• Journal of the Korean Chemical Society
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• v.10 no.2
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• pp.67-75
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• 1966

Four kinds of clays from Sinyewon mine which is located in Chungchoungnam-Do district and two kinds of Japanese clays (Gairome, Kibushi) were selected and studied on the fundamental properties of these clays and those which are refined by the elutriation method. Chemical analysis, grading analysis such as refractoriness, specific gravity, color, fired color and plasticity, particle size distribution, various thermal tests, X-ray diffraction analysis and electron microscopic survey were carried out on these clays. The comparison of domestic clays with Japanese clays was made. 1. In chemical composition and physical properties, these four kinds of Sinyewon clays are almost similar to each other and also to Gairome and Kibushi clays. In refractoriness, Gairome and Kibushi clays have relatively high value such as SK 34 and 35, while Sinyewon clays have the value of about SK 32. Especially Sinyewon clay B has the low refractoriness (SK 18) and plasticity. Refined clays have the tendency of somewhat higher value than crude ones in refractoriness. 2. When burnt up to $900^{\circ}C$, the coefficients of contraction of Sinyewon clays were under 1.5%, Gairome under 1.3%, Kibushi under 3.0%. Only Sinyewon clay B showed expansion (1.0%) instead of contraction. 3. X-ray diffraction analysis and electron micrography showed that all of four Sinyewon clays and two Japanese clays are mainly composed of poorly crystallized kaolin, containing small amount of halloysite, sericite and considerable amount of quartz and feldspar. Sinyewon clay B contains especially large amount of quartz and feldspar. In general, it has been found out that the refined clays were free from large amount of iron oxide, quartz and feldspar.

• Geomechanics and Engineering
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• v.7 no.2
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• pp.213-231
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• 2014

An elastoplastic model for structured clays, which is formulated based on the fact that the difference in mechanical behavior of structured and reconstituted clays is caused by the change of fabric in the post-yield deformation range, is present in this paper. This model is developed from an elastoplastic model for overconsolidated reconstituted clays, by considering that the variation in the yield surface of structured clays is similar to that of overconsolidated reconstituted clays. However, in order to describe the mechanical behavior of structured clays with precision, the model takes the bonding and parabolic strength envelope into consideration. Compared with the Cam-clay model, only two new parameters are required in the model for structured clays, which can be determined from isotropic compression and triaxial shear tests at different confining pressures. The comparison of model predictions and results of drained and undrained triaxial shear tests on four different marine clays shows that the model can capture reasonable well the strength and deformation characteristics of structured clays, including negative and positive dilatancy, strain-hardening and softening during shearing.

• Geomechanics and Engineering
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• v.18 no.2
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• pp.121-131
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• 2019

This article discusses the phenomenon of plastic volumetric deformation of naturally structured clays before virgin yielding, i.e., subyielding behavior. A simple approach representing both the compression and shear responses of the clays during subyielding is demonstrated. A new compression model for structured clays based on the theoretical framework of the Structured Cam Clay (SCC) model via incorporation of the subyielding behavior is presented. Two stress surfaces are introduced to distinguish the subyielding and virgin yielding. The hardening and destructuring processes of structured clays under isotropic compression and shear are the focus of this work. The simulations of the compression and shear of eleven natural clays are studied for validation. The proposed work can accurately predict the subyielding behavior of structured clays both qualitatively and quantitatively and can be used for modeling structured clays under compression and shear responses in geological and geotechnical engineering problems.

• Geomechanics and Engineering
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• v.23 no.6
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• pp.561-573
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• 2020

The creep and consolidation behaviors of clays subjected to thermal cycles are of fundamental importance in the application of energy geostructures. This study aims to numerically investigate the physical mechanisms for the temperature-triggered volume change of saturated clays. A recently developed thermodynamic framework is used to derive the thermo-mechanical constitutive model for clays. Based on the model, a fully coupled thermo-hydro-mechanical (THM) finite element (FE) code is developed. Comparison with experimental observations shows that the proposed FE code can well reproduce the irreversible thermal contraction of normally consolidated and lightly overconsolidated clays, as well as the thermal expansion of heavily overconsolidated clays under drained heating. Simulations reveal that excess pore pressure may accumulate in clay samples under triaxial drained conditions due to low permeability and high heating rate, resulting in thermally induced primary consolidation. Results show that four major mechanisms contribute to the thermal volume change of clays: (i) the principle of thermal expansion, (ii) the decrease of effective stress due to the accumulation of excess pore pressure, (iii) the thermal creep, and (iv) the thermally induced primary consolidation. The former two mechanisms mainly contribute to the thermal expansion of heavily overconsolidated clays, whereas the latter two contribute to the noticeable thermal contraction of normally consolidated and lightly overconsolidated clays. Consideration of the four physical mechanisms is important for the settlement prediction of energy geostructures, especially in soft soils.

