• Journal of the Korean earth science society
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• v.36 no.3
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• pp.222-235
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• 2015

Samples were collected from both places including the coastal area within the height of 5 m above the mean sea level (msl) (DH) and the top of the coastal terrace of 10-15 m msl (KS) high in Gwangseungri, Gochanggun, Korea. To find the origin of the deposit in the coastal area, granulometric analysis and geochemical analysis were performed. The result showed that the DH samples were originated from the reddish soils overlaying weathered bedrock which presented gradual change of chemical composition from the bottom toward the top. Clay minerals were found from the DH samples. These results concluded that the DH samples were found as in-situ weathered materials. The KS samples were originated from the soil layer covering gravel layer at the foot slope of the hill along the coast. The KS samples contained different chemical compositions from the DH. It is inferred that some of this layer was disturbed or experienced the influx of foreign material. The particle size of the KS samples was different from those found on the beach. The particle size of lower parts of KS site was finer than that on the beach, but the particle size of middle part of the site was coarser than that on the beach. The sorting of the KS site was poorer than that on the beach. Thus, it is inferred that some parts of the layer were formed by short-lived high energy event rather than sustained and continuous action of tidal currents and/or waves. Analysis using an optically stimulated luminescence (OSL) method showed that the burial age of samples from KS site were found 0.65-0.71 ka. Though the characteristics of the sediment layer and forming event in this area should be further studied, it can be inferred that this sedimentary layer formed by coastal flooding with storm.

• The Journal of Engineering Geology
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• v.27 no.1
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• pp.67-79
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• 2017

Evaluation of the weathering index using the quantitative element composition of rocks is very effective in predicting the degree of weathering of rocks and the secondary weathering residuals. While the process of weathering varies according to the types of rocks, the study of weathering in Korea is concentrated on acidic igneous rocks. This study calculated the weathering indices using whole rock analysis (X-ray fluorescence analysis) of sandstone, mudstone, and shale belonging to clastic sedimentary rocks. The statistical significance of the indices was examined based on the correlation of the calculated weathering indices. Clastic sedimentary rocks showed higher significance of Wp, CIA, CIW and PIA weathering index indicating weathering of feldspar. Chemical Index of alteration (CIA) has the advantage of predicting weathering pathway and clay mineral production, but it is effective to consider chemical index of weathering index (CIW) simultaneously to improve accuracy. In order to reduce uncertainties due to carbonate rocks and to estimate the accurate weathering index, rock samples with high CaO content should be excluded from the evaluation of weathering index.

• Economic and Environmental Geology
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• v.32 no.4
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• pp.385-398
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• 1999

The Narim gold mine is located approimately 200km southeast of Seoul within the Muju mineralized district of the Sobaegsan gneiss complex, Korea. Environmental geochemistry were undertaken for various kinds of water (surface, ground and mine water) collected of April, September and November in 1998 from the narim mine creek. Hydrogeochemical compositions of water samples are characterized by the relatively significant enrichment of Na+K, alkali ions, $HCO_{3}$, $NO_{3}$, Cl and F in groundwater, wheras the mine and surface waters are relatively enriched in Ca+Mg, hea표 metals and $SO_{4}$. Therefore, the groundwaters belong to the (Na+Ca)-( $HCO_{3}+SO_{4}$) type, respectively. The pH and EC values of the non-mining creek surfers are relatively lower compared with those of the surface water of the mine and ore dump area. The d values ($\delta$D-8$\delta^{18}$O) of all kinds of water from the Narim mine creek are 5.8 to 13.1 The range of $\delta$D and $\delta^{18}$O values (relative to SMOW) are shown in distinct two groups as follows: for the April waters of -64.8 to -67.8$\textperthousand$ and -9.6 to -10.0$\textperthousand$(d value=10.1 to 13.1), and for the November waters of -65.9 to -70.2$\textperthousand$ and -9.3 to -9.6$\textperthousand$ (d value=5.8 to 7.9), respectively. This range variation indicates that two group water were composed of distinct waters with seasonal difference. Geochemical modeling showed that mostly toxic metals (As, Fe, Mn, Ni, Pb, Zn) may exist largery in the from of metal $(M2^+)$ and metal-sulfate $(MSO_4\;^{2-$\mid$),\; and \;SO_4^{2-$\mid$}$ concentration influenced the speciation of heavy metals in the meteoric water. These metals in the groundwater could be formed of $CO_3 \;and \;(OH)_3$ complex ions. Using computer program, saturation index of albite, calcite, dolomite in meteoric water show undersaturated and progreddively evolved toward the saturation state, however, ground and mine water are nearly saturated. The gibbsited water-mineral reaction and stabilities suggest that the weathering of silicate minerals may be stable kaolinite, illite and Nasmectite. The clay minerals will be transformed to more stable kaolinite owing to the contiunous reaction.

