• Title/Summary/Keyword: Clay materials

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Mineralogical Characteristics and Origins of Smectite in the Marine Sediment around South Shetland Islands, Antarctica (남극 사우스셰틀란드 해양퇴적물내 스멕타이트의 광물학적 특성과 기원)

  • 정기영;윤호일
    • Journal of the Mineralogical Society of Korea
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    • v.15 no.1
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    • pp.22-32
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    • 2002
  • Mineral composition and chemistry of the clay minerals in the three cores from the continental shelves of South Shetland Islands (NCS09) and Anberse Island (GC98-2), and from the fjord of King George Island (A10-01) were determined by X-ray diffraction and electron microprobe analysis in search of the distributions and origin of the clay minerals in the Antarctic marine sediments. Smectite content is relatively high in NCS09 regardless of core depths (av. 8.3%), but low in GC98-2 (1.1%). In Al0-01, smectite content is higher in the upper section than in the lower section. Kaolinite was not detected from all the cores in this study Yellow to yellowish green clay granules were commonly scattered in the sediments of NCS09 cores. The clays contain 16.97% and 2.53% $Fe_2$$O_3$$K_2$O. Average structural formula of the clay indicates ferrian beidellite . The (Fe, K)-rich smectite of NSC09 must have been derived from relatively young basaltic volcanics altered by reaction with seawater near Shetland Islands by glacial erosion or eolian process related to volcanic eruption. GC98-2 nearer to Antarctic continent is very low in smectite content. In A10-01, the lower diamicton was deposited from the glacial erosion of smectite-free ancient volcanics in the interior of King George Island, while the upper section was derived from the smectite-bearing terrestrial debris and eolian materials after retreat of glaciers in Marian Cove and ice cover in Barton Peninsula. Thehigh K contents of smectites suggest the interstratification of illite and smectite layers, which might be observed by future TEM lattice fringe imaging.

A Study on the Effect of Organic Permeant on Permeability of a Natural Clay (유기투과물이 자연점토의 투수성에 미치는 영향에 대한 연구)

  • 전상옥;장병우;우철웅;박영곤
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.39 no.4
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    • pp.98-105
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    • 1997
  • Compacted clay materials are often used to form barriers for waste disposal by means of landfill. The performance of clay barrier depends on its permeability characteristics under the site environments. The study discusses permeability characteristics of 4 types of permeants through a compacted clayey soil. Permeabilities are measured using the modified rigid-wall permeater and with water, PEG, Ethanol, and TCE, ranging 80 to 3.4 of dielectric constants. Results of the study are as follows : 1) Absolute permeabilities of Ethanol and TCE that their dielectric constants are lower than that of water are $K=1.0{\times} 10^{-12} cm^2$, and $5.8{\times} 10^{-12} cm^2$, respectively, that is, 1.67, and 9.67 times of permeability of water, respectively. Absolute permeability and dielectric constant of water are $K=6{\times} 10^{-13} cm^2$, and 80, respectively. 2) Changes in absolute permeability of Ethanol and TCE converge to a constant after 3.5 pore volume of permeant flows through the clay sample. This can be explained that diffuse double layer of clay is no longer reacted with permeants and contracted their pores. However there is no change in absolute permeability when water is used as a per-meant. 3) It is found that absolute permeability in reversely proportional to the value of dielectric constant of the permeants. Change in absolute permeability of the permeants with 40 or over of dielectric constant is not significant. However change in absolute permeability of the permeant with 30 or lower dielectric constant is abruptly increased. 4) A lower absolute permeability of PEG is found because of its high viscosity.

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Compressibility Characteristics of the Lime Treated Clay (생석회 혼합토의 압축특성에 관한 연구)

  • 민덕기;황광모;오미희
    • Journal of the Korean Geotechnical Society
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    • v.19 no.6
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    • pp.23-29
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    • 2003
  • In this paper, effects of the acidification of ground and the chemical additive materials-ferric oxide, calcium chloride and calcium sulphate on the compressibility characteristics of the marine clay treated with quick lime were investigated. The rapid inflection point method was carried out. Results showed that the compression index of the untreated marine clay increased as the pH of pore water decreased. Also, the preconsolidation pressure, the coefficient of consolidation and the coefficient of permeability of the untreated marine clay decreased with pH of pore water. In the case of the marine clay treated with the quick lime-calcium chloride, the compression index decreased and the coefficient of consolidation and the coefficient of permeability increased. Specially, the preconsolidation pressure of sample treated with the quick lime-ferric oxide was higher than that of another samples.