• Proceedings of the Korean Geotechical Society Conference
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• 2000.11a
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• pp.361-368
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• 2000

In other to examine the compressibility characteristics of cohesive soils in the mouth of the Nakdong river, the oedometer tests were peformed on undisturbed and reconstituted samples obtained by continuous boring typically at 3 different sites. It is meaningful to compare the consolidation behavior of natural clays with a reference state because the natural clays are depending on the stress history, sedimentary environment and geological history. In this study, the insitu state of the Pusan clays was investigated using the concepts of ISL(Nagaraj, 2000) and ICL and SCL(Burland, 1990). And for the purpose of confirming the existence of the underconsolidated clays, a standpipe type piezometer test and a dissipation test by piezocone were performed at their sites. Consequently, the Pusan clays were evaluated as normally consolidated clays.

• Journal of Environmental Health Sciences
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• v.27 no.2
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• pp.138-144
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• 2001

This study was carried out to investigate characteristics and Pb(II) removal effect of natural clays in the batch mode test. The effect of parameters such as temperature, adsorption time and coexisting cations on the sorption ability and characteristics was investigated to find out whether the clays could be used as adsorbents. Several natural clays from domestic have been investigated to have high specific surface area and have minerals such as SiO$_2$ and $Al_2$O$_3$. As a result, removal effects of Pb(II) on clays were reached at equilibrium in aqueous solutions by stirring about 20 minutes. The removal effect of Pb(II) was best for Kang Jin clay than other clays in terms of fixed time. Adsorption efficiency was not influenced by the possibility of continuous treatment system of wastewater which contain heavy metals by using natural clays from domestic.

• Economic and Environmental Geology
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• v.28 no.1
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• pp.1-8
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• 1995

The smectite-rich clays were found locally in Paleozoic calcareous sedimentary rocks in the Samcheok area. Their occurrences were investigated in detail, and the physico-chemical properties of the clays were also determined by X-ray diffraction, chemical analysis, thermal analysis and cation exchanging experiment. The smectite clays occur as the fissure filling dyke developed in calcareous sedimentary rock and as alteration products of intrusive rhyolite. Most of clays occur at the contact between the sedimentary rock and the rhyolite, and the alteration zone was observed only in rhyolite body close to the contact. Judging from their occurrences, it is believed that the smectite-rich clays in this area were formed by the hydrothemal alteration. The smectite clays from the area are mainly composed of Ca-montmorillonite, and associated with small quantities of quartz, opal-CT and feldspar. The montmorillonites from this area are lower in Fe content, and higher in exchangeable Ca ion, compared to those of bentonite from the Yangnam-Yeongil area.

• Proceedings of the Korean Geotechical Society Conference
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• 2003.03a
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• pp.341-348
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• 2003

In the estuary of Nagdong River thick marine sediments were deposited by the Holocene marine transgression. The sediments largely consist of silty clay, which is called Pusan clays in the geotechnical field. This paper presents engineering geological characteristics of Pusan clays in Beombangdong area. Overall geological environmental changes based on several geological properties are discussed and synthesized as Geological Environmental Zones. And also, engineering properties of the clays in laboratory and field are discussed and synthesized as Engineering Zones. Two zones are correlated and engineering characteristics are evaluated in view of engineering geology.

• Geomechanics and Engineering
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• v.4 no.4
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• pp.243-249
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• 2012

In the companion paper, the nonlinear consolidation of soft clays subjected to cyclic loading was analytically investigated. This paper reports the results of an experimental program conducted to verify some critical assumptions made in the analytical study. It, also, includes a numerical study carried out to examine the capability of the proposed theory to determine the consolidation characteristics of soft clays subjected to cyclic loading. Results show that the permeability of the soft clays does not significantly change during the cyclic loading. It is also shown that, compared to the Terzaghi's solution for a linear clay, the inherit nonlinearity of the clay tends to decrease the degree of consolidation due to the smaller rate of dissipation in the excess pore water pressure.

• Journal of the Korean Applied Science and Technology
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• v.21 no.2
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• pp.124-131
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• 2004

The adsorption of heavy metals in the waste water carried out on the various domestic clays and waste pottery. The effect of parameters such as pH, temperature, adsorption time and coexisting cations on the adsorption ability and characteristics were investigated to find out whether the clays could be used as adsorbents. Adsorption equilibrium was reached within 20 minutes on all the clays. The optimum pH was found to be above 5. When other cations such as Cu(II) or Zn(II) coexisted with Pb(II), the adsorption amount of Pb(II) decreased because of competing adsorption.