• Journal of The Korean Society of Grassland and Forage Science
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• v.13 no.4
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• pp.238-250
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• 1993

Sixty two natural habitats of Korean lespedeza (Lespedeza stipulacea Maxim) were investigated to obtain basic data on the plant growth and the soil physico-chemical properties such as pH, mineral elements, organic matter content, soil separats and texture. Analyzed results can be summarized as follows. 1. Plant height and dry matter yield of the samples higher in late August and early September, although they varied greatly depending on the sampling date and location. 2. The plant shoot should higher contents of N, P, K. Ca and Mn than root and the plant root was higher in Mg, Fe, Cu, and Zn contents than shoot. 3. Soil pH and Ca content of the natural habitats were higher, but the contents of P$_2$O$_{5}$, K, Mg, Na and organic matter were lower than those of the average soil in Korea. The soil texture of natural habitats showed much higher portion of sand and extremely low portion of silt and clay 4. Korean lespedeza is well adapted to soils so low in fertility and organic matter that other crops and most weed fail. also it appears to thrive on the loamy sands, sandy loams of the piedmont region and on similar soils with variously physico-chemical properties.

• Journal of the Korean earth science society
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• v.34 no.4
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• pp.289-302
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• 2013

In order to determine the provenance of the Huksan Mud Belt sediments in the southeastern Yellow Sea, the major and rare earth elements of the same sediments were analyzed. The surface sediments were sampled from top of piston-cores and box-cores taken at 51 sites within the Huksan Mud Belt. With the mean grain size of $5-6{\phi}$, the sediments of the study area are mud-dominated. The spatial distribution patterns show that silt content is high in the northern Mud Belt, whereas clay content increases as it moves toward the southern Mud Belt. Interestingly, the geochemical compositions both of major and rare earth elements have resulted in differences of sediment provenance. Among the major elements, plots of Fe/Al vs. Mg/Al ratios, $Al_2O_3$ vs. MgO ratios, and $Al_2O_3$ vs. $K_2O$ reveal that the Huksan Mud Belt sediments are dominated by the Korean river-derived sediments. However, the characteristics of rare earth elements infer sediments originating from the Chinese rivers. This discrepancy between the above provenances is attributed to the different contributory factors in the content of chemical elements. Considering strong correlation between major elements with grain sizes, the contents of the major elements are thought to be influenced by the grain size. However, there is a weak correlation between rare earth elements and grain sizes. The behaviour of rare earth elements may be controlled by heavy minerals, rather than grain sizes. Further study requires to solve the discrepancy arose from the difference in applied chemical tracers.