Prediction of UCS and STS of Kaolin clay stabilized with supplementary cementitious material using ANN and MLR

  • Kumar, Arvind;Rupali, S.
    • Advances in Computational Design
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    • v.5 no.2
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    • pp.195-207
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    • 2020
  • The present study focuses on the application of artificial neural network (ANN) and Multiple linear Regression (MLR) analysis for developing a model to predict the unconfined compressive strength (UCS) and split tensile strength (STS) of the fiber reinforced clay stabilized with grass ash, fly ash and lime. Unconfined compressive strength and Split tensile strength are the nonlinear functions and becomes difficult for developing a predicting model. Artificial neural networks are the efficient tools for predicting models possessing non linearity and are used in the present study along with regression analysis for predicting both UCS and STS. The data required for the model was obtained by systematic experiments performed on only Kaolin clay, clay mixed with varying percentages of fly ash, grass ash, polypropylene fibers and lime as between 10-20%, 1-4%, 0-1.5% and 0-8% respectively. Further, the optimum values of the various stabilizing materials were determined from the experiments. The effect of stabilization is observed by performing compaction tests, split tensile tests and unconfined compression tests. ANN models are trained using the inputs and targets obtained from the experiments. Performance of ANN and Regression analysis is checked with statistical error of correlation coefficient (R) and both the methods predict the UCS and STS values quite well; but it is observed that ANN can predict both the values of UCS as well as STS simultaneously whereas MLR predicts the values separately. It is also observed that only STS values can be predicted efficiently by MLR.

Refinement of Low-grade Clay using Iron-reducing Bacteria [II] : Removal Characteristics of Iron Impurity from Various Porcelain Clays (철환원세균을 이용한 저품위 점토의 개량 [II] : 도자기 점토 종류별 철불순물 제거 특성)

  • 조경숙;류희옥
    • KSBB Journal
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    • v.15 no.2
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    • pp.208-213
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    • 2000
  • Using three types of porcelain clays such as White, Blue, and Yellow clays, which were used as raw materials for Bae씨a, C Chungja, and common porcelains, the biological refinement by an enrichment culture of iron reducing bacteria was studied. | In the biological clay refining, amounts of leached iron increased as increasing sucrose $\infty$ncentration, which was s supplemented as a carbon and electron donor source for cell growth and iron reduction. Total amounts of the leached iron a and specific rate of iron reduction were dependent on the types of the clay. Strength and chromaticity of refined clays which a are important properties required for porcelain clays were improved as increasing sucrose concentration. The degree of s shrinking, however, did not changed. the redness among the chromaticity of refined clays is favorably reduced through the r ripening by the iron reducing bacteria. Considering iron removal efficiency and the change of physical properties, the optimal c concentration of sucrose was 4%(w/w) in the clay.

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Synthesis and Characterization of Organo-modified Montmorillonite by Ion-exchange Method (유기물로 수식된 몬트모릴로나이트 제조 및 특성조사)

  • Kim, Jae-Myung;Yoo, Jung-Whan;Choi, Eui-Seok;Lee, Sung-Min;Kim, Hyung-Tae
    • Journal of the Korean Ceramic Society
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    • v.41 no.1
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    • pp.41-44
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    • 2004
  • Hydrophilicity and hydrophobicity of pottery bodies can be controlled via chemical substitution of layered clay with hydrophilic and hydrophobic organics. In this study, organo-clay nanocomposites were prepared by ion-exchange of montmorillonite with dodecylamine and hexadecylamine, respectively. Substitution sites of organics and the interval changes of layered materials are characterized by FT-IR and WAXD and organics amounts loaded and water comtents contained by C/S analysis and TG-DSC. The organics were selectively intercalated so that increase layer interval from 12${\AA}\; to\;16{\AA}$. Organo-modified clay is changed to more hydrophobic comparing to clay itself.

Paleo-red Soil on the High Fluvial Surface in the Middle Basin of Nam-Han River (남한강 중류 하성고위면의 고적색토)

  • Kang, Young-Pork;Lee, Sang-Min
    • Journal of the Korean earth science society
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    • v.26 no.8
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    • pp.828-835
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    • 2005
  • The purpose of this study is to clarify the landform development of fluvial terrace and the soil characteristics occurring on the terrace deposit. In order to achieve the purpose, the characteristics of soil profiles, the physic-chemical properties of soils that are developed on terrace deposits and X-ray diffraction analysis of clay were investigated. The horizon of Al in the high fluvial surface is silt clay loam of red (2YR 4/6). The soil structure is a developed granular structure. The horizon of B1 is silt clay reddish-brown (2.5YR 4/6). The soil structure is a medium subangular blocky structure. This red soil structure is made on heavy textured and compactly packed parent materials of high terrace sediments and usually has A-B-C profile. In most cases, clay accumulations in B-horizon and clay cutans on ped surfaces are observed, which mean the formation of agrillic horizon. As the result of this study, soils derived from fluvial terrace deposits on high fluvial surfaces are considered paleo-red soil which were developed by pedogenese-strong desilicification and rubefaction and strong leaching of bases- under warmer bio-climatic condition during in the old Pleistocene period.

