• Title/Summary/Keyword: Cluster Site

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Molecular dynamics simulation of ultra-low energy ion implantation for GSI device technology development (GSI소자 개발을 위한 극 저 에너지 이온 주입에 대한 분자 역학 시뮬레이션)

  • 강정원;손명식;황호정
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.35D no.3
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    • pp.18-27
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    • 1998
  • Molecular dynamicsinvestigations of ion implantation considering point defect generation were performed with ion energies in the range of ~1keV, Simulation starts perfect diamond cubic lattice site. Stillinger-Weber potential and ZBL potential were used to calculate forces between atoms. We have simulated slowing-down of ion velocity, ion trajectory and coupled-coing between ion and silicon. We also discussed distribution of point defect using rdial distribution function. We found that interstitial produced by ion bombardment mainly formed interstitial cluster.

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One-dimensionally Ordered Array of Co and Fe Nanoclusters on Carburized-W(110) via Template Assisted Self-Assembly

  • Kim, Ji-Hyun;Yang, Serlun;Kim, Jae-Sung;Lukashev, Pavel;Rojas, Geoffrey;Enders, Axel;Sessi, Violetta;Honolka, Jan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.135-136
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    • 2012
  • Carbon atoms near the surface of W(110) induce reconstructions such as $R(15{\times}12)$ -C/W(110) which consists of two characteristic parts, one square shaped and bright protrusion and two smaller ones. In the atomic resolution STM image, the bigger protrusion shows the periodicities of clean W(110), indicating that it is almost carbon poor region. The smaller protrusion contains hexagonal carbide surface layer of ${\alpha}$-W2C on W(110). Employing this carburized W(110) as templates, we grow Co and Fe clusters of less than ten atoms. Due to the selectivity of bonding sites, growth of larger cluster is highly unfavorable for Co and the size of clusters is very uniform. Since Co atoms prefer to sit on the bigger protrusion rather than smaller one, Co cluster can be arranged one-dimensionally in $R(15{\times}12)$-C/W(110) with quite uniform size distribution. However, Fe clusters sit on both sites without favored site, but still with uniform size distribution. On the other hand, Fe clusters can be grown with quasi one-dimensional order in $R(15{\times}3)$-C/W(110), which consists of only smaller protrusions. We investigate the magnetic properties of the ordered nano-sized clusters. Experiments using XMCD reveals little magnetic moment of Co cluster on $R(15{\times}12)$-C/W(110). This observation is consistent with the predictions of our first principles calculations that small Co clusters can be nonmagnetic or antiferromagnetic with low mean magnetic moment per atom.

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Eicosapentaenoic Acid (EPA) Biosynthetic Gene Cluster of Shewanella oneidensis MR-1: Cloning, Heterologous Expression, and Effects of Temperature and Glucose on the Production of EPA in Escherichia coli

  • Lee, Su-Jin;Jeong, Young-Su;Kim, Dong-Uk;Seo, Jeong-Woo;Hur, Byung-Ki
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.11 no.6
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    • pp.510-515
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    • 2006
  • The putative EPA synthesis gene cluster was mined from the entire genome sequence of Shewanella oneidensis MR-1. The gene cluster encodes a PKS-like pathway that consists of six open reading frames (ORFs): ORFSO1602 (multi-domain beta-ketoacyl synthase, KS-MAT-4ACPs-KR), ORFSO1600 (acyl transferase, AT), ORFSO1599 (multi-domain beta-ketoacyl synthase, KS-CLF-DH-DH), ORFSO1597 (enoyl reductase, ER), ORFSO1604 (phosphopentetheine transferase, PPT), and ORFSO1603 (transcriptional regulator). In order to prove involvement of the PKS-like machinery in EPA synthesis, a 20.195-kb DNA fragment containing the genes was amplified from S. oneidensis MR-1 by the long-PCR method. Its identity was confirmed by the methods of restriction enzyme site mapping and nested PCR of internal genes orfSO1597 and orfSO1604. The DNA fragment was cloned into Escherichia coli using cosmid vector SuperCos1 to form pCosEPA. Synthesis of EPA was observed in four E. coli clones harboring pCosEPA, of which the maximum yield was 0.689% of the total fatty acids in a clone designated 9704-23. The production yield of EPA in the E. coli clone was affected by cultivation temperature, showing maximum yield at $20^{\circ}C$ and no production at $30^{\circ}C$ or higher. In addition, production yield was inversely proportional to glucose concentration of the cultivation medium. From the above results, it was concluded that the PKS-like modules catalyze the synthesis of EPA. The synthetic process appears to be subject to regulatory mechanisms triggered by various environmental factors. This most likely occurs via the control of gene expression, protein stability, or enzyme activity.

