• Title/Summary/Keyword: Clean Gas

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Large-Scale PSA Process for Hydrogen Separation from Gas Mixture (혼합가스에서 수소분리를 위한 애용량 PSA공정)

  • Choi, Dae-Ki;Jin, Yin-Zhe;Kang, Seok-Hyun;Row, Kyung-Ho
    • Journal of Hydrogen and New Energy
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    • v.17 no.1
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    • pp.8-20
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    • 2006
  • For large scale separation hydrogen from different mixing ratio(60/40 and 80/20 vol.%) of hydrogen and methane $1Nm^3/hr$ and $4Nm^3/hr$ 2bed-6step pressure swing adsorption(PSA) process was used, respectively. The effects of the feed gas pressure, adsorption time, the feed flow rate and the P/F(purge to feed) ratio on the process performance were evaluated. In the $1Nm^3/hr$ PSA results, 11 atm adsorption pressure and 0.10 P/F ratio might be optimal values to obtain more than 75 % recovery and 99 % purity hydrogen in these processing. The optimum feed flowrate was 22 LPM and 17 LPM in the ratio 60/40 and 80/20, respectively. In the $4Nm^3/hr$ PSA results, 10 atm adsorption pressure might be simulated values to obtain more than 80 % recovery and 99 % purity hydrogen in these processing.

Analysis of Residual Nuarimol in Apples (사과 중 Nuarimol의 잔류성 분석)

  • Kim, Il Kwang;Han, Seong Soo;Kim, Youn Geun;Kim, Hea Jin
    • Analytical Science and Technology
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    • v.6 no.3
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    • pp.283-288
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    • 1993
  • The solvent extraction and clean up processes for the gas chromatographic determination of muarimol pesticide residues in apples were investigated and examined the changes of residual concentration with the passage of time. The extracted pesticide with methanol were partitioned with dichloromethane after adding sodium chloride solution. The separated solutions were concentrated and transfered to the alumina column for clean up, and eluated with 1-chlorobutane : methanol solution. As a results their recovering for 0.200 and 1.00ppm muarimol spiked on apples have shown 79~95%. Residual amounts of nuarimol in apple was 0.0830ppm when the fungicide was treated eight times until 3 days before its harvest. It seems to be safely used when nuarimol is treated six times until 7 days before harvest of apple.

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Operation Characteristics of Coal Syngas Production and DME Conversion Facilities (석탄 합성가스 제조 및 화학원료(DME) 전환설비의 운전 특성)

  • Chung, Seok-Woo;Kim, Mun-Hyun;Lee, Seung-Jong;Yun, Yong-Seung
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.83-86
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    • 2006
  • In this study, the syngas producing facility that consists of pulverized coal feeding/gasification and hot gas clean-up system was tested for Indonesian subbituminous coal. And the DME conversion facilities have been developed and tested for converting syngas to DME by reactions with catalysts. So, the entrained-bed slagging type pi lot scale coal gasifier was operated normally in the temperature range of $1,400{\sim}1,450^{\circ}C,\;7{\sim}8kg/cm^2$ pressure. And Roto middle coal produced syngas that has a composition of $36{\sim}38%$ CO, $14{\sim}16%\;H_2,\;and\;5{\sim}8%\;CO_2$. Particulates in syngas were 99.8% removed by metal filters. $H_2S$ composition in syngas was also desulfurized by the Fe chelate system to yield less than 0.1 ppm level. When the clean syngas $70{\sim}100 Nm^3/h$ was provided to DME conversion rector, normally operated in the temperature range of $230{\sim}250^{\circ}C$ and $60kg/cm^2$ pressure, 4.5% DME was yielded.

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Influence of partial accommodation coefficients on the aerodynamic parameters of an airfoil in hypersonic, rarefied flow

  • Zuppardi, Gennaro
    • Advances in aircraft and spacecraft science
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    • v.2 no.4
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    • pp.427-443
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    • 2015
  • The present paper is the follow-on of a former work in which the influence of the gas-surface interaction models was evaluated on the aerodynamic coefficients of an aero-space-plane and on a section of its wing. The models by Maxwell and by Cercignani-Lampis-Lord were compared by means of Direct Simulation Monte Carlo (DSMC) codes. In that paper the diffusive, fully accommodated, semi-specular and specular accommodation coefficients were considered. The results pointed out that the influence of the interaction models, considering the above mentioned accommodation coefficients, is pretty strong while the Cercignani-Lampis-Lord and the Maxwell models are practically equivalent. In the present paper, the comparison of the same models is carried out considering the dependence of the accommodation coefficients on the angle of incidence (or partial accommodation coefficients). More specifically, the normal and the tangential momentum partial accommodation coefficients, obtained experimentally by Knetchel and Pitts, have been implemented. Computer tests on a NACA-0012 airfoil have been carried out by the DSMC code DS2V-64 bits. The airfoil, of 2 m chord, has been tested both in clean and flapped configurations. The simulated conditions were those at an altitude of 100 km where the airfoil is in transitional regime. The results confirmed that the two interaction models are practically equivalent and verified that the use of the Knetchel and Pitts coefficients involves results very close to those computed considering a diffusive, fully accommodated interaction both in clean and flapped configurations.