• Economic and Environmental Geology
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• v.33 no.2
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• pp.91-100
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• 2000

It has been more than ten years since Dukun mine was abandoned. Tailings of waste deposits and slime dumps in the abandoned Dukum mine have been left to be deserted for fifty years. The results of fifty years of neglecting are nothing short of major environmental problems. Slime dumps have been exposed to air and water in the mine over ten years and then soil profile has been formed well. Soil in the upper layer (A horizon) is the light gray color due to the leaching of cations. Soil in the lower layer (A2 horizon, 0.2∼0.3m)is tinted with reddish brown and yellowish brown color due to the development of iron oxides and iron hydroxides. Soil in the lower part of B horizon of (1.0∼3.0m) with the growth of copper and zinc oxides exposes to the bluish green, light blue, and dark gray. Ranging from 3m to 8m in depth, 85 samples were taken from 22 sampling sites with 50m intervals located on the slime dump area with hand auger and trench (open cut). As tailings was distributed, heavy metal elements extracted by the process of surface water and ground water move and disperse in to the hydrosphere. Waste dumps were distributed in and around the mine and water draining from those dumps be a potential source of contamination. Soils, thus, can be dispersed into downslope and downstream through wind and water by clastic movement. These materials may be deposited in another horizon if the water is withdrawn, or if the materials are precipitated as a result of differences in pH, or other conditions in deeper horizons. These were primarily associated with acid mine drainage. The characteristics and rate of release of acid mine drainage are influenced by various chemical and biological reactions at the source of acid generations. Prolonged extration of heavy metal elements has a detrimental effect on the agricultural land and residental area. Twenty soil samples were collected from the agricultural land in the area (0∼30 cm). Seventeen samples were also taken from the sediment in the stream running alongside the dumps. The dispersion patterns of heavy metal elements are as follows: The content of As ranged 2∼6 ppm in a horizon, 20∼125 ppm in B horizon with large amount of clay mineral is concentrated and the content of Cd ranged 1∼2 ppm in A horizon, 4∼22 ppm in B horizon. Like Cd, the content of As, Cu, Zn, Pb in B horizon is higher than that in A horizon (approximately 5∼100 times). When soil formation proceeds in stages, it is necessary to investicate the B horizon with the concentration of heavy metal and preventive measures will have to established.

• Economic and Environmental Geology
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• v.31 no.4
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• pp.297-310
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• 1998

Geochemical characteristics of environmental toxic elements at the Narim mine area were investigated on the basis of major, minor, rare earth element geochemistry and mineralogy. Ratios of $Al_2O_3/Na_2O$ and $K_2O/Na_2O$ in soils and sediments range from 11.57 to 22.21 and from 1.86 to 3.93, and are partly negative and positive correlation against $SiO_2/Al_2O_3$ (3.41 to 4.78), respectively. These suggested that sediment source of host granitic gneiss could be due to rocks of high grade metamorphism originated by sedimentary rocks. Characteristics of some trace and rare earth elements of V/Ni (0.33 to 1.95), Ni/Co (2.00 to 6.50), Zr/Hf (11.27 to 53.10), La/Ce (0.44 to 0.55), Th/Yb (4.07 to 7.14), La/Th (2.35 to 3.93), $La_N/Yb_N$ (6.58 to 13.67), Co/Th (0.63 to 2.68), La/Sc (3.29 to 5.94) and Sc/Th (0.49 to 1.00) are revealed a narrow range and homogeneous compositions may be explained by simple source lithology. Major elements in all samples are enriched $Al_2O_3$, MgO, $TiO_2$ and LOI, especially $Fe_2O_3$ (mean=7.36 wt.%) in sediments than the composition of host granitic gneiss. The average enrichment indices of major and rare earth elements from the mining drainage are 2.05 and 2.91 of the sediments and are 2.02 and 2.60 of the soils, normalizing by composition of host granitic gneiss, respectively. Average composition (ppm) of minor and/or environmental toxic elements in sediments and soils are Ag=14 and 1, As=199 and 14, Cd=22 and 1, Cu=215 and 42, Pb=1770 and 65, Sb=18 and 3, Zn=3333 and 170, respectively, and extremely high concentrations are found in the subsurface sediments near the ore dump. Environmental toxic elements were strongly enriched in all samples, especially As, Cd, Cu, Pb, Sb and Zn. The level of enrichment was very severe in mining drainage sediments, while it was not so great in the soils. Based on the EPA value, enrichment index of toxic elements is 8.63 of mining drainage sediments and 0.54 of soils on the mining drainage. Mineral composition of soils and sediments near the mining area were partly variable being composed of quartz, mica, feldspar, amphibole, chlorite and clay minerals. From the gravity separated mineralogy, soils and sediments are composed of some pyrite, arsenopyrite, chalcopyrite, sphalerite, galena, goethite and various hydroxide minerals.

