• 제목/요약/키워드: Co(II)

검색결과 2,040건 처리시간 0.033초

Influence of Implant Surface Coated with pH Buffering Agent on Early Osseointegration

  • Kang, Joo Hyun;Kim, Su-Kyoung;Pae, Hyung Chul;Park, Jin Young;Cha, Jae-Kook;Choi, Seong-Ho
    • Journal of Korean Dental Science
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    • 제11권1호
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    • pp.5-13
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    • 2018
  • Purpose: Surface treatment with pH buffering agent has been developed to achieve higher and faster osseointegration. The aim of this study was to evaluate its influence by measuring removal torque and analyzing histological characteristics. Materials and Methods: Titanium implants with following surfaces were used in this study: sand-blasted acid-etched (SA) surface (SA group as control I group), SA surface in calcium chloride aqueous solution (CA group as control II group) and SA surface coated with pH buffering agent (pH group as test group). Removal torque test after 2 weeks and bone-to-implant contact and bone area analyses at 2 and 4 weeks were performed. Result: The rotational torque values at 2 weeks were significantly higher in pH group ($107.5{\pm}6.2Ncm$, P<0.05). The mean values of bone-to-implant contact at 2 and 4 weeks were both higher in pH group ($93.0%{\pm}6.4%$ at 2 weeks, $88.6%{\pm}5.5%$ at 4 weeks) than in SA group ($49.7%{\pm}9.7%$ at 2 weeks, $47.3%{\pm}20.1%$ at 4 weeks) and CA group ($73.7%{\pm}12.4%$ at 2 weeks, $72.5%{\pm}10.9%$ at 4 weeks) with significances (P<0.05). The means of bone area showed significantly higher numbers in pH group ($39.5%{\pm}11.3%$ at 2 weeks, $71.9%{\pm}10.9%$ at 4 weeks, P<0.05). Conclusion: Our findings demonstrated that surface modification with pH buffering agent improved early osseointegration with superior biomechanical property.

돈분과 피마자박의 혼합비율에 따른 퇴비화 연구 (Composting of the Mixtures with Pig Manure and Castor Meal)

  • 장기운;이종진;홍주화;김남천;김완주;최우영
    • 농업과학연구
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    • 제34권2호
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    • pp.181-188
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    • 2007
  • This study was conducted to estimate the humificating grade according to experiment of physico-chemical characterization and phyto-toxicity during composting of using with pig manure and castor meal. The material ratios of the compost which was mixed with pig manure(P), castor meal(C), and saw dust(S) were 5 : 1 : 4(PCS-I), 5 : 2.5 : 2.5(PCS-II) and 5 : 4 : 1(PCS-III) by volume to volume, and they were decomposed for 60 days. In the result, the changes of temperature in all treatments during composting were rapidly increased more than $68^{\circ}C$ at the incipient stage, and gradually decreased within $39^{\circ}C$ at 60 days the after treatment. pH was slowly increased from 7.5 to 7.7, and the C/N ratio was 13~14 at the final composting stage. The low C/N ratio value in this compost was caused by the castor meal contented high nitrogen level(T-N 5.7 %). G.I.(germination index) was showed 73 to 78 range in all treatments at the $60^{th}$ day. Among all treatments PCS-I was appeared to be the best condition for composting.

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도자기 유약용 Wagnerite의 합성(II) (Synthesis of wagnerite and its analogues for ceramic pigments (ll))

  • Yong- Sun Chung;Keun Ho Auh
    • 한국결정성장학회지
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    • 제7권4호
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    • pp.648-657
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    • 1997
  • 합성원료로써 $Mg_3(PO_4)_2$$MgF_2$분말을 혼합한 후 백금밀폐용기를 사용하여 $1040^{\circ}C$에서 단일상의 wagnerite$(Mg_2PO_4F)$를 합성하였으며 이 결정상의 동질이상에 대하여 연구한 결과, 이미 발표된 연구 결과들과는 달리 $1255^{\circ}C$에서 단 한번의 가역적인 상전이가 관찰되었고, $1340^{\circ}C$에서 용융될 때까지 열분해 현상은 나타나지 않았으며, 이로써 2가 금속이온의 치환에 의해 여러 종류의 고용체를 합성해 낼 경우, 유약 및 플라스틱의 색상발현을 위한 안료로 사용될 수 있는 것으로 밝혀졌다. $Zn_4P_2O_8F_2$$Zn_3MgP_2O_8F_2$ wagnerite의 Zn 대신 2가 금속을 치환한 경우, 전반적으로 d값이 줄어들었으며 Co는 자주색, Ni은 금색, Cu는 녹색을 나타내었다. 또한 charge-coupled 치환을 시도한 결과, $A^{1+}A_3^{2+}X^{5+}X^{6+}O_8_F2$의 경우만 wagnerite가 형성되었다.

