• 동력기계공학회지
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• 제9권1호
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• pp.70-75
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• 2005

The damping property of Fe-12Cr-22Mn-X alloys has been investigated to develop high damping and high strength alloy. Particularly, the effect of the phase of austenite, alpha and epsilon martensite, which constitute the structure of the alloys Fe-12Cr-22Mn-X alloys, on the damping capacity at room temperature has been investigated. Various fraction of these phases were formed depending on the alloy element and cold work degree. The damping capacity is strongly affected by ${\varepsilon}$ martensite while the other phase, such as ${\alpha}'$ martensite, actually exhibit little effect on damping capacity. In case of Fe-12Cr-22Mn-3Co alloy, the large volume fraction of ${\varepsilon}$ martensite formed at about 30% cold rolling, and in case of Fe-12Cr-22Mn-1Ti alloy, formed at about 20% cold rolling and showed the highest damping capacity. Damping capacity showed higher value in Fe-12Cr-22Mn-1Ti alloy than one in Fe-12Cr-22Mn-3Co alloy.

• 한국재료학회지
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• 제11권12호
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• pp.1042-1046
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• 2001

Co-22%Cr alloy films are promising for high-density perpendicular magnetic recording media with their perpendicular anisotropy and large coercivity of 3000 Oe. We observed that a self organized nano structure(SONS) of fine ferromagnetic Co-enriched phase and paramagnetic Cr-enriched phase appears inside the grain of Co-Cr magnetic alloy thin films at the elevated substrate temperature after do-sputtering. We prepared 1000 $\AA$-thick Co-22%Cr films on 2000 $\AA$- SiO$_2$/Si(100) substrates at the deposition rate of 100 $\AA$/min with substrate temperatures of 3$0^{\circ}C$, 10$0^{\circ}C$, 15$0^{\circ}C$, 20$0^{\circ}C$, 30$0^{\circ}C$, and 40$0^{\circ}C$, respectively. We employed a vibrating sample magnetometer(VSM) to measure the B-H loops showing the saturation magnetifation, coercivity, remanence in in- plane and out- of- plane modes. In- plane coercivity, perpendicular coercivity, and perpendicular remanence increased as substrate temperature increased, how-ever they decreased after 30$0^{\circ}C$ slowly. Transmission electron microscope (TEM) characterization revealed that the self organized nano structure (SONS) appears at the elevated substrate temperature, which forms fine Co-enriched phases inside a grain, then it eventually affect the perpendicular magnetic property. Our results imply that we may tune the perpendicular magnetic properties with SONS obtained at appropriate substrate temperature.

• The Journal of Advanced Prosthodontics
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• 제6권4호
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• pp.272-277
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• 2014

PURPOSE. The purpose of this study was to investigate the impact of different surface treatment methods and thermal ageing on the bond strength of autopolymerizing acrylic resin to Co-Cr. MATERIALS AND METHODS. Co-Cr alloy specimens were divided into five groups according to the surface conditioning methods. C: No treatment; SP: flamed with the Silano-Pen device; K: airborne particle abrasion with $Al_2O_3$; Co: airborne particle abrasion with silica-coated $Al_2O_3$; KSP: flamed with the Silano-Pen device after the group K experimental protocol. Then, autopolymerized acrylic resin was applied to the treated specimen surfaces. All the groups were divided into two subgroups with the thermal cycle and water storage to determine the durability of the bond. The bond strength test was applied in an universal test machine and treated Co-Cr alloys were analyzed by scanning electron microscope (SEM). Two-way analysis of variance (ANOVA) was used to determine the significant differences among surface treatments and thermocycling. Their interactons were followed by a multiple comparison' test performed uing a post hoc Tukey HSD test (${\alpha}=.05$). RESULTS. Surface treatments significantly increased repair strengths of repair resin to Co-Cr alloy. The repair strengths of Group K, and Co significantly decreased after 6,000 cycles (P<.001). CONCLUSION. Thermocycling lead to a significant decrease in shear bond strength for air abrasion with silica-coated aluminum oxide particles. On the contrary, flaming with Silano-Pen did not cause a significant reduction in adhesion after thermocycling.

