• Title/Summary/Keyword: Co alloy

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Giant Magnetoresistance Behavior and the Effect of Ferromagnetic Layer on the Co-Ag Nano-granular Alloy Films (Co - Ag 합금박막의 거대자기저항 및 강자성 상하지층의 효과)

  • 김용혁;이성래
    • Journal of the Korean Magnetics Society
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    • v.7 no.1
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    • pp.31-37
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    • 1997
  • The magnetoresistance and the saturation field behavior of the Co-Ag nano granular films as a function of the composition and the ferromagnetic underlayer and overlayermaterials were investigated. The maximum magnetoresistance of 23% and the saturation field of 2.3 kOe at room temperature were obtained in the as-deposited 3000$\AA$ $Co_{30}Ag_{70}$ single alloy films. The magnetoresistance and the saturation field of 100$\AA$ $Co_{30}Ag-{70}$ alloy film were 3.65 % and 3.0 kOe respectively. Those of the sandwiched films with 200$\AA$ Fe were 3.3 % and 1.23 kOe respectively. The saturation field of the sandwiched alloy films could be reduced by the exchange coupling between the ferromagnetic layers and the alloy layer. The effective depth of the exchange coupling was approximately 150$\AA$ in each Fe layer. Among the Fe, Co, and FeNi, the most effective materials to reduce the saturation field of the sandwiched alloy films was Fe.

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Surface Segregation and Order of FeCo Alloy (FeCo 합금의 표면 편석과 질서도)

  • Han, Wone-Keun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.3
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    • pp.240-244
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    • 2010
  • The surface segregation and surface order near the order-disorder phase transition of FeCo alloy was studied through Monte Carlo simulation of an Ising type model Hamiltonian. The results showed that the proper choice of Hamiltonian parameters could reproduce the recent observation of surface order above the transition temperature and that the field term played dominant role.

Electrochemical Corrosion Properties of Amorphous Co-Nb-B Alloys Prepared by Melt-Spinning Method (액체급냉법에 의해 제조한 비정질 Co-Nb-B 합금의 전기화학적 부식 특성)

  • Kim, Eun-Sun;Kim, Hyun-Goo;Jang, HeeJin
    • Corrosion Science and Technology
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    • v.13 no.4
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    • pp.152-156
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    • 2014
  • This study was undertaken to examine the electrochemical corrosion properties of an $Co_{80}Nb_{10}B_{10}$ and $Co_{82}Nb_8B_{10}$ amorphous alloys prepared by melt-spinning method under various conditions. The potentiodynamic polarization responses at various levels of pH (pH 2, pH 7, pH 12) showed that the corrosion current rate of $Co_{80}Nb_{10}B_{10}$ alloy is lower than that of $Co_{82}Nb_8B_{10}$ alloy in all levels of pH, implying the general corrosion resistance of the alloy with higher Nb content is better than that with higher Co content. The pitting potential of $Co_{80}Nb_{10}B_{10}$ alloy was also better than that of $Co_{82}Nb_8B_{10}$, evidenced by the higher pitting potential. Nb is thought to be effective in increasing the protectiveness of the passive film and hence to improve the corrosion resistance of Co-Nb-B alloys.

Corrosion Behaviors of TiN Coated Dental Casting Alloys (TiN피막 코팅된 치과주조용 합금의 부식거동)