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Physiological Responses of Calystegia soldanella under Drought Stress

  • Bae, Chae-Youn;Hwang, Jeong-Sook;Bae, Jeong-Jin;Choi, Sung-Chul;Lim, Sung-Hwan;Choi, Deok-Gyun;Kim, Jong-Guk;Choo, Yeon-Sik
    • Journal of Ecology and Environment
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    • 제36권4호
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    • pp.255-265
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    • 2013
  • This study was conducted to determine the extent of drought resistance based on physiological responses of Calystegia soldanella under water deficit. In order to investigate the changes of plant growth, stomatal density, photosynthesis, chlorophyll fluorescence, the contents of chlorophyll and carotenoid, osmolality, total ion contents, the contents of carbohydrate and proline, C. soldanella was grown under well watered and drought stressed conditions for 12 days. In this study, water-deficit resulted in remarkable growth inhibition of C. soldanella. The effect of water-deficit on plant growth was associated with low osmotic potential of soil. On day 12 after drought treatment, dry weight, relative water contents, number and area of leaves and stem length were lower than those of control. The stomatal conductance and net photosynthetic rate were significantly reduced in water stressed plant to regulate inner water contents and $CO_2$ exchange through the stomatal pore. Chlorophyll fluorescence and chlorophyll contents were not different in comparison with the control, indicating that the efficiency of photosystem II was not affected by drought stress. This results could be explained that water-deficit in C. soldanella limits the photosynthetic rate and reduces the plant's ability to convert energy to biomass. A significant increase in total ion contents and osmolality was observed on day 7 and day 12. Accumulation of proline in leaves is associated with the osmotic adjustment in C. soldanella to soil water-deficit. Consequently, this increase in osmolality in water stressed plant can be a result in the increase of ion contents and proline.

IPS Empress $2^(R)$를 이용한 전부도재관의 변연적합성과 파절강도에 관한 연구 (A STUDY ON THE MARGINAL FIDELITIES AND FRACTURE STRENGTH OF IPS EMPRESS $2^(R)$ CERAMIC CROWNS)

  • 유지형;김용철;강동완
    • 대한치과보철학회지
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    • 제38권5호
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    • pp.606-617
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    • 2000
  • The purpose of this study was to measure the marginal fidelities and the fracture strength of IPS Empress $2^{(R)}\;and\;In-Ceram^{(R)}$ ceramic crowns. After constructed of 12 experimental dies for each group, ceramic crowns were fabricated on the metal master dies prepared on the maxillary right premolar Marginal gaps were measured on the specimen between the margin of each crown and finish-ing line of the metal master die by using stereo-microscope($SZ-ST^{(R)}$ Olympus, Japan) and all specimens were cemented on the metal master die with Bistite $II^{(R)}$ (Tokuyama soda Co, LTD., Japan) resin cement. Finally marginal gaps were measured again. To measure of the fracture strength, buccal incline on the functional cusp of specimens were loaded until the catastrophic failure occurred by using the AGS-1000 $D^{(R)}$(Shimadzu, Japan). The result of marginal fidelities and fracture strength were statistically analyzed with the SPSS version 8.0 programs. The results of this study were as follows : 1. No significant difference was found in the mean marginal fidelities and fracture strength between the IPS Empress $2^{(R)}\;and\;In-Ceram^{(R)}$. 2. In comparison of marginal fidelities between before and after cementation, there was significant difference(P<0.05). The IPS Empress 2 system was shown in this study that had good marginal fidelities and fracture strength compared to In-Ceram ceramics. Although this system was acceptable to clinical applications, the system still has to be considered long-term researches about marginal fidelities and fracture strength due to the lack of data about the clinical researches.

