• Title/Summary/Keyword: Chun-Kwang

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Hydrogen Reduction Characteristics of Ni-based Mixed Oxides: TPR and XRD Study (니켈 기반 혼합 산화물의 수소 환원 특성: TPR 및 XRD 연구)

  • Ryu, Jae-Chun;Cha, Kwang-Seo;Lee, Dong-Hee;Lee, Young-Seak;Park, Chu-Sik;Kim, Young-Ho
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.2
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    • pp.89-97
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    • 2010
  • $Al_2O_3$, $TiO_2$, $ZrO_2$, $Al_2O_3-TiO_2$, $Al_2O_3-ZrO_2$, 및 $TiO_2-ZrO_2$ 혼합 산화물을 지지체로 한 Ni 기반 혼합 산화물을 졸-겔법으로 제조하였다. 제조된 혼합 산화물은 1173K에서 열처리 한 후 구조적 특성 변화를 전자현미경 및 X-선 회절 분석을 이용하여 관찰하였으며, 수소를 이용한 승온 환원(TPR; temperature-programmed reduction) 실험을 통하여 1173K 까지 각 시료들의 환원 피크를 비교 고찰하였다. $Al_2O_3$ 또는 $TiO_2$ 가 혼합된 시료의 경우 1173K 에서의 열처리 후 니켈 알루미네이트 또는 니켈 티타네이트와 같은 새로운 결정상의 생성이 관찰되었으나 $ZrO_2$가 혼합된 경우에는 새로운 결정상의 생성이 관찰되지 않았다. TPR 결과에 의하면, $Al_2O_3$ 또는 $TiO_2$를 혼합된 시료의 경우 벌크 NiO의 TPR 결과와는 달리 생성된 새로운 결정상에 기인한 여러 개의 환원 피크가 나타났으나 $ZrO_2$를 혼합한 경우 벌크 NiO와 비슷한 환원 피크를 보였다. TPR 결과를 기초로 Arrhenius plot 으로부터 각 혼합 산화물들의 수소 환원 활성화 에너지를 도출하였다. $ZrO_2$를 지지체로 사용하는 경우 다른 혼합 산화물들보다 지지체로서 안정한 혼합 산화물상을 형성한다는 것을 지시하듯이 상대적으로 가장 낮은 활성화 에너지를 나타냈다.

A Basic Study on the Development of Backfill Material with Fly Ash and Bottom Ash of Circulating Fluid Bed Combustion (순환유동층보일러의 Fly Ash, Bottom Ash를 활용한 채움재 개발에 관한 기초연구)

  • Cho, Yong-Kwang;Lee, Yong-Mu;Nam, Seong-Young;Kim, Chun-Sik;Seo, Shin-Seok;Jo, Sung-Hyun;Lee, Hyoung-Woo;Ahn, Ji-Whan
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.1
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    • pp.25-31
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    • 2018
  • In this study, the Controlled Low Strength Material (CLSM) was investigated to utilize the bottom ash and fly ash generated in the Circulating Fluidized Bed Combustor (CFBC). It was confirmed that the CFBC fly ash (CFBC-F) and CFBC bottom ash (CFBC-B) had an irregular particle shape through SEM measurement. According to the results of the hazard analysis, it was also confirmed that they were environmentally safe. In the case of mixing with CFBC-F, the unit quantity was increased. Regarding the rate of change of length, shrinkage in the range of -0.05~0.50% occurred in the air dry curing condition and expansion in the range of 0.1~0.6% in the sealed curing condition. Compressive strength was increased in the sealed curing condition compared to the air dry curing condition because there was enough moisture for hydration reaction in the long term. Therefore, the results of this study are likely be used as basic research data of mine filler materials.

Changes of Understory Vegetation Structure for 10 Years in Long-Term Ecological Research Site at Mt. Gyebang (계방산 장기생태조사지에서 10년간 하층식생구조변화)

  • Cheon, Kwang Il;Chun, Jung Hwa;Yang, Hee Mun;Lim, Jong Hwan;Shin, Joon Hwan
    • Journal of Korean Society of Forest Science
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    • v.103 no.1
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    • pp.1-11
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    • 2014
  • This study was conducted to investigate the changes understory vegetation composition (shrub and herb layers) in Mt. Gyebang as a northern-temperate deciduous broadleaf forest. Tracheophytes were 146 taxa, consisting 56 families, 93 genera, 124 species, 17 varieties, 3 forma, 2 sub-species and 1 unknown taxa in research subject area. As species area curve analysis, herbaceous layer and shrub species have been decreased over time. As a result of Mantel-test, basal area of upper layer affects to understory vegetation change (p<0.0001). Mean importance value was dominated Lindera obtusiloba (21.585%), Rhododendron schlippenbachii (19.774%) in the shrub layer, identified Sasa borealis (14.082%) and Lindera obtusiloba (7.921%) in the herb layer. According to NMS analysis of shrub layer, Species characterized by strong correlation have been reduced as time goes by. And it reports different species as an increasing in basal area of the upper layer. Herb layer plots of the NMS analysis, Rhododendron schlippenbachii and Rhododendron mucronulatum consistently were affected in shrub layer. In consequence of MRPP-test for changes in vegetation composition, It was analyzed that there are no significant differences for vegetation composition changes on shrub layer in 5-10 years. As a changes of vegetation composition on herb layer were analyzed significantly, composition change of herb layer species was larger than shrub layer species in understory vegetation.