• The Journal of Engineering Geology
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• v.14 no.3 s.40
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• pp.259-272
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• 2004

The purpose of this study is to investigate the effect of hydrochemical variation of groundwater on the gas tigtness in an unlined oil storage cavern. The groundwater chemistry is greatly influenced by the seawater mixing, the water curtain and the dissolution of grounting cements. The chemical composition of groundwater greatly varies ac-cording to both the location of monitoring wells and the sampling period. Most of groundwater shows alkaline pH and high electrical conductivity. The chemical types of groundwater show the dominant order as follows : Na-Cl type > Ca-Cl type > $Ca-HCO_3(CO_3)$ type. Thermodynamic equilibrium state between chemical composition of groundwater and major minerals indicates that carbonate minerals except clay minerals can be precipitated as a secondary mineral. It means that the secondary precipitates can not greatly exerts the clogging effect into fracture aperture in rock mass around oil storage cavern. The content of total organic carbon (TOC) shows a slightly increasing trend from initial stage to late stage. The $EpCO_2$ was computed so as to assess the gas contribution on the $CO_2$ in groundwater. The $EpCO_2$ of 0$\~$41.3 indicates that the contribution of oil gas on $CO_2$ pressure in groundwater system can be neglected.

• The Journal of Engineering Geology
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• v.20 no.2
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• pp.191-202
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• 2010

In this study, the relationship between the settlements and the horizontal displacements according to embankment was analyzed at the marine sedimentary grounds for preparation of a site, and then the empirical equations of both the settlement and the horizontal displacement considering the embankment load and the thickness were proposed. To do this, the field and laboratory tests were performed at the improvement section where the pre-loading method was applied, and the field monitoring was performed using various sensors. Based on the results of the tests and monitoring, the ground deposits, soil characteristics and engineering properties were analyzed and the settlements and lateral movements were estimated by the Regression analysis. The ground deposits from the ground surface were composed of reclaimed soils, sedimentary soils and based rocks. The thickness of clay in the sedimentary soils layer was ranged from 3.9 m to 44.5 m. The embankment heights to improve the ground during pre-loading were constructed from 4.7 m to 7.8 m in each section. The settlements during embankment were ranged from 0.959 m to 2.217 m and the lateral movements were ranged from 0.048 m to 0.313 m. As the result of regression analysis, the equations of settlements and horizontal displacements according to embankments may be proposed as $s=0.02h^2+0.11h$ and ${\delta}=0.01e^{0.37h}$, respectively. The proposed empirical equations of the settlements and the horizontal displacements according to embankment on the marine sedimentary ground may be applied to the site where has a similar condition of study area.

• The Korean Journal of Pesticide Science
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• v.4 no.4
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• pp.56-60
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• 2000

A study was performed to determine the maintenance conditions of the earthworm, Lumbricus rubellus, for the acute toxicity test. To fine out climatic and soil conditions, the earthworms were maintained in artificial soil consisting of sand, clay mineral and peat at different levels of conditions for 14 days. Lumbricus rubellus led to an increase of biomass at temperature $22{\pm}2^{\circ}C$, soil pH $7.0{\pm}1$ and moisture 40%. And four fungicides were tested for acute toxicities to Lumbricus rubellus, according to the optimum condition. The test earthworms were exposed to each pesticide with various concentration gradients. After 14 days, the number of surviving earthworms and their weight alteration during the test period was determined. The 14-day $LC_{50}$ values for the Lumbricus rubellus, of carbendazim, benomyl, thiophanate-methyl and thiabendazole were determined to be 59, 53, 64 and 36 mg/ kg soil dry weight, respectively.