• Title/Summary/Keyword: Clay materials

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Hygroscopic Characteristic of Gypsum Boards Using Porous Materials (다공성 원료를 사용한 석고보드의 흡습 특성)

  • Jeong, Eui-Jong;Lee, Jong-Kyu;Cheong, Deock-Soo;Chu, Yong-Sik;Song, Hun
    • Korean Journal of Materials Research
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    • v.19 no.10
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    • pp.538-543
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    • 2009
  • Active clays, Diatomite, bentonite and zeolite were used as porous materials for fabricating hygroscopic gypsum boards. Pohang active clay and Cheolwon diatomite showed excellent characteristics of moisture adsorption and desorption. These characteristics were caused by higher surface area and pore volume of porous materials. Moisture adsorption content of gypsum board with 10% active clay(P1) was 62.0 g/m$^2$, and moisture desorption content was 50.2 g/m$^2$. Moisture adsorption content of gypsum board with 10% diatomite(P) was 59.5 g/m$^2$, and moisture desorption content was 49.0 g/m$^2$. Moisture adsorption contents of gypsum boards with porous materials were higher than that moisture desorption contents of gypsum board without porous materials. Correlation coefficient between surface area and moisture adsorption content of gypsum boards was 0.98. Also, correlation coefficient between surface area and moisture desorption content of gypsum boards was 0.97. Moisture adsorption and desorption contents were influenced by surface area and pore volume of the gypsum boards, and surface area had a larger effect on moisture adsorption and desorption.

Hydrogeochemical Research on the Characteristic of Chemical Weathering in a Granitic Gatchment (水文化學的 資料를 통한 花崗岩質 流域의 化學的 風化特性에 關한 硏究)

  • Park, Soo-Jin
    • Journal of the Korean Geographical Society
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    • v.28 no.1
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    • pp.1-15
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    • 1993
  • This research aims to investigate some respects of chemical weathering processes, espcially the amount of solute leaching, formation of clay minerals, and the chemical weathering rate of granite rocks under present climatic conditions. For this purpose, I investigated geochemical mass balance in a small catchment and the mineralogical composition of weathered bedrocks including clay mineral assemblages at four res-pective sites along one slope. The geochemical mass blance for major elements of rock forming minerals was calculated from precipitation and streamwater data which are measured every week for one year. The study area is a climatically and litholo-gically homogeneous small catchment($3.62Km^2$)in Anyang-shi, Kyounggi-do, Korea. The be-drock of this area id Anyang Granite which is composed of coarse-giained, pink-colored miner-als. Main rock forming minerals are quartz, K-Feldspar, albite, and muscovite. One of the chracteristics of this granite rock is that its amount of Ca and Mg is much lower than other granite rock. The leaching pattern in the weathering profiles is in close reltion to the geochemical mass balance. Therefore the removal or accumulation of dissolved materials shows weathering patterns of granite in the Korean peninsula. Oversupplied ions into the drainage basin were $H^+$, $K^+$, Fe, and Mn, whereas $Na^2+$, $Mg^2+$, $Ca^2+$, Si, Al and $HCO-3^{-}$ were removed from the basin by the stream. The consumption of hydrogen ion in the catchment implies the hydrolysis of minerals. The surplus of $K^+$ reflects that vegetation is in the aggravation stage, and the nutrient cycle of the forest in study area did not reach a stable state. And it can be also presumed that the accumulation of $K^+$ in the top soil is related to the surplus of $K^+$. Oversupplied Fe and Mn were presumed to accumulate in soil by forming metallic oxide and hydroxide. In the opposite, the removal of $Na^+$, Si, Al resulted from the chemical weathering of albite and biotite, and the amount of removal of $Na^+$, Si, Al reflected the weathering rate of the bedrock. But $Ca^2+$ and $Mg^2+$ in stream water were contaminated by the scattered calcareous structures over the surface. Kaolinite is a stable clay mineral under the present environment by the thermodynamical analysis of the hydrogeochemical data and Tardy's Re value. But this result was quite different from the real assemblage of clay miner-als in soil and weathered bedrock. This differ-ence can be explained by the microenvironment in the weathering profile and the seasonal variation of climatic factors. There are different clay forming environments in the stydy area and these differences originate from the seasonal variation of climate, especially the flushing rate in the weathering profile. As it can be known from the results of the analysis of thermodynamic stability and characteristics of geochemical mas balance, the climate during winter and fall, when it is characterized by the low flushing rate and high solute influx, shows the environmental characteristics to from 2:1 clay minerals, such as illite, smectite, vermiculite and mixed layer clay minerals which are formed by neoformation or transformation from the primary or secondary minerals. During the summer and spring periods, kaoli-nite is a stable forming mineral. However it should consider that the other clay minerals can transformed into kaolinite or other clay minerals, because these periods have a high flushing rte and temperature. Materials which are directly regulated by chemical weathering in the weathered bedrock are $Na^+$, Si, and Al. The leaching of Al is, however, highly restricted and used to form a clay mineral, and that of Si falls under the same category. $Na^+$ is not taked up by growing veget ation, and fixed in the weathering profile by forming secondary minerals. Therefore the budget of $Na^+$ is a good indicator for the chemical weathering rate in the study area. The amount of chemical weathering of granite rocks was about 31.31g/$m^2+$/year based on $Na^+$ estimation.