• 한국자기학회지
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• 제12권1호
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• pp.30-33
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• 2002

초미세결정렵 Nd-Fe-B-Mo-Cu합금에서 Co 치환이 미세조직과 자기특성에 미치는 영향을 조사 하였다. 급속응고법으로 제조된 비정질 Nd-(Fe, Co)-B-Mo-Cu합금은 결정화에 의하여 $\alpha$-Fe기 초미세결정립 Nd-(Fe, Co)-B-Mo-Cu합금이 제조되었다. Co로의 Fe치환은 결정립 미세화에 기여하며, 이로 인하여 경자기특성이 개선되었다. 최적열처리된 초미세결정립 N $d_4$(F $e_{0.85}$ $Co_{0.15}$)$_{82}$ $B_{10}$M $o_3$Cul합금의 잔류자화, Curie온도는 Co가 치환되지 않은 합금에 비하여 개선된 우수한 특성을 나타내었다. 64$0^{\circ}C$, 10분 열처리된 초미세결정립 N $d_4$(F $e_{0.85}$ $Co_{0.15}$)$_{82}$ $B_{10}$M $o_3$Cu 합금의 평균결정립 크기는 약 15 nm이며, 이때 보자력, 잔류자화 및 최대에너지적은 각각 239kA/m, 1.4 T 및 103.5 kJ/ $m^3$이었다.

• 센서학회지
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• 제7권1호
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• pp.45-50
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• 1998

마그네트론 코스퍼터링법으로 측온저항체 온도센서용 Pt-Co 합금박막을 $Al_{2}O_{3}$ 기판위에 증착시켰다. Lift-off 방법을 이용하여 $Al_{2}O_{3}$ 기판위에 Pt-Co 합금박막 저항체를 만들었으며, 인가전력, 진공도, 열처리 온도 및 신간에 따른 합금박막의 물리적, 전기적 특성을 조사하였다. 열처리 온도, 시간이 증가할수록 박막의 비저항 및 면저항이 감소하였다. 인가전력 Pt : $4.4 W/cm^{2}$, Co : $6.91\;W/cm^{2}$, 진공도 10 mTorr, $800^{\circ}C$, 60분간 열처리를 행한 Pt-Co 합금박막의 비저항 및 면저항은 각각 $15{\mu}{\Omega}{\cdot}cm$, $0.5{\Omega}/{\square}$이었다. 그리고 $25{\sim}600^{\circ}C$의 온도범위에서 $3000{\AA}$ 두께를 가지는 Pt-Co 합금박막의 저항온도계수는 $3740ppm/^{\circ}C$로 측정되었다. 이러한 결과로 Pt-Co 합금 박막은 측온저항체 온도센서로서의 가능성을 확인하였다.

• The Journal of Advanced Prosthodontics
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• 제10권1호
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• pp.25-31
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• 2018

PURPOSE. The aim of the present study was to record the metal-ceramic bond strength of a feldspathic dental porcelain and a Co-Cr alloy, using the Direct Metal Laser Sintering technique (DMLS) for the fabrication of metal substrates. MATERIALS AND METHODS. Ten metal substrates were fabricated with powder of a dental Co-Cr alloy using DMLS technique (test group) in dimensions according to ISO 9693. Another ten substrates were fabricated with a casing dental Co-Cr alloy using classic casting technique (control group) for comparison. Another three substrates were fabricated using each technique to record the Modulus of Elasticity (E) of the used alloys. All substrates were examined to record external and internal porosity. Feldspathic porcelain was applied on the substrates. Specimens were tested using the three-point bending test. The failure mode was determined using optical and scanning electron microscopy. The statistical analysis was performed using t-test. RESULTS. Substrates prepared using DMLS technique did not show internal porosity as compared to those produced using the casting technique. The E of control and test group was $222{\pm}5.13GPa$ and $227{\pm}3GPa$, respectively. The bond strength was $51.87{\pm}7.50MPa$ for test group and $54.60{\pm}6.20MPa$ for control group. No statistically significant differences between the two groups were recorded. The mode of failure was mainly cohesive for all specimens. CONCLUSION. Specimens produced by the DMLS technique cover the lowest acceptable metal-ceramic bond strength of 25 MPa specified in ISO 9693 and present satisfactory bond strength for clinical use.

• 대한치과보철학회지
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• 제36권2호
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• pp.336-354
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• 1998

Traditionally, many kinds of mechanical bonding techniques were used for bonding resins to the surface of the metal alloys. If there is a seperation between resin and metal junction by stress accumulation and temperature change of oral cavity, the cracks or crazing may occur, accompanied by failure of resin bonding to metal. This study was designed to compare the shear bond strength of the type IV gold alloy and Cr-Co alloy surfaces treated with various methods and thermocycling. Universal Instron (Model 1000) and scanning electron microscope (JEOL, Japan) was used to record the shear bond strength of 5 groups. Forty specimens were made for each group ; group 1 was treated with sandblasting only, group 2 was coated with V-primer after sandblasting, group 3 was coated with Metal primer, group 4 wase coated with MR Bond and group 5 was coated with silane. After treated with various methods, thermocycling was done for half of the each group. The surfaces of failed pattern were observed with SEM. The results were as follows : 1. Shear bond strength of the group 1 was lower than that of another groups in type IV gold alloys and bond strength of the group 1, 2 were lower than that of group 3, 4, 5 in Cr-Co alloys. 2. Shear bond strength of the gold alloy with resin was higher than that of Cr-Co alloy when specimens were coated with V-primer. 3. Shear bond strength of the Co-Cr alloys with resin was higher than that of gold alloys when specimens were coated with Metal primer. 4. The bond strength of all specimens did not decreased significantly after thermocycling. 5. Adhesive failures were found in group 1 and Cr-Co alloy in group 2, but adhesive and cohesive failures were found in another groups.