Analysis of Characteristics of NPS Runoff and Pollution Contribution Rate in Songya-stream Watershed (송야천 유역의 비점오염물질 유출 특성 및 오염기여율 분석)

  • Kang Taeseong;Yu Nayeong;Shin Minhwan;Lim Kyoungjae;Park Minji;Park Baekyung;Kim Jonggun
    • Journal of Korean Society on Water Environment
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    • v.39 no.4
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    • pp.316-328
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    • 2023
  • In this study, the characteristics of nonpoint pollutant outflow and contribution rate of pollution in Songya-stream mainstream and tributaries were analyzed. Further, water pollution management and improvement measures for pollution-oriented rivers were proposed. An on-site investigation was conducted to determine the inflow of major pollutants into the basin, and it was found that pollutants generated from agricultural land and livestock facilities flowed into the river, resulting in a high concentration of turbid water. Based on the analysis results of the pollution load data calculated through actual measurement monitoring (flow and water quality) and the occurrence and emission load data calculated using the national pollution source survey data, the S3 and S6 were selected as the concerned pollution tributaries in the Songya-stream basin. Results of cluster analysis using Pearson correlation coefficient evaluation and Density based spatial clustering of applications with noise (DBSCAN) technique showed that the S3 and S6 were most consistent with the C2 cluster (a cluster of Songya-stream mainstream owned area) corresponding to the mainstream of Songya-stream. The analysis results of the major pollutants in the concerned pollution tributaries showed that livestock and land pollutants were the major pollutants. Consequently, optimal management techniques such as fertilizer management, water gate management in paddy, vegetated filter strip and livestock manure public treatment were proposed to reduce livestock and land pollutants.

Theoretical Study of the Cobalt Substituting Site in the Framework of $AlPO_{4}-5$ Molecular Sieves

  • Sang Joon Choe;Dong Ho Park;Do Sung Huh
    • Bulletin of the Korean Chemical Society
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    • v.14 no.1
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    • pp.55-58
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    • 1993
  • In order to determine the cobalt substituting site in $AlPO_4-5$ framework, ASED-MO theory has been used. The substitution of cobalt for aluminum is energetically more favorable than that for phasphorous. The stabilized energy of the former is 51 eV lower than that of the latter. The calculated net charge was +1.27 for Al, +0.85 for P, and +1.56 for Co, respectively. The valence electron population (VEP), reduced overlap population (ROP) and net charge for the charged cluster models were compared for $AlPO_4-5$ and $CoAlPO_4-5$ systems. Then, twe find that the covalency of P-O bond was greater than that of Al-O bond.

Development of Determination System for Optimal Combination of Earthwork Equipments (토공사를 위한 건설장비 투입 최적 조합 산정 시스템 개발)

  • Park, Jae-Woo;Yeom, Dong-Jun
    • Journal of the Korean Society of Industry Convergence
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    • v.23 no.6_2
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    • pp.957-969
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    • 2020
  • The primary objective of this study is to develop a determination system for an optimal combination of earthwork equipment that improves the traditional way in convenience, prediction accuracy, and productivity. For this, the following research works are conducted sequentially; 1)literature review, 2)technology development trend analysis, 3)develop a determination system for the optimal combination of earthwork equipment, 4)simulation of a developed system. As a result, core considerations are deducted for the development of a determination system. Furthermore, site simulation is performed using a developed system. Site simulation result, Cluster 1(R1200LC 7㎥, CAT 775G 65ton×2) was selected from 6 clusters because of its production cost (₩491/㎥). It is expected that the application range and impact on the construction industry will be enormous due to the availability of the developed system.

Effect of Erosion Control Works on Benthic Macroinvertebrate Communities (사방공작물 시공이 저서성 대형무척추동물 군집에 미치는 영향)

  • Lee, Ik-Soo;Jung, Yu-Gyeong;Lee, Heon-Ho
    • Journal of Korean Society of Forest Science
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    • v.101 no.4
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    • pp.686-694
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    • 2012
  • This study was conducted to investigate that affect benthic macroinvertebrates for installed erosion control works at a mountain torrential stream. The survey was carried out six times from April 2007 to October 2008 at two points where erosion control works were installed and at a control point in the upstream with no such works. Variations in the community structure and cluster of benthic macroinvertebrates and ecological water quality were analyzed in the survey. From the six times survey, the identified benthic macroinvertebrates were 6,922 individuals belonged to 27 species, 24 families, 13 orders, 6 classes and 4 phyla. As the average results of three surveyed sites, the dominant species was Gammarus sobaegensis of Amphipoda. The species diversity index(H') showed the highest as 1.47 at Site 2 of the fourth survey and the lowest as 0.24 at Site 2 of the sixth survey. The evenness Index(EI) showed the highest as 0.823 at Site 2 of the fourth survey and the lowest as 0.194 at Site 1 of the fifth survey. The richness index(RI) showed the highest as 2.794 at Site 1 of the first survey and the lowest as 0.291 at Site 2 of the sixth survey. The ecological score of benthic macroinvertebrate community(ESB) and individual of EPT-group were declined during the survey period. The functional feeding group(FFG) showed the highest SH types during the survey period.