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Characteristics of sound absorption materials by using ecological aggregates (에코골재를 사용한 흡음재의 특성)

  • Kim, Kang-Duk;Ryu, Yu-Gwang;Kim, Yoo-Taek
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.18 no.6
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    • pp.264-270
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    • 2008
  • Ecological lightweight aggregates were made by using the wastes come from various industrial fields. Wastes were crushed and pulverized by mills and a certain portions of wastes were mixed and formed by pelletizer like small beads. The formed lightweight aggregates were finally sintered with $1125^{\circ}C$/15 min conditions by using rotary kiln. Lightweight concrete sound absorbers were made of ecological lightweight aggregates K73 (Coal bottom ash 70 wt%: Dredged soil 30 wt%) and K631 (Clay 60 wt%: Stone sludge 30 wt%: Spent bleaching clay 10 wt%). For the reference, lightweight concrete sound absorbers made of DL (German made 'L' company LWA) were also made under the same conditions. Sound absorption characteristics were observed and measured according to the kinds of aggregates, water/cement ratio (W/C=20, 25, and 30%), and designed pore rates (V=20, 25, and 30%). The pore rates of the lightweight concrete sound absorber were turned out to be 5 to 10% higher than designed ones. Absorption coefficient of the lightweight concrete sound absorber by using K631 aggregates with W/C=20% and V=25% conditions was 0.88 at 1000 and 3150 Hz from the measurement by the impedance tube.

Formation Processes of Fault Gouges and their K-Ar Ages along the Dongnae Fault (동래단층 지역 단층비지의 생성과정과 K-Ar 연령)

  • 장태우;추창오
    • The Journal of Engineering Geology
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    • v.8 no.2
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    • pp.175-188
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    • 1998
  • This paper describes the internal structures and K-Ar ages of fault gouges collected from the Dongnae fault zone. This fault zone is internally zoned and occurs in the multiple fault cores. A fault core consists of thin gouge and narrow cataclastic zones that are bounded by a much thicker damage zone. Intensity of deformation and alteration increases from damage zone through cataclastic zone to gouge zone. It is thought that cataclasis of brittle deformation was the dominant strain-accomodation mechanism in the early stage of deformation to form the gouge zone and that crushed materials in the regions of maximum localization of fault slip subsequently moved by cataclastic flow. Deformation mechanism drastically changed from brittle processes to fluid-assisted flow along the gouge zone as the high porosity and permeability of pulverzied materials during faulting facilitated the influx of the hydrothermal fluids. Subsequently, the fluids reacted with gouge materials to form clay minerals. Fracturing and alteration could have repeatedly taken place in the gouge zone by elevated fluid pressures generated from the reduction of pore volume due to the formation of clay minerals and precipitation of other materials. XRD analysis revealed that the most common clay minerals of the gouge zones are illite and smectite with minor zeolite and kaolinite. Most of illites are composed of 1Md polytype, indicating the products of hydrothermal alteration. The major activities of the Dongnae fault can be divided into two periods based upon K-Ar age data of the fault gouges : 51.4∼57.5Ma and 40.3∼43.6Ma. Judging from the enviromental condition of clay mineral formation, it is inferred that the hydrothermal alteration of older period occured at higher temperature than that of younger period.