  • Jo, Ho-Hyeong;Park, Geun-Hyeng;Kim, Won-Gi;Choe, Han-Cheol
    • Korean Journal of Metals and Materials
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    • v.47 no.2
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    • pp.129-137
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    • 2009
  • Corrosion behaviors of TiN coated dental casting alloys have been researched by using various electrochemical methods. Three casting alloys (Alloy 1: 63Co-27Cr-5.5Mo, Alloy 2: 63Ni-16Cr-5Mo, Alloy 3: 63Co-30Cr-5Mo) were prepared for fabricating partial denture frameworks with various casting methods; centrifugal casting(CF), high frequency induction casting(HFI) and vacuum pressure casting(VP). The specimens were coated with TiN film by RF-magnetron sputtering method. The corrosion behaviors were investigated using potentiostat (EG&G Co, 263A. USA) in 0.9% NaCl solution at $36.5{\pm}1^{\circ}C$. The corrosion morphologies were analyzed using FE-SEM and EDX. Alloy 1 and Alloy 2 showed the ${\alpha}-Co$ and ${\varepsilon}-Co$ phase on the matrix, and it was disappeared in case of TiN coated Alloy 1 and 2. In the Alloy 3, $Ni_2Cr$ second phases were appeared at matrix. Corrosion potentials of TiN coated alloy were higher than that of non-coated alloy, but current density at passive region of TiN coated alloy was lower than that of non-coated alloy. Pitting corrosion resistances were increased in the order of centrifugal casting, high frequency induction casting and vacuum pressure casting method from cyclic potentiodynamic polarization test.

Effect of Fcrromagnetic Layer and Magnetoresistance Behavior of Co-Evaporated Ag-CoFe Nano-Granular Alloy Films (Ag - CoFe 합금박막의 자기저항 및 강자성 상하지층의 효과)

  • 김용혁;이성래
    • Journal of the Korean Magnetics Society
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    • v.7 no.6
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    • pp.308-313
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    • 1997
  • The magnetoresistance (MR) and the saturation field behavior of the CoFe-Ag nano granular films as a function of the ferromagnetic underlayer and overlayer materials were investigated. The maximum MR ratio of 25.7 % and the saturation field of 2.1 kOe in the as-deposited 3000 $\AA$ $(Co_{92}Fe_8)_{31}Ag_{69}$ single alloy films at room temperature were obtained. The MR ratio and the saturation field of the 100 $\AA$ alloy film were 1.2 % and 5.2 kOe, respectively. Those of the sandwiched alloy films of 200 $\AA$ thick with the Fe under and overlayer of 100 $\AA$ were 11 % and 1.8 kOe respectively. The reduction of saturation field in the sandwiched alloy films is due to the exchange coupling between the ferromagnetic layers and the alloy layer. Among the Fe and FeNi, the more effective materials to reduce the saturation field of the sandwiched alloy films was Fe.

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Effects of W Contents in Co Matrix of the Thermal Sprayed WC-Co on the Corrosion Behavior in Molten Zinc

  • Seong, Byeong-Geun;Hwang, Sun-Young;Kim, Kyoo-Young;Lee, Kee-Ahn
    • Corrosion Science and Technology
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    • v.6 no.4
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    • pp.147-153
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    • 2007
  • This study sought to investigate the reaction of Co-binder containing tungsten with molten zinc. Four kinds of Co-W alloys (pure, 10%W, 20%W, 30%W) were prepared using the powder metallurgy method. The specimens were immersion-tested in molten pure zinc baths at $460^{\circ}C$. To evaluate the corrosion property in molten zinc, the weight loss of the specimen was measured after the immersion tests at different immersion times (10~300 min.). Co-10%W alloys, compared with pure cobalt, showed no effect of tungsten addition on the reaction rate in molten zinc. The relationship between the weight loss and the square root of immersion period represents a straight line in both pure cobalt and Co-10%W alloy. The Co-Zn reaction layer in Co- 1O%W alloy consists of $\gamma2$, $\gamma1$, $\gamma$ and ($\beta1$ phases. The rate of weight loss significantly increases and the weight loss behavior is not well accord with the linear relationship as the tungsten content in the Co-W alloy increases. The $\beta1$ layer was not formed on the Co-20%W alloy and neither was a stable Co-Zn intermetallic compound layer found on the Co-30%W alloy. The main cause of increase in reaction rate with increasing tungsten content is related with the instability of the Co-Zn reaction phases as seen on micro-structural analysis.