Flora and Community Structure of Benthic Marine Algae in Ilkwang Bay, Korea (한국 일광만 저서 해조류의 해조상과 군집구조)

  • Kang, Pil-Joon;Kim, Young-Sik;Nam, Ki-Wan
    • ALGAE
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    • v.23 no.4
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    • pp.317-326
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    • 2008
  • Marine algal flora and community structure were investigated seasonally at three sites in Ilkwang Bay on the southern east coast of Korea from May 2007 to February 2008. Total 103 species including 10 of green algae, 17 of brown algae, 76 of red algae were collected and identified. Among these species, 21 species were found throughout the year. Ulva pertusa, Enteromorpha linza, Grateloupia lanceolata, Chondracanthus intermedia and Caulacanthus ustulatus were distributed dominantly in upper intertidal zone. By contrast, crustose coralline algae, Grateloupia spp., Chondracanthus tenellus, Prionitis cornea and Sargassum spp. occurred predominantly in middle intertidal zone. Grateloupia spp., Sargassum spp., Ecklonia cava and Ulva pertusa were dominant in lower intertidal zone. Annual mean biomass in wet weight was 478.3 g m$^{-2}$. Maximum biomass was recorded in site 1 (731.8 g m$^{-2}$), and minimum was recorded in site 3 (78.5 g m$^{-2}$). The R/P, C/P and (R + C)/P value reflecting flora characteristics were 4.47, 0.59 and 5.06, respectively. Two groups produced by cluster analysis, one including sites 1, 2 and the other including site 3, showed meaningful difference in similarity, each other. Site 3 showed the limited species composition due to inflow of fresh water and absence of solid substratum. However, there was no significant difference between site 1 and site 2. In conclusion, the number of marine algae species and biomass in Ilkwang Bay were markedly reduced comparing with the previous studies. These suggest that a solution for reconstruction of the poor marine algal vegetation is considerably demanded.

Hydroxylation of Indole by PikC Cytochrome P450 from Streptomyces venezuelae and Engineering Its Catalytic Activity by Site-Directed Mutagenesis

  • Lee Sang-Kil;Park Je-Won;Park Sung-Ryeol;Ahn Jong-Seog;Choi Cha-Yong;Yoon Yeo-Joon
    • Journal of Microbiology and Biotechnology
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    • v.16 no.6
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    • pp.974-978
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    • 2006
  • The cytochrome P450 monooxygenase from the pikromycin biosynthetic gene cluster in Streptomyces venezuelae, known as PikC, was observed to hydroxylate the unnatural substrate indole to indigo. Furthermore, the site-directed mutagenesis of PikC monooxygenase led to the mutant enzyme F171Q, in which Phe171 was altered to Gln, with enhanced activity for the hydroxylation of indole. From enzyme kinetic studies, F171Q showed an approximately five-fold higher catalytic efficiency compared with the wild-type PikC. Therefore, these results demonstrate the promising application of P450s originating from Streptomyces, normally involved in polyketide biosynthesis, to generate a diverse array of other industrially useful compounds.

A Classification of Luxury Fashion Brands' E-commerce Sites

  • Kim, Sunghee
    • Journal of Fashion Business
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    • v.17 no.6
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    • pp.125-140
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    • 2013
  • The aim of this study was to analyze e-commerce sites of luxury fashion brands in order to provide insights on how to enhance online site quality. For the research, forty-eight components of thirty-one luxury fashion brands' e-commerce sites were investigated during October 2013. For the analysis of clustering e-commerce site components and segmenting e-commerce sites of luxury brands, a hierarchical cluster analysis was applied through using the Ward's method and squared Euclidian distance for binary data. Further, Fisher's exact test was applied in order to distinguish three groups of characteristics in the luxury e-commerce sites. These analyses were carried out by SPSS 21. The result indicated that the components of e-commerce sites were grouped into three categories: basic elements, additional elements and elements of building brand identity. These components were categorized by whether their functions were basic and essential or additional and advanced. The other norm of categorization was related to brand identity. Furthermore, the luxury brands' e-commerce sites were segmented into three groups: a group of endeavoring to promote goods, a group of undistinguished performance, and a group of endeavoring to intensify brand identity. In this segmentation, brand identity or promotional aspects were decisive. Overall, luxury brands were trying to convey their traditional strength through their e-commerce sites. In order to achieve this purpose, brand identity or promotional aspects played an important role.