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Lightweight Aggregate Bloating Mechanism of Clay/Incinerated Ash/Additive System (점토/소각재/첨가제계 인공 경량골재의 발포기구)

  • Kwon, Yong-Joon;Kim, Yoo-Taek;Lee, Ki-Gang;Kim, Young-Jin;Kang, Seung-Gu;Kim, Jung-Hwan;Park, Myoung-Sik
    • Journal of the Korean Ceramic Society
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    • v.38 no.9
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    • pp.811-816
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    • 2001
  • The influence of the incinerated ash and additives on glass phase formation of lightweight aggregate, weight-lightening, and the bloating mechanism was investigated. Clay was used as base materials and incinerated ash was added from 0 to 30wt%. The additives such as $Na_2CO_3,\;CaCo_3,\;K_2CO_3,\;MgCO_3$, and a little amount of waste oil were added to the mixed body. In clay/incinerated ash/additive system, it turned out that $CaCO_3\;and\;MgCO_3$ were the components for glass phase formation and $Na_2CO_3$ was the component for both glass phase formation and weight-lightening. The small addition of waste oil from 0.5wt% to 3.0wt% affect on the bloating of aggregate. Incinerated ash had a good effect on the glass phase controlling. The most effective condition controlling glass phase and bloating of aggregate was 10wt% incinerated ash, 2wt% waste oil at 1200$^{\circ}$C. The bloating mechanism of lightweight aggregate is as follows; 1) micro-crack formation caused by thermal-shock and gas generation from inside of aggregate, 2) volume expansion by glass phase formation on the aggregate surface and rapid gas bloating inside of aggregate, 3) densification after bloating.

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The Fabrication of Artificial Fine Aggregates Using Stone Sludge and Spent Bleaching Clay

  • Kim, Kangduk
    • Journal of the Korean Ceramic Society
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    • v.51 no.5
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    • pp.492-497
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    • 2014
  • Artificial fine aggregates (denoted AFA) were fabricated using spent bleaching clay (denoted SBC) generated from processed vegetable oil and stone sludge (denoted SS) produced from crushed aggregate manufacturing materials for use as functional construction materials. Each raw material was crushed to particle size finer than $150{\mu}m$, and fine spherical pellets of approximately 1 ~ 4 mm in diameter were prepared by a pelletizing process. The physical properties of the AFA were measured with different types of sintering equipment. A new type of vertical furnace that sinters fine aggregates in a fluidized bed at high temperatures was designed and tested. AFA sintered in a rotary kiln at $1125^{\circ}C$ showed a bulk density of $1.5g/cm^3$ and a water absorption of 16%. AFA sintered in the vertical furnace at $1125^{\circ}C$ showed a bulk density of $1.9g/cm^3$ and water absorption of 8.5%. The bulk density of the AFA sintered in the vertical furnace showed a bulk density 27% higher and water absorption 47% lower than those of AFA sintered in the rotary kiln.