Multiple Applications of Lime Sulfur for Fruit Thinning of 'Fuji' and 'Hongro' Apple Trees (석회유황합제의 다중처리에 따른 '후지' 및 '홍로' 사과의 적과 효과)

  • Chun, Ik-Jo;Zheng, Wei-Wei;Choi, Cheol;Song, Yang-Yik;Kwang, In-Kye;Hirst, Peter
    • Journal of Bio-Environment Control
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    • v.21 no.4
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    • pp.445-451
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    • 2012
  • The thinning effects of lime sulfur either alone or combined with fish oil on two apple cultivars 'Fuji'/M.9 and 'Hongro'/M.9 were investigated during two consecutive seasons. Either 1% or 2% lime sulfur at full bloom decreased the amounts of both terminal and axillary fruits compared with unsprayed 'Fuji' control trees in the first year. However, 1% or 2% lime sulfur did not decrease terminal fruit set in the second year. Only, triple applications of 1% lime sulfur significantly reduced the number of terminal and axillary fruits in both years. Multiple application of 1% lime sulfur was the most effective in thinning of 'Hongro'. In the first year, double or triple applications of 1% lime sulfur was effective in thinning terminal or axillary fruit, but one time applications of 1% or 2% lime sulfur was not reduced axillary fruit in 'Hongro' apple trees. In the second season, all treatments reduced terminal or axillary fruit in 'Hongro' clusters, except single application of 1% lime sulfur. Fish oil did not always improve the thinning effects of lime sulfur in 'Fuji' or 'Hongro' apple trees. None of treatments caused significant russeting in the harvested fruits. Most of thinning treatments had little effect on 'Fuji' or 'Hongro' fruit quality in terms of fruit weight, firmness, soluble solids concentration or titratable acidity.

Frostfall Forecasting in the Naju Pear Production Area Based on Discriminant Analysis of Climatic Data (기후자료 판별분석에 근거한 나주 배 생산지 서리발생 예측)

  • Han, Jeom-Hwa;Choi, Jang-Jeon;Chung, U-Ran;Cho, Kwang-Sik;Chun, Jong-Pil
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.11 no.4
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    • pp.135-142
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    • 2009
  • In order to predict frostfall, nocturnal cooling rate and air temperature changes were analyzed on days with and without frost when the maximum temperature was lower than $20^{\circ}C$. In general, the nocturnal cooling rates on frosty days were higher than those on non-frosty days. The cooling rates averaged from 19:00 to 24:00 on frosty and non-frosty days were $1.7^{\circ}Ch^{-1}$ and $0.7^{\circ}Ch^{-1}$ respectively. As expected, the nocturnal temperature on frosty days was lower than that on non-frosty days. Especially, the midnight air temperature averaged about $3.9{\pm}1.5^{\circ}C$ on frosty days, which was lower than that on non-frosty days (i.e., $10.1{\pm}2.9^{\circ}C$). The discriminant analysis using three independent variables (i.e., total cloud amount, air temperature at 24:00, and 5-day rainfall amount) successfully classified the presence of frost with 87% accuracy.

Sulfate Resistance of Alkali-Activated Materials Mortar (알칼리 활성화 결합재 활용 모르타르의 황산염 침식 저항성)

  • Park, Kwang-Min;Cho, Young-Keun;Lee, Bong-Chun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.2
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    • pp.94-101
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    • 2016
  • This paper presents an investigation into the durability alkali-activated materials(AAM) mortar and paste samples manufactured using fly-ash(FA) and ground granulated blast furnace slag(GGBFS) exposed to a sulfate environment with different GGBFS replace ratios(0, 30, 50 and 100%), sodium silicate modules($Ms[SiO_2/Na_2O]$ 1.0, 1.5 and 2.0) and initial curing temperatures($23^{\circ}C$ and $70^{\circ}C$). The tests involved immersions for a period of 6 months into 10% solutions of sodium sulfate and magnesium sulfate. The evolution of compressive strength, weight, length expansion and microstructural observation such as x-ray diffraction were studied. As a results, as higher GGBFS replace ratio or Ms shown higher compressive strengths on 28 days. In case of immersed in 10% sodium sulfate solution, the samples shows increase in long-term strength. However, for samples immersed in magnesium sulfate solutions, the general observation was that the compressive strength decreased after immersion. The most drastic reduction of compressive strength and expansion of weight and length occurred when GGBFS or Ms ratios were higher. Also, the XRD analysis of samples immersed in magnesium sulfate indicated that expansion of AAM caused by gypsum($CaSO_4{\cdot}2H_2O$); the gypsum increased up to 6 months continuously.