Incorporation of water sludge, silica fume, and rice husk ash in brick making

  • Hegazy, Badr El-Din Ezzat;Fouad, Hanan Ahmed;Hassanain, Ahmed Mohammed
    • Advances in environmental research
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    • v.1 no.1
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    • pp.83-96
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    • 2012
  • The water sludge is generated from the treatment of water with alum. Disposing of sludge again to the streams raises the concentrations of aluminum oxides in water, which has been linked to Alzheimer's disease. The use of water treatment plant (WTP) sludge in manufacturing of constructional elements achieves both the economical and environmental benefits. Due to the similar mineralogical composition of clay and WTP sludge, this study investigated the complete substitution of brick clay by sludge incorporated with some of the agricultural and industrial wastes, such as rice husk ash (RHA) and silica fume (SF). Three different series of sludge to SF to RHA proportions by weight were tried, which were (25: 50: 25%), (50: 25: 25%), and (25: 25: 50%), respectively. Each brick series was fired at 900, 1000, 1100, and $1200^{\circ}C$. The physical and mechanical properties of the produced bricks were then determined and evaluated according to Egyptian Standard Specifications (E.S.S.) and compared to control clay-brick. From the obtained results, it was concluded that by operating at the temperature commonly practiced in the brick kiln, a mixture consists of 50% of sludge, 25% of SF, and 25% of RHA was the optimum materials proportions to produce brick from water sludge incorporated with SF and RHA. The produced bricks properties were obviously superior to the 100% clay control-brick and to those available in the Egyptian market.

Stabilization of oily contaminated clay soils using new materials: Micro and macro structural investigation

  • Ghiyas, Seyed Mohsen Roshan;Bagheripour, Mohammad Hosein
    • Geomechanics and Engineering
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    • v.20 no.3
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    • pp.207-220
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    • 2020
  • Clay soils have a big potential to become contaminated with the oil derivatives because they cover a vast area of the earth. The oil derivatives diffusion in the soil lead to soil contamination and changes the physical and mechanical properties of the soil specially clay soils. Soil stabilization by using new material is very important for geotechnical engineers in order to improve the engineering properties of the soil. The main subjects of this research are a- to investigate the effect of the cement and epoxy resin mixtures on the stabilization and on the mechanical parameters as well as the microstructural properties of clay soils contaminated with gasoline and kerosene, b- study on the phenomenon of clay concrete development. Practical engineering indexes such as Unconfined Compressive Strength (UCS), elastic modulus, toughness, elastic and plastic strains are all obtained during the course of experiments and are used to determine the optimum amount of additives (cement and epoxy resin) to reach a practical stabilization method. Microstructural tests were also conducted on the specimens to study the changes in the nature and texture of the soil. Results obtained indicated that by adding epoxy resin to the contaminated soil specimens, the strength and deformational properties are increased from 100 to 1500 times as that of original soils. Further, the UCS of some stabilized specimens reached 40 MPa which exceeded the strength of normal concrete. It is interesting to note that, in contrast to the normal concrete, the strength and deformational properties of such stabilized specimens (including UCS, toughness and strain at failure) are simultaneously increased which further indicate on suitability and applicability of the current stabilization method. It was also observed that increasing cement additive to the soil has negligible effect on the contaminated soils stabilized by epoxy resin. In addition, the epoxy resin showed a very good and satisfactory workability for the weakest and the most sensitive soils contaminated with oil derivatives.

IP Characteristics of Sand and Silt for Investigating the Alluvium Aquifer (충적대수층 조사를 위한 모래와 점토의 유도분극 특성 고찰)

  • Choi, Sang-Hyuk;Kim, Hyoung-Soo;Kim, Ji-Soo
    • The Journal of Engineering Geology
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    • v.18 no.4
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    • pp.423-431
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    • 2008
  • In general, water-saturated silt or clay alluvium is characterized with relatively low-resistivity. Thus we often encountered the problem that such a low-resistivity layer is misguided to be good aquifer of high-permeability and low-resistivity in the development of groundwater. This research was conducted with an emphasis on the identification of saturated silt or clay layer from the aquifer by performing the laboratory experiment of IP and resistivity methods on the various materials consisting of alluvium aquifer. Silt or clay layer is found to be characterized with the higher chargeability zone, compared to the sand layer. Regarding the mixture of sand and clay, the higher clay volume, the lower resistivity and the higher chargeability. Subsequently chargeability decreases.