Effect of channel hight on Bubble growth under Saturated Nucleate Pool Boiling for Various Channel Height using Heater with Artificial Cavity (인공 캐비티를 가진 히터를 이용한 가열면의 채널 높이가 풀비등시 기포성장에 미치는 영향에 대한 기초연구)

  • Kim, Jeong-Bae;Park, Moon-Hee;Jeon, Woo-Cheol
    • Journal of the Korean Solar Energy Society
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    • v.30 no.5
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    • pp.93-99
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    • 2010
  • Nucleate pool boiling experiments with constant heat flux condition were performed using pure R113 for various channel heights under saturated pool condition. A circular heater of 1mm diameter, with artificial cavity in the center, fabricated using MEMS technique and the high-speed controller were used to maintain the constant heat flux. Images of bubble growth were taken at 5,000 frames per second using a high-speed CCD camera. The bubble geometry was obtained from the captured bubble images. The effects of channel height on the bubble growth behaviors were analyzed as dimensional scales for the initial and thermal growth regions. The parameters for the bubble growth behaviors were bubble radius, bubble growth rate, and bubble shapes. These phenomena require further analysis for various surface angles, but this study will provide good experimental data with constant heat flux boundary condition for such works.

SO2 Removal by Internal Circulation of de-SOx Absorbents (흡수제 내부순환형 탈황장치의 SO2 제거성능 특성)

  • Park, Young-Ok;Park, Hyun-Jin;Kim, Yong-Ha
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.6
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    • pp.672-680
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    • 2011
  • Three new granular absorbents were prepared from calcium hydroxide, and applied to an FGD process with internal circulation. The aim of the study was finding the most efficient of the these three applied absorbents for the $SO_2$ removal at high flue gas temperatures. The absorbent is fed to the testing unit at high operation temperature and fluidized inside the FGD system where the sorbent particles react with the $SO_2$ gas. The rate of $SO_2$ decomposition was high in C-type absorbent which had the large surface area. De-SOx characteristics of the current absorbents appeared to be similar to the other conventional agents in this fluidized bed combustor. In particular, the optimum de-SOx condition could be achieved at high mole ratios of Ca to S which can reduce the residual $SO_2$.

Low Temperature Tensile Properties of High Temperature Gas-nitrided Duplex Stainless Steel

  • On, Han-Yong;Kong, Jung-Hyun;Kim, Mi-Jeong;Park, Sang-Joon;Kang, Chang-Yong;Sung, Jang-Hyun
    • Journal of the Korean Society for Heat Treatment
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    • v.23 no.5
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    • pp.263-268
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    • 2010
  • This investigation was focused on the low temperature tensile properties, phase change, changes in nitrogen content and corrosion resistance in the 22Cr-5Ni-3Mo duplex stainless steel after high temperature gas nitriding and solution annealing (HTGN-SA). From the HTGN-SA treatment, the duplex (ferrite + austenite) phase changed into austenite single phase. The nitrogen content of austenite single-phase steel showed a value of ~0.54%. For the HTGN-SA treated austenitic steel, tensile strength increased with lowering test temperature, on the other hand elongation showed the maximum value of 28.2% at $-100^{\circ}C$. The strain-induced martensitic transformation gave rise to lead the maximum elongation. After HTGN-SA treatment, corrosion resistance of the austenite single-phase steel increased remarkably compared with HTGN- treated steel.

A Study of Benzene Desorption Characteristics Using Steam on Activated Carbon (벤젠이 흡착된 활성탄의 수증기에 의한 탈착특성 연구)

  • Kwon, Jun Ho;Min, Byong Hoon;Suh, Sung-Sup
    • Clean Technology
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    • v.12 no.4
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    • pp.217-223
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    • 2006
  • The operating variables of a desorption step were experimentally investigated tor the cycle of the process made up of benzene adsorption, steam desorption, and drying step. The effect of adsorbent regeneration depending on existence and nonexistence of drying step was studied by breakthrough curves obtained in the adsorption step of the second cycle. The duration of drying step was determined by the experimental results. In case that the amount of nitrogen gas was fixed, the regeneration efficiency increased with the amount of steam. However, the effect of steam decreased as the amount of nitrogen increased. Therefore, it would be possible to predict the optimum amount of steam comparing the amount of nitrogen gas with amount of steam in economic view.

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Comparisons of Environmental Characteristics between Diesel and Dimethyl Ether as Fuels (디젤과 디메틸에테르의 연료로서의 환경적 특성 비교)

  • Han, Soon-Rye;Chung, Yon-Soo
    • Clean Technology
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    • v.14 no.2
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    • pp.144-151
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    • 2008
  • Life cycle assessment was carried out to evaluate the environmental values of dimethylas a diesel alternative fuel with the assumption of dimethyl ether production from natural gas via synthesis gas. The whole life cycles from raw material acquisitions to the final usages of diesel and dimethyl ether were involved in the assessment. Inventory analysis showed that the most significant environmental impacts came from resource depletions and air emissions. Impact assessment revealed that dimethyl ether was environmentally better in the aspect of human health and ecosystem quality but worse in resource depletions compared with diesel fuel. Suggestions for environmental improvement of dimethyl ether as a diesel alternative fuel were prepared based on the assessment results.

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Development of PSA Process for Medical Oxygen Generator (의료용 산소발생기 제작을 위한 PSA 공정의 개발)

  • Choi, Jae-Wook;Na, Byung-Ki
    • Clean Technology
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    • v.15 no.2
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    • pp.75-80
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    • 2009
  • In order to separate oxygen from air, the effects of feed gas flow rate and rinse gas flow rate on the product purity and flow were examined using 2 bed PSA with 4 step cycle. The addition of product pressurization step increased the product purity and flow rate. The addition of pressure equalization increased the product flow rate. The test product was manufactured and the purity and flow rate of product oxygen was examined. The results were compared with the commercial medical oxygen generator of 5 ${\ell}/min$ and 90% oxygen purity.