• 한국세라믹학회지
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• 제51권4호
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• pp.367-373
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• 2014

In this study, the reducing agent hydrazine and precipitator NaOH were used with $NiCl_2$ as a starting material in order to compound Ni-based material with spherical nano characteristics; resulting material was used as an anode for SOFC. Synthetic temperature, pH, and solvent amounts were experimentally optimized and the synthesis conditions were confirmed. Also, a 0 ~ 0.15 mole ratio of metal(Co, Fe) was alloyed in order to increase the catalyst activation performance of Ni and finally, spherical nano $Ni_{(1-x)}-M_{(x=0{\sim}0.15)}$(M = Co, Fe) alloy materials were compounded. In order to evaluate the catalyst activation for hydrocarbon fuel, fuel gas(10%/$CH_4$+10%/Air) was added and the responding gas was analyzed with GC(Gas Chromatography). Catalyst activation improvement was confirmed from the 3% hydrogen selectivity and 2.4% methane conversion rate in $Ni_{0.95}-Co_{0.05}$ alloy; those values were 4.4% and 19%, respectively, in $Ni_{0.95}-Fe_{0.05}$ alloy.

• Nuclear Engineering and Technology
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• 제43권1호
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• pp.19-24
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• 2011

These experimental studies are carried out to build a database for analyzing fuel performance in nuclear power plants. In particular, this study focuses on the mechanical and irradiation properties of three kinds of zirconium alloy (Alloy A, Alloy B and Alloy C) irradiated in the HANARO (High-flux Advanced Neutron Application Reactor), one of the leading multipurpose research reactors in the world. Yield strength and ultimate tensile strength were measured to determine the mechanical properties before and after irradiation, while irradiation growth was measured for the irradiation properties. The samples for irradiation testing are classified by texture. For the irradiation condition, all samples were wrapped into the capsule (07M-13N) and irradiated in the HANARO for about 100 days (E > 1.0 MeV, $1.1{\times}10^{21}\;n/cm^2$). These tests and results indicate that the mechanical properties of zirconium alloys are similar whether unirradiated or irradiated. Alloy B has shown the highest yield strength and tensile strength properties compared to other alloys in irradiated condition. Even though each of the zirconium alloys has a different alloying content, this content does not seem to affect the mechanical properties under an unirradiated condition and low fluence. And all the alloys have shown the tendency to increase in yield strength and ultimate tensile strength. Transverse specimens of each of the zirconium alloys have a slightly lower irradiation growth tendency than longitudinal specimens. However, for clear analysis of texture effects, further testing under higher irradiation conditions is needed.

• Journal of Magnetics
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• 제6권4호
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• pp.122-125
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• 2001

Phase relationships of the HDDR (hydrogenation, disproportionation, desorption and recombination)-treated Sm$_3$(Fe,M)$_{29}$-type alloy with chemical composition of Sm$_{9}$Fe$_{65}$ $Co_{20}$V$_{6}$ were studied by X-ray diffraction (XRD) and by thermomagnetic analysis (TMA). The alloy was disproportionated into a mixture of $SmH_{x}$ and $\alpha$-Fe at high temperature under hydrogen gas. The disproportionated material was recombined into a mixture of Sm-(Fe,M) (M = Co and/or V) and $\alpha$-Fe phases. The structure of the Sm-(Fe,M) phase was dependent upon the recombination conditions, and a detailed phase diagram showing the phase relationships in the HDDR-treated alloy has been established. The Sm-(Fe,M) phase in material recombined above $900^{\circ}C$ had the $Sm_2Fe_{17}$-type structure, and it exhibited the $SmFe_{7}$-type structure when recombined at temperatures ranging from $700^{\circ}C$ to $850^{\circ}C$. Recombination below $650^{\circ}C$ led to the $SmFe_3$-type structure of the Sm-(Fe,M) phase. Curie temperatures of the Sm-(Fe,M) phases in the recombined material were significantly higher than those of the corresponding stoichiometric phases. It was suggested that the chemical composition of the Sm-(Fe,M) phases may be significantly different from that of the corresponding stoichiometric phases. All the HDDR-treated $Sm_{9}Fe_{65}Co_{20}V_{6}$ materials showed the soft magnetic features regardless of the phase constitution.n.