An Experimental Study on High Strength Lightweight Concrete Using Compound Materials (혼화재를 사용한 고강도 경량콘크리트에 관한 실험적 연구)

  • Kim, Jong-In;Choi, Young-Wha;Kim, Jeong-Hun
    • Journal of the Korean Society of Industry Convergence
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    • v.6 no.2
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    • pp.115-122
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    • 2003
  • This experimental study on high strength lightweight concrete using compound materials has been performed. In which, expanded clay was used as coarse aggregate, and silica fume and fly ash as admixtures varying by 0, 10% and 0, 5, 10, 15, 20% of cement amount respectively were added. Thus, the properties of fresh and hardened concrete have been investigated. The results of this study can be summarized as follows ; Each slump loss of mixtures replaced fly ash has been decreased by increasing replacement rate. The compressive strength have shown 465, 428 and $401kgf/cm^2$ at 30, 40 and 50% of W/B in 28days respectively, all of which have satisfied the criterion $270kgf/cm^2$ of high strength lightweight concrete. The unit volume weight of hardened concrete has been decreased by increasing replacement rate of silica fume and fly ash, values of which have satisfied the criterion $2000kgf/cm^3$of light weight concrete.

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The Development of Corrosion Standard System of Water and Wastewater in Soil Environment (상·하수도 배관재의 토양환경에서의 부식표준시스템 개발)

  • Park, Kyeong-Dong;Shin, Yeong-Jin;Lee, Ju-Yeong
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.5 no.4
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    • pp.7-12
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    • 2006
  • Galvanized steel pipe, copper pipe and stainless steel pipe, which is being used in waterworks piping materials. In case of galvanized steel pipe, the precipitation of a product is being generated due to the pollution of the tap water, a white water phenomenon, and various corrosion reaction because a zinc ion is melted by tap water. And in case of a cupper pipe, many problems which is harm in sanitation appeared because of a inflow of harmfulness substance by a frequent accident of a water leakage. So, to prevent these problems, it is substituted for stainless steel pipe. However, those problems is still occurring because of badness of welding, a problem of a water leakage in connection part, and a increment of construction expenses. Therefore, this research has examined the laying period according to each piping thickness and a corrosion shape according to each laying depth after laying in various soils(sandy loam, loamy, clay loam, clay) using galvanized steel pipe, copper pipe, and stainless steel pipe. That is, we has studied the data which is necessary for a rational method of preserving the quality of water by examining the corrosion properties of piping materials in the soil environment which waterworks piping materials is being used.

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New Bio-based Polymeric Materials from Plant Oils

  • Uyama, Hiroshi
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.359-359
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    • 2006
  • This study deals with development of new bio-based polymeric materials from epoxidized soybean oil (ESO). The curing of ESO in the presence of organophilic montmorillonite produced an oil polymer-clay nanocomposite ("green nanocomposite") showing flexible property. A green nanocomposite (oil polymer-silica nanocomposite) coatings were synthesized by an acidcatalyzed curing of ESO with 3-glycidoxypropyltrimethoxysilane. The curing of ESO in the presence of a biodegradable plastic, poly(caprolactone), produced a composite with semi-IPN structure. The mechanical properties of the composite was much superior to those of polyESO. These new oil-based materials have large potential for applications in various fields.

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Synthesis and Characterization of High Impact Polystyrene/Organically Modified Layered Silicate Nanocomposites (내충격성 폴리스티렌과 유기화 층상 실리케이트 나노복합체의 합성 및 특성)

  • 김관영;임효진;박상민;이성재
    • Polymer(Korea)
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    • v.27 no.4
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    • pp.377-384
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    • 2003
  • High impact polystyrene/organically modified layered silicate (HIPS/OLS) nanocomposites by in situ polymerization were synthesized to investigate the effect of clay on the particle size and properties of rubber. In the OLS, the montmorillonite having benzyl group showed best dispersion in polystyrene phase. With the addition of clay, the intercalated peak from XRB was confirmed, but the peak gradually shifted to lower angle as rubber concentration increased. Thus, it is speculated that the organoclay disperses better in rubber phase than in polystyrene phase. The average rubber particle size increased and the particle size distribution widened as the amount of clay increased, which may be caused by the increase of the viscosity ratio of rubber to polystyrene phases and the unstable dispersion. The materials having clay showed improved thermal properties from thermogravimetric analysis. Rheological properties such as complex viscosity and storage modulus increased as the amount of clay increased.