• 제목/요약/키워드: Class transition temperature

검색결과 26건 처리시간 0.022초

Extraordinary Magnetomechanical Coupling as a Result of a Combined Magnetic Structural Transition in a New Class of Rare Earth Compound

  • Jiles, D.C.;Lee, S.J.;Han, M.;Lo, C.C.H.;Snyder, J.E.;Gschneidner, K.A.;Pecharsky, V.K.;Pecharsky, A.O.;Lograsso, T.;Schlagel, D.
    • Journal of Magnetics
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    • 제8권1호
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    • pp.1-6
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    • 2003
  • The new class of $Gd_5(Si_xGe_{1-x})_4$ compounds undergoes a simultaneous magnetic/structural phase transition giving a high level of strain that can be induced either by change in temperature or by application of a magnetic field. Profound changes of structural, magnetic, and electronic changes occur in the $Gd_5(Si_xGe_{1-x})_4$ system lead to extreme behavior of the material such as the giant magnetocaloric effect, colossal magnetostriction, and giant magnetoresistance. These unique material characters can be utilized for various applications including magnetic solid refrigerants, sensors, and actuators.

154kV급 고온초전도 변압기용 부싱의 절연설계에 관한 연구 (Research on Insulation Design of the Bushing for a 154kV Class HTS Transformer)

  • 곽동순;천현권;최재형;김해종;윤문수;김영석;김상현
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.216-217
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    • 2006
  • A common problem in many fields of cryogenic power engineering is to apply high voltage to cold parts of superconducting equipment. In many of these cases a bushing provides electrical insulation for the conductor which makes the transition from ambient temperature to the cold environment. The cryogenic high voltage bushing for the 154kV, 100MVA high temperature superconducting(HTS) transformer is described. The bushing is energized with the line-to-ground voltage between the coaxial center and outer surrounding conductors, in the axial direction there is a temperature difference from ambient to about 77 K. For the insulation design of cryogenic bushing, the arrangement of condenser cone and electrical insulation characteristics of GFRP, Air, $LN_2$ and $GN_2$ were discussed in this paper.

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변형 LIGA 공정을 이용한 마이크로 렌즈 어레이 개발: 몰딩 및 모델링 (Formation of Microlens Array via a Modified LIGA Process: Molding and Modeling)

  • Kim, D. S.;Lee, H. S.;S. S. Yang;Lee, B.K.;Lee, S.K.;T. H. Kwon;Lee, S. S.
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2003년도 춘계학술대회논문집
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    • pp.465-469
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    • 2003
  • Microlens arrays were fabricated using a novel fabrication technology based on the exposure of a PMMA (Polymethylmethacrylate) sheet to deep X-rays and subsequent thermal treatment. X-ray irradiation causes the decrease of molecular weight of PMMA, which in turn decreases the glass transition temperature and consequently causes a net volume increase during the thermal cycle resulting in a swollen microlens. A new physical modeling and analyses for microlens formation were presented according to experimental procedure. A simple analysis based on the new model is found to be capable of predicting the shapes of microlens which depend on the thermal treatment. For the replication of microlens arrays having various diameters with different foci on the same surface, the hot embossing and the microinjection molding processes has been successfully utilized with a mold insert that is fabricated by Ni-electroplating based on a PMMA microstructure of microlenses. Fabricated microlenses showed good surface roughness with the order of 1 nm.

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레이저 유리 접합 공정의 유한요소해석 (Finite Element Analysis of Laser Class Bonding Process)

  • 홍석관;강정진;변철웅
    • 한국레이저가공학회지
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    • 제11권3호
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    • pp.10-15
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    • 2008
  • This study is aimed to analyse the laser glass bonding process numerically. Due to the viscoelastic behaviour of glass, the extremely large deformation of the frit seal is resulted continuously over the transition temperature, so that the thermal boundary condition be changed in the entire calculation process. The commercial FEM algorithm is restrictively able to remesh the large geometrical boundary shape and to adapt the boundary conditions simultaneously. According to our manual adaptation of increasing the laser line intensity to 700 mW/mm, it is possible to estimate the thermal glass bonding process under the fracture stress in principle. But it should be studied further in the case of high laser line intensity.

