Pressed Cr2AlC Compounds at 900-1200℃ for Up to 50 Hours in Air (열간 압축법으로 제조된 Cr2AlC 화합물의 900-1200℃, 50시간 동안의 대기중 산화)

  • Lee, Dong-Bok
    • Journal of the Korean institute of surface engineering
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    • v.44 no.4
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    • pp.125-130
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    • 2011
  • $Cr_2AlC$ compounds were synthesized by hot pressing, and oxidized between 900 and $1200^{\circ}C$ in air for up to 50 hours. They oxidized to a thin $Al_2O_3$ layer containing a small amount of $Cr_2O_3$with the liberation of carbon as CO or $CO_2$ gases. The consumption of Al to form the $Al_2O_3$ layer led to the depletion of Al and enrichment of Cr just below the $Al_2O_3$ layer, resulting in the formation of an underlying $Cr_7C_3$ layer. As the oxidation temperature and time increased, the $Cr_7C_3$ oxide layer and the underlying $Cr_7C_3$ layer thickened. The oxidation resistance of $Cr_2AlC$ was generally good due to the formation of the $Al_2O_3$ barrier layer.

The Trade Regulation in the Multilateral Environmental Agreements on Climate Change (기후변화관련(氣候變化關聯) 국제환경협약체제하(國際環境協約體制下)의 무역규제조항(貿易規制條項))

  • Chung, Ye-Mo
    • THE INTERNATIONAL COMMERCE & LAW REVIEW
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    • v.14
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    • pp.349-370
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    • 2000
  • The environmental problems such as global climate change, global waming, ozone depletion, environmental pollution have been caused by the rapid economic growth, increasing in use of fossil fuels for industrialization and scientific technology development. Especially human activities are significantly altering the atomosphere's composition and its radiative properties. To Stabilize greenhouse gas concentrations in the atmosphere at a level that would prevent dangerous anthropogenic interference with the climate system, the international community adopted the UN Framework Convention on Climate Change in 1992 and Kyoto protocol in 1997. Also to protect ozone layer the international community adopted the Vienna Convention for the Protection of the Ozone Layer in 1985, and the Montreal Protocol on Substances that Deplete the Ozone Layer in 1987. To achieve global environmental objectives, some multilateral environmental agreements includes trade regulation. For example, Montreal Protocol includes the provisions to regulate the world trade of the sudstances which might destroy ozone layer. However Kyoto Protocol has no provisions to regulate trade and is not in force yet. Although there is no trade regulation article in Kyoto Protocol, the international world trade will be influenced by limitation and reduction of CO2 and strengthening the CO2 emission standard for import good. For example Korean car industy agreed with EU to reduce CO2 emission from new passenger car and Korean Semiconductor industry agreed with WSC(World Semiconductor Council) to reduce PFCs in 1999.

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Effect of Ultra-thin Catalyst Deposited upon $In_2O_3$ Thin Film on CO Sensitivity ($In_2O_3$ 박막위에 증착된 초박막 촉매가 CO의 검출 감도에 미치는 영향)

  • Lee, Hye-Jung;Song, Jae-Hoon;Kwon, Soon-Nam;Kim, Tae-Song;Kim, Kwang-Ju;Jung, Hyung-Jin;Choi, Won-Kook
    • Journal of Sensor Science and Technology
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    • v.9 no.6
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    • pp.430-439
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    • 2000
  • $In_2O_3$-based thin film sensor with 500-600 nm thick was fabricated for the detection of CO gas by rf magnetron sputtering. In order to improve both sensitivity to CO gas and selectivity to hydrogen gas containing -CH, ultra-thin transition metal Co catalyst was sputtered over $In_2O_3$ thin film and annealed at $500^{\circ}C$. Sensitivity to CO was maximum at the thickness of Co 2.1 nm and $300^{\circ}C$, and that to $C_3H_8$ was at the thickness of Co 1.4 nm and $350-400^{\circ}C$. From the x-ray photoelectron spectroscopy (XPS) result, ultra-thin Co was existed into CoO covered with $Co_2O_3$ on $In_2O_3$ particles, and thus p-n junction of $In_2O_3(n-type)$-CoO(p-type) was thought to be formed. In this p-n junction type sensors, sensing mechanism with reducing gases can be explained by the variation of depletion layer thickness formed in the interface.