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수전해용 Pt/공유가교 SPEEK-HPA 복합막/Pt-Ru MEA의 전기화학적 특성 (The Electrochemical Characteristics of MEA with Pt/Cross-Linked SPEEK-HPA Composite Membranes/Pt-Ru for Water Electrolysis)

  • 황용구;우제영;이광문;정장훈;문상봉;강안수
    • 한국수소및신에너지학회논문집
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    • 제20권3호
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    • pp.194-201
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    • 2009
  • The e1ectrocatalytic properties of heteropolyacids(HPAs) entrapped in covalently cross-linked sulfonated polyetheretherketone(CL-SPEEK/HPA) membranes have been studied for water electrolysis. The HPAs, including tungstophosphoric acid(TPA), molybdophosphoric acid(MoPA), and tungstosilicic acid(TSiA) were used as additives in the composite membranes. The MEA was prepared by a non-equilibrium impregnation-reduction(I-R) method, using reducing agent, sodium borohydride(NaBH4) and tetraamineplatinum(II) chloride(pt(NH$_3$)$_4$Cl$_2$). The electrocatalytic properties of composite membranes such as the cell voltage were in the order of magnitude CL-SPEEKlMoPA40 (wt%) > /TPA30 > /TSiA40. In the optimum cell applications for water electrolysis, the cell voltage of PtlPEM/Pt-Ru MEA with CL-SPEEKlTPA30 membrane was 1.75 V at 80$^{\circ}$C and I A/cm$^2$ and this voltage carried lower than that of 1.81 V of Nafion 117. Consequently, in regards of electrochemical and mechanical characteristics and oxidation durability, the newly developed CL-SPEEKITPA30 composite membrane exhibited a better performance than the others, but CLSPEEKlMoPA40 showed the best electrocatalytic activity (1.71 Vat 80$^{\circ}$C and 1 A/cm$^2$) among the composite membranes.

장비정도관리에 Calibrator[I-125] Set 적용 (The Application of New Calibrator[I-125]Set for Equipment Quality Management)

  • 김지나;안재석;원우재
    • 핵의학기술
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    • 제19권2호
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    • pp.108-111
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    • 2015
  • Purpose Lately, in accordance with the increasing interest about Healthcare accreditation program and International laboratory accreditation scheme, requirements about the instrument quality management are gradually taking shape. In nuclear medicine In vitro laboratory, the most typical instruments are multi detector gamma counter and automatic dispensing system. Each laboratory continue with the quality control adequate for circumstances. The purpose of this study is to application and establish the new Calibrator[I-125]Set which is efficient at standardization of equipment quality management. Materials and Methods Deviation between detectors were measured with 12 solid samples of the Calibrator[I-125]Set. their activities differ from each other by less than 1%. Multi detector gamma counters are GAMMA-10;Shinjin medics. Inc, Goyansi, Korea(Gamma counter A), SR300;Stratec biomedical systems AG, Gewerbestr, Germany(Gamma counter B) and COBRA II; Packard Instrument Co. Inc, Meriden, USA(Gamma counter C). Evaluation of two automatic dispensing system used A, B liquid tracer of the Calibrator[I-125]Set. After dispensing and counting, calculated using the ratio of the measured value and proposed value. We used solution A for 20, 25ul and solution B for 50, 100ul. Method of data analysis and reference range was provided by kit documentation. Furthermore, we could calculate our counter efficiency indirectly. Results The CV(%) of measured values by Gamma counter A, B, C are 0.34, 0.70, 1.30. Calculated value are 1.05314, 2.10419, 4.08485. Provided reference range is less than 3. A dispensing system's calculated values are 0.986, 0.989, 1.023, 1.017 and B are 0.874, 0.725, 1.021, 0.904. Provided reference range is from 0.95 to 1.05. Also, counter's efficiency are 74.18, 72.79, 74.32% at counter A, B, C and efficiency of the one detector counter is 79.26%. Conclusion If using this Calibrator[I-125]Set after verifying whether quality assurance, is applicable to equipment quality management on behalf of the role of gold standard.

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요구공학을 적용한 센서기반 스마트 의류 디자인 프로세스 연구 (A Study of Design Process for Sensor-based Smart clothing based on requirement engineering)

  • 조하경;이주현
    • 감성과학
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    • 제16권3호
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    • pp.397-408
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    • 2013
  • 최근 건강에 대한 관심의 증가와 고령화 사회의 진입으로 인해 센서 기반 스마트 의류는 다양한 어플리케이션과 타입으로 개발되고 있다. 센서기반 스마트 의류는 인체로부터 생체 신호를 측정, 모니터링을 주 목적으로하는 기능성 의류의 한 분야로 신호의 정확성, 기기의 착용성, 센서의 인체 적합성 등의 인체-기기-의류간의 상호작용을 고려하여 디자인되어야 한다는 점에서 기존의 스마트 의류와 다른 특성을 지닌다. 센서기반 스마트 의류의 이러한 특성은 의복의 제작 단계에 있어 요구공학의 단계를 기반으로 개발 목적에 대한 요구의 명확한 문서화 뿐 아니라, 각 단계 진행을 위해 기기분야와 의류분야간의 상호운용성 평가가 이루어져야 하는 필요성을 갖을 것으로 예상된다. 따라서, 본 연구에서는 요구공학이 적용된 센서 기반 스마트 의류 프로세스의 효용성 평가를 위해 실증적 수행 분석을 통해 스마트 의류의 기본 프로세스를 도출하고, 요구공학 분석기법의 단계를 도입하여 두가지 스마트 의류 프로세스를 도출하였다. 제시된 두 프로세스의 실증적 단계별 진행을 통해 프로세스의 효율성 및 디자인의 질적 평가를 수행하였으며, 요구공학이 적용된 센서 기반 스마트 의류의 프로세스의 효용성을 제시하였다.