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Research on Powder Metallurgy Technology in Fusion Materials in China

  • Ge, Chang-Chun;Zhou, Zhang-Jian;Du, Juan;Song, Shu-Xiang
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.896-897
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    • 2006
  • In the viewpoint of engineering, materials problem is a key problem, which determines whether the exploitation of fusion energy will be success. The most important class of fusion materials is plasma-facing materials (PFM). W, as high Z high melting-point metal is one of the most important candidate materials due to its high plasma erosion resistance. Improving the ductility of W and W based alloy, lowering its ductile-brittleness transition temperature for meeting the requirements of fusion application is an important task. In this paper, severalpowder meatllurgy methods of fabricating W and W based materials are being investigated.

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에폭시/몬모릴로나이트 나노복합재료의 유전특성 평가 (Evaluation on Dielectric Properties of Epoxy/Montmorillonite Nanocomposites)

  • 장용균;김우년;김준경;박민;윤호규
    • 폴리머
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    • 제30권6호
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    • pp.492-497
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    • 2006
  • 에폭시/몬모릴로나이트(MMT) master batch의 혼합온도를 달리하여 복합재료를 제조하였으며, MMT의 박리에 의한 복합재료의 유전특성을 비교하였다. MMT 함량이 낮은 복합재료에서 MMT의 박리가 지배적으로 발생하였으며, 고함량의 MMT 복합재료에서는 master batch 제조온도가 증가할수록 MMT의 층간거리가 증가하였다. 박리가 지배적인 저함량의 MMT 복합재료에서는 적절한 후경화 조건에 의해 유리전이온도가 증가되는 것을 알 수 있었다. MMT의 박리가 효과적으로 발생한 복합재료에서는 에폭시 분자구조의 배향분극이 억제됨으로써 유전율과 유전손실이 감소하였으며, 에폭시/MMT master batch의 혼합온도 및 시간, 그리고 복합재료의 후경화 조건에 따라서 복합재료의 유전특성을 향상시킬 수 있었다.

Magnetic Semiconductors Thin Films-Unidirectional Anisotropy

  • Lubecka, M.;Maksymowicz, L.J.;Szymczak, R.;Powroznik, W.
    • Journal of Magnetics
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    • 제4권1호
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    • pp.33-37
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    • 1999
  • Unidirectional magnetic anisotropy field ($H_an$) was investigated for thin films of $CdCr{2-2x}In_{2X}Se_4 (0$\leq$x$\leq$0.2). This anisotropy originates from the microscopic anisotropic Dzyaloshinskii-Moriya (DM) interaction which arise from the spin-orbit scattering of the conduction electrons by the nonmagnetic impurities. This interaction maintains the remanent magnetization in the direction of the initial applied field. Then the single easy direction of the magnetization is parallel to the direction of the magnetic field. The anisotropy produced by field cooling is unidirectional I.e. the spins system deeps some memory of the cooling field direction. The chalcogenide spinel of$ CdCr_{2-2x}In){2X}Se_4$belongs to the class of the magnetic semiconductors. The magnetic disordered state is obtained when ferromagnetic structure is diluted by In. Then we have the mixed phase characterised by coexistence the magnetic long range ordering (IFN-infinite ferromagnetic network) and the spin glass order (Fc-finite clusters). The total magnetic anisotropy energy depends on the state of magnetic ordering. In our study we concentrated on the magnetic state with reentrant transition and spin glass state. The polycrystalline $ CdCr_{2-2x}In){2X}Se_4$ thin films were obtained by rf sputtering technique. We applied the ferromagnetic resonance (FMR) and M-H loop techniques for determining the temperature composition dependencies of Han. From the experimental data, we have found that Han decreases almost linearly when temperature is increased and in the low temperature is about three times bigger at SG state with comparison to the state with REE.