Structural and Magnetic Properties of Co2MnSi Heusler Alloy Films

  • Lim, W.C.;Okamura S.;Tezuka N.;Inomata K.;Bae, J.Y.;Kim, H.J.;Kim, T.W.;Lee, T.D.
    • Journal of Magnetics
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    • v.11 no.1
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    • pp.8-11
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    • 2006
  • Recently half-metallic full-Heusler alloy films have attracted significant interests for spintronics devices. As these alloys have been known to have a high spin polarization, very large TMR ratio is expected in magnetic tunnel junctions. Among these alloys, $Co_2MnSi$ full-Heusler alloy with a high spin polarization and a high Curie temperature is considered a good candidate as an electrode material for spintronic devices. In this study, the magnetic and structural properties of $Co_2MnSi$ Heusler alloy films were investigated. TMR characteristics of magnetic tunnel junctions with a $Co_2MnSi/SiO_2/CoFe$ structure were studied. A maximum MR ratio of 39% with $SiO_2$ substrates and 27% with MgO(100) substrates were obtained. The lower MR ratio than expectation is considered due to off-stoichiometry and atomic disorder of $Co_2MnSi$ electrode together with oxidation of the electrode layer.

Co-Re-based alloys a new class of material for gas turbine applications at very high temperatures

  • Mukherji, D.;Rosler, J.;Wehrs, J.;Eckerlebe, H.;Gilles, R.
    • Advances in materials Research
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    • v.1 no.3
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    • pp.205-219
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    • 2012
  • Co-Re alloy development is prompted by the search for new materials for future gas turbines which can be used at temperatures considerably higher than the present day single crystal Ni-based superalloys. The Co-Re based alloys are designed to have very high melting range. Although Co-alloys are used in gas turbine applications today, the Co-Re system was never exploited for structural applications and basic knowledge on the system is lacking. The alloy development strategy therefore is based on studying alloying additions on simple model alloy compositions of ternary and quaternary base. Various strengthening possibilities have been explored and precipitation hardening through fine dispersion of MC type carbides was found to be a promising route. In the early stages of the development we are mainly dealing with polycrystalline alloys and therefore the grain boundary embrittlement needed to be addressed and boron addition was considered for improving the ductility. In this paper recent results on the effect of boron on the strength and ductility and the stability of the fine structure of the strengthening TaC precipitates are presented. In the beginning the alloy development strategy is briefly discussed.

Process Optimization for Co-based Self-flux Alloy Coating by Taguchi Method (다구찌 기법에 의한 코발트기 자융성합금 용사코팅의 최적공정 설계)

  • Lee, Jae-Hong;Kim, Yeong-Sik
    • Journal of Power System Engineering
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    • v.17 no.6
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    • pp.108-114
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    • 2013
  • This paper describes process optimization for thermal-sprayed Co-based self-flux alloy coating by Taguchi method. Co-based self-flux alloy coatings were fabricated according to $L_9(3^4)$ orthogonal array using flame spray process. Hardness test and wear test were performed, the results were analyzed by analysis of variance(ANOVA) considering a multi response signal to noise ratio(MRSN). From the results of ANOVA, the optimal combination of the flame spray parameters on Co-based self-flux alloy coating could be predicted. The calculated hardness and wear rate of the coatings by ANOVA were found to be close to that of confirmation experimental result.

Effect of Oxygen on Mechanical Properties of Metal Injection Molded Titanium and Titanium Alloy

  • Doi, Kenji;Hanami, Kazuki;Tanaka, Hideki;Teraoka, Tsuneo;Terauchi, Shuntaro
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.771-772
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    • 2006
  • Mechanical properties of metal injection molded titanium and titanium alloy parts were investigated in this study. Material powders with low oxygen content and spherical shape were obtained by electrode induction-melting gas atomization which could melt and atomize titanium and titanium alloy bars with no touch on crucible or tundish. Tensile specimens were fabricated from obtained powders by metal injection molding process. Tensile strength of the specimens increases with increasing oxygen content. This result corresponds to a tendency of wrought metal.

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