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팔당호 상류수계에 위치한 환경기초시설의 인 기여도 분석 (Analysis of the Phosphorus Contribution Rate by the Environment Fundamental Facilities Located in Upstream Basin of Paldang Lake)

  • 우영국;박은영;전양근;양희정;임재명
    • 한국물환경학회지
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    • 제26권6호
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    • pp.1016-1027
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    • 2010
  • The phosphorus contribution rate on water quality of North and South-Han River, and Gyungan-cheon by effluents from environmental fundamental facilities located in upstream basin of Paldang Lake were analyzed. QUALKO2 model was selected for the analysis of contrubution rate, and was constructed considering the location of the main point sources and all facilities in study area. The pollutant loading rates and arrival rates for each unit-watershed in study area were calculated for model operation. For the calibration and verification of model, 2006 water quality dataset from Ministry of Environment and the effluent loadings of the environmental fundamental facilities were used. Reliability Index (RI) method was used to estimate the validity of the results of calibration and verification. The phosphorous contribution rate(%) for each environmental fundamental facility were analyzed by excepting the effluent loading of the facility. The contribution rate was analyzed for each facility, facility groups separated by each main river and each unit-watershed. The main results of analysis for each facility are as follows; (i) the phosphorous contribution of B1 facility is 50%, which is the highest phosphorous contribution rate among those of nine facilities in the North-Han River Basin; (ii) the highest phosphorous contribution is 55.6% from J facility among eight facilities in the Gyungan Stream Basin; (iii) 40% from E treatment facility is the highest among those of twenty eight facilities in the South-Han River Basin.

체외배양기술로 생산된 초기배에 의한 한우 송아지 생산기술 III. 배반포와 발생에 미치는 발생배지의 효과와 동결융해후의 생존율에 미치는 Sucrose와 Trehalose의 효과 (Development of Production Techniques for Korean Native Cattle Calves from Embryos by In Vitro Technology 3. Effects of Culture Medium on Blastocyst Development and Effects of Sucrose and Trehalose on the Survival Rate of In Vitro Developed Embryos after Thawing)

  • 서경덕;김호중;김갑수;김광식
    • 한국수정란이식학회지
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    • 제13권2호
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    • pp.173-178
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    • 1998
  • The objective of this study was to evaluate the embryonic development ability and the appearance of blastocysts of bovine in vitro fertilized oocytes cultured in different culture media, and also to evaluate survival rate after thawing of frozen embryos by using 1.5 or 1.8M ethylene glycol(EG) with sucrose or trehalose. Fertilized oocytes were divided into three groups; i ) monolayer of cumulus /granulosa cell prepared by TGM 199+5% calf serum(TGM199), ii)GRlaa+5% CS, iii)SOF+5% CS, and they were cultured after insemination for 9 days, at 39˚C, under 5% $CO_2$ in air, but SOF+5% CS was cultured at 39˚C, under 5% 02, 5% GO2, 99% N2. Blastocysts derived from GRlaa + 5% CS on day 7~8 after insemination were frozen by using 1.5M EG or 1.8M EG with/without 0.2M sucrose or O.1M trehalose. The development rate of blastocysts on day 7 after insemination in SOF+5% CS was significant higher than in TCM199 or CR1aa(P<0.05). The appearance rate of blastocysts on day 7-8 after insemination was higher than in TCM199, when fertilized oocytes were cultured in GRlas or SOF. The survival rate of frozen blastocysts after thawing tended to increase, when blastocysts were frozen by using 1.8M EG with 0.2M sucrose or O.1M trehalose. These results indicated that SOF or CRlaa media with amino acids was superior to TCM199 with monolayer in terms of blastocyst development in culturing of in vitro fertilized bovine nocytes, and sucrose or trehalose was supposed to prevent embryos from the freezing shock.

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