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Valorization of Pineapple Peel Waste for Sustainable Polyhydroxyalkanoates Production

  • Kannika Bunkaew;Kittiya Khongkool;Monthon Lertworapreecha;Kamontam Umsakul;Kumar Sudesh;Wankuson Chanasit
    • 한국미생물·생명공학회지
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    • 제51권3호
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    • pp.257-267
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    • 2023
  • The potential polyhydroxyalkanoates (PHA)-producing bacteria, Bacillus megaterium PP-10, was successfully isolated and studied its feasibility for utilization of pineapple peel waste (PPW) as a cheap carbon substrate. The PPW was pretreated with 1% (v/v) H2SO4 under steam sterilization and about 26.4 g/l of total reducing sugar (TRS) in pineapple peel hydrolysate (PPH) was generated and main fermentable sugars were glucose and fructose. A maximum cell growth and PHA concentration of 3.63 ± 0.07 g/l and 1.98 ± 0.09 g/l (about 54.58 ± 2.39%DCW) were received in only 12 h when grown in PPH. Interestingly, PHA productivity and biomass yield (Yx/s) in PPH was about 4 times and 1.5 times higher than in glucose. To achieve the highest DCW and PHA production, the optimal culture conditions e.g. carbon to nitrogen ratios of 40 mole/mole, incubation temperature at 35℃ and shaking speed of 200 rpm were performed and a maximum DCW up to 4.24 ± 0.04 g/l and PHA concentration of 2.68 ± 0.02 g/l (61% DCW) were obtained. The produced PHA was further examined its monomer composition and found to contain only 3-hydroxybutyrate (3HB). This finding corresponded with the presence of class IV PHA synthase gene. Finally, certain thermal properties of the produced PHA i.e. the melting temperature (Tm) and the glass transition temperature (Tg) were about 176℃ and -4℃, respectively whereas the Mw was about 1.07 KDa ; therefore, the newly isolated B. megaterium PP-10 is a promising bacterial candidate for the efficient conversion of low-cost PPH to PHA.

Anisotropy of the Electrical Conductivity of the Fayalite, Fe2SiO4, Investigated by Spin Dimer Analysis

  • Lee, Kee Hag;Lee, Jeeyoung;Dieckmann, Rudiger
    • Bulletin of the Korean Chemical Society
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    • 제34권2호
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    • pp.629-632
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    • 2013
  • Many properties of inorganic compounds are sensitive to changes in the point-defect concentrations. In minerals, such changes are influenced by temperature, pressure, and chemical impurities. Olivines form an important class of minerals and are magnesium-rich solid solutions consisting of the orthosilicates forsterite $Mg_2SiO_4$ and the fayalite $Fe_2SiO_4$. Orthosilicates have an orthorhombic crystal structure and exhibit anisotropic electronic and ionic transport properties. We examined the anisotropy of the electrical conductivity of $Fe_2SiO_4$ under the assumption that the electronic conduction in $Fe_2SiO_4$ occurs via a small polaron hopping mechanism. The anisotropic electrical conductivity is well explained by the electron transfer integrals obtained from the spin dimer analysis based on tight-binding calculations. The latter analysis is expected to provide insight into the anisotropic electrical conductivities of other magnetic insulators of transition metal oxides.

주사슬에 설폰기를 함유하는 전기발광 공액 고분자의 합성과 특성분석 (Synthesis and Characterization of Electroluminescent Conjugated Polymers Containing Sulfone Group in the Main Chain)

  • 강민성;정호국;박수영;김장주
    • 폴리머
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    • 제29권4호
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    • pp.357-362
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    • 2005
  • 중합체의 공액길이를 제어하고 이들이 갖는 에너지 준위를 조절하며, 발광성능향상과 발광파장을 조절하려는 목적으로 설폰기가 포함된 페닐렌-비닐렌계의 새로운 전기발광 고분자들을 Witting 중합을 통해 합성하였다. 합성된 고분자들은 일반 유기 용매에 좋은 용해성을 보였고 $400^{circ}C$ 정도의 초기분해온도와 $200^{circ}C$ 전후의 높은 유리전이온도를 가짐으로써 열적 안정성이 매우 높음을 확인하였다. 각각의 고분자는 용액과 필름상태에서 모두 설폰기의 꺾임에 의해 공액길이가 짧아질수록 UV 흡수와 발광 스펙트럼이 단파장으로 이동하였고 이를 통해 설폰기가 효율적으로 발광파장을 제어하는 것을 확인하였다. 또한 CV측정과 이론적인 계산을 통해 전자친화도가 큰 설폰기에 의해서 합성된 고분자들의 HOMO 및 LUMO 에너지 준위가 상대적으로 낮아짐으로써 소자의 전기발광특성이 향상됨을 확인하였다.