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Development of the Assessment Framework for the Environmental Impacts in Construction

  • Tahoon Hong;Changwoon Ji;Kwangbok Jeong;Joowan Park
    • International conference on construction engineering and project management
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    • 2013.01a
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    • pp.196-203
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    • 2013
  • Environmental problems like global warming have now become important issues that should be considered in all industries, including construction. In South Korea, many studies have been conducted to achieve the government's goals of reduction in environmental impacts. However, the research on buildings has only focused on CO2 emission as a research target despite the fact that other environmental impacts resulting from ozone depletion and acidification should also be considered, in addition to global warming. In this regard, this study attempted to propose assessment criteria and methods to evaluate the environmental performance of the structures from various aspects. The environmental impact category can be divided into global impacts, regional impacts, and local impacts. First, global impacts include global warming, ozone layer depletion, and abiotic resource depletion, while regional impacts include acidification, eutrophication, and photochemical oxidation. In addition, noise and vibration occurring in the building construction phase are defined as local impacts. The evaluation methods on the eight environmental impacts will be proposed after analyzing existing studies, and the methods representing each environmental load as monetary value will be presented. The methods presented in this study will present benefits that can be obtained through green buildings with a clear quantitative assessment on structures. Ultimately, it is expected that if the effects of green buildings are clearly presented through the findings of this study, the greening of structures will be actively expanded.

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Life Cycle Assessment(LCA) of Rubber Recycling Process in Waste Tire (폐타이어 고무 재활용 공정의 전과정평가 연구)

  • Ahn, Joong Woo;Kim, Jin Kuk
    • Resources Recycling
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    • v.27 no.1
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    • pp.74-83
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    • 2018
  • This study conducted the Life Cycle Assessment(LCA) on waste rubber recycling technology for recovering rubber product from the waste tires. Environmental impacts were assessed for the five categories of impacts: global warming, resource depletion, acidification, eutrophication, photochemical oxide production, and ozone layer depletion. When recycling 1ton of waste tire containing rubber, global warming impact was 1.77E+02 kg $CO_2-eq.$, resource depletion impact was 1.23E+00 kg Sb-eq., acidification impact was 5.92E-01 kg $SO_2-eq.$, eutrophication impact was 1.23E-01 kg $PO{_4}^{3-}-eq.$, photochemical oxide production impact was 3.42E-01 kg $C_2H_4-eq.$, and ozone layer depletion impact was 1.87E-04 kg CFC11-eq. In terms of overall environmental impacts, carbon, softener and electricity the greatest impact, so it is necessary to compare the environmental impacts of the raw materials to replace carbon and softener, and a method to reduce the filler usage in the process is needed. In addition, it is necessary to improve energy efficiency, change to low-energy sources, and apply renewable energy.

Oxidation Behavior at the Interface between E-beam Coated $ZrO_{2}$-7wt.%$Y_{2}O}_{3}$and Plasma Sprayed CoNiCrAlY (전자빔 코팅 및 플라즈마 용사에 의한 안정화지르코니아/CoNiCrAlY 계면의 산화거동)

  • Choi, Won-Seop;Kim, Young-Do;Jeon, Hyeong-Tag;Kim, Hyon-Tae;Yoon, Kook-Han;Hong, Kyung-Tae;Park, Jong-Ku;Park, Won-Sik
    • Korean Journal of Materials Research
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    • v.8 no.6
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    • pp.538-544
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    • 1998
  • The spallation of a thermal barrier coating layer depends on the formation of brittle spinels. thermal expansion mismatch between ceramic and metal. the phase transformation of a ceramic layer and residual stress of coating layer. In this work. the formation mechanism of oxide scale formed by oxidation treatment at 90$0^{\circ}C$ was investigated in order to verify oxidation behavior at the interface between E-beam coated $Zr0_2$-7wt.% $Y_20_3$ and plasma sprayed CoNiCrAIY. Some elements distributed in the bond coating layer were selectively oxidized after oxidation. At the initial time of oxidation. AI-depletion zone and $\alpha$-$Al_O_3$,O, were formed at the bond coating layer by the AI-outward diffusion. After layer grew until critical thickness. spinels. $Cr_20$, and $C0_2CrO_4$ by outward diffusion of Co. Cr, Ni were formed. It was found that the formation of spinels may be related to the spallation of $Zr0_2$-7wt.% $Y_20_3$ during isothermal oxidation.

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Research for a cases of overseas constructions and domestic tentative execution about high vacuum dewatering and consolidation/dehydration by Super Well point method (슈퍼웰포인트공법에 의한 고진공배수 압밀탈수에 대한 시공사례)

  • Shin, Chang-Beom;Kim, Dae-Hwal;Takahashi, Shigeyoshi;Lee, Kwang-Yeol
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.10a
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    • pp.581-590
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    • 2008
  • A SWP method is a revolutionary dewatering method. The conventional dewatering method, deep-well method, had ever occurred a civil appeal caused by the well depletion in compliance with the reduction of the groundwater level over a wider area considerably by the deep-well pumping from homogeneous sand-layer ground for a dry-work, while pump groung excavation working in Sendai city, Japan 10 years ago. it'd developed with the problematic proposal to find the new method which can lower the groundwater level only within the sheet pile without any reduction of groundwater outside of the sheet pile and until currently steady improvement came. It's been confirmed with plenty of executional results that there was almost no decreasing of water-level from surroundings, over so many construction-sites including vertical shafts which completely does not enter into non-water permeable layer and pumping ground etc. The SWP method in this time has been introducing initially and carried into a the execution tentatively at a construction-site and made a various result get through the execution.

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Development of the Assessment Framework for the Environmental Impacts in Construction

  • Hong, Tahoon;Ji, Changwoon;Jeong, Kwangbok;Park, Joowan
    • Journal of Construction Engineering and Project Management
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    • v.3 no.3
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    • pp.1-9
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    • 2013
  • Environmental problems like global warming have now become important issues that should be considered in all industries, including construction. In South Korea, many studies have been conducted to achieve the government's goals of reduction in environmental impacts. However, the research on buildings has only focused on CO2 emission as a research target despite the fact that other environmental impacts resulting from ozone depletion and acidification should also be considered, in addition to global warming. In this regard, this study attempted to propose assessment criteria and methods to evaluate the environmental performance of the structures from various aspects. The environmental impact category can be divided into global impacts, regional impacts, and local impacts. First, global impacts include global warming, ozone layer depletion, and abiotic resource depletion, while regional impacts include acidification, eutrophication, and photochemical oxidation. In addition, noise and vibration occurring in the building construction phase are defined as local impacts. The evaluation methods on the eight environmental impacts will be proposed after analyzing existing studies, and the methods representing each environmental load as monetary value will be presented. The methods presented in this study will present benefits that can be obtained through green buildings with a clear quantitative assessment on structures. Ultimately, it is expected that if the effects of green buildings are clearly presented through the findings of this study, the greening of structures will be actively expanded.

An Estimation of the New Production in the Southern East Sea Using Helium Isotopes

  • Kim, Kyung-Ryul;Hahm, Do-Shik
    • Journal of the korean society of oceanography
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    • v.36 no.1
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    • pp.19-26
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    • 2001
  • The biological pump is one of the important pumping mechanisms absorbing CO$_2$ from the atmosphere into the ocean and can be quantified by estimating new production. New production in the open ocean mostly depends on the supply of nitrate from the water below the mixed layer. While nitrate is affected by many biological processes, the helium isotope ($^3$He) is inert and has very simple physical properties. Using the $^3$He flux and the relation between $^3$He and NO${_3}\;{^-}$- within the thermocline, the nitrate flux supporting new production was estimated in the southern East Sea. The average ${\delta}^3$He within the mixed layer was -14$%_o$ and -l5.4$%_o$ in the winter and autumn, respectively. Through the year excess $^3$He occurs in the mixed layer except for a slight depletion of -17$%_o$ in summer. The $^3$He flux of 13$%_o$md$^{-1}$ associated with the concentration gradient at the air-sea interface was calculated from the product of the piston velocity and the excess $^3$He. Tritium decay within the mixed layer could support only 2$%_o$md$^{-1}$ of the flux. Thus, the remaining 11$%_o$md^{-1}$ could be attributed to the flux of tritiugenic $^3$He from the water below the mixed layer. Nitrate and $^3$He were positively correlated within the thermocline layer with the slope of 0.21 ${\mu}$mol kg$^{-1}$ $%_o\;^{-1}$. The annual nitrate flux estimated from the upward flux of $^3$He and the NO$_{3}\;{^-}$-$^3$He relation was 0.8${\pm}$0.2 mol(N) m$^{-2}$yr$^{-1}$. This flux corresponds to an annual new production of 64 g(C) m$^{-2}$yr$^{-1}$, which is consistent with that in the north-west Pacific.

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