Fire Examples Study of Intake and Exhaust System, Alternator Tuning and Inflow of Inflammables on Exhaust Part in a Car (자동차 흡배기장치, 발전기 튜닝 및 배기측 인화성 물질 유입에 관련된 화재사례 연구)

  • Lee, Il Kwon;Kook, Chang Ho;Suh, Moon Won;You, Chang Bae;Youm, Kwang Wook;Lim, Chun Moo;Jung, Dong Hwa
    • Journal of the Korean Institute of Gas
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    • v.18 no.5
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    • pp.47-51
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    • 2014
  • This paper is to analyze and study the fire examples in respect of intake and exhaust, alternator tuning and inflow of inflammables on exhaust part in a car. In the first example, the driver diverted the intake and exhaust system for tuning of a car. Stopping a car to rest for moment, the flammable styrofoam scrap go into exhaust pipe that installed with exhaust manifold newly. It certified the fact that catched fire gradually, furthermore enlarged the fire by leaking fuel. In the second example, the driver enlarged the generator performance to divert the audio system in side room., it knew the fact that the electric wiring connected with generator gave the cause of outbreak a fire by overheating. In the third example, the serviceman replaced the engine oil using funnel-shaped, he put the a bottle of plastic pat onto engine cover carelessly. Consequentially, it found the fire occurrence in the engine room. Therefore, the driver never divert the intake and exhaust and generator construction of a car abnormally. Also, repairing and inspecting a car, the serviceman have a care to not occur the fire by inflammables.

Effects of Different Seeding Rates on Disease Incidences of Wheat Sharp Eyespot and Selection of Fungicides (밀 잎집눈무늬병의 발생에 파종량이 미치는 영향과 방제 약제 선발)

  • Park, Jong-Chul;Lee, Eun-Sook;Cho, Kwang-Min;Lee, Mi-Ja;Kang, Chun-Sik;Choi, Jae-Seong
    • Research in Plant Disease
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    • v.18 no.1
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    • pp.10-16
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    • 2012
  • This study was conducted to examine the effects of the seeding rate on the disease incidence of sharp eyespot(Rhizoctonia cerealis) on three different varieties and to select effective chemicals to control the disease. When the seeds were sown twice as many as the recommendation, the disease incidence increased by approximately 13%. However, the susceptible variety 'Jopummil' alone showed the significantly enhanced disease incidence at a two-fold seeding rate. Two chemicals such as Hexaconazole EC and Tebuconazole EC highly inhibited the fungal growth on agar medium. However, two strobilurin fungicides such as Pyraclostrobin EC and Trifloxystrobin SC were relatively weak. The fungicides tested displayed the similar in vivo antifungal activities as in vitro activities. Hexaconazole EC and Tebuconazole EC showed the strongest both protective and curative activities and the protective activities of the chemicals were generally higher than the curative activities. Hexaconazole EC and Tebuconazole EC controlled the disease by 64% and 73%, respectively, and the two chemicals reduced the disease by 45% and 39%, respectively, when they were applied one day after pathogen inoculation. These results indicate that both Hexaconazole EC and Tebuconazole EC could be used to control sharp eyespot on wheat.

Optimal timing for salvage surgery after definitive radiotherapy in hypopharyngeal cancer

  • Chun, Seok-Joo;Keam, Bhumsuk;Heo, Dae Seog;Kim, Kwang Hyun;Sung, Myung-Whun;Chung, Eun-Jae;Kim, Ji-hoon;Jung, Kyeong Cheon;Kim, Jin Ho;Wu, Hong-Gyun
    • Radiation Oncology Journal
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    • v.36 no.3
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    • pp.192-199
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    • 2018
  • Purpose: Use of radiotherapy combined with chemotherapy is increasing in hypopharyngeal cancer. However, many show residual tumor after radiotherapy. Timing for treatment evaluation and salvage therapy is essential. However, optimal timing for salvage surgery has not been suggested. In this study, we tried to evaluate optimal timing for salvage surgery. Methods and Materials: Patients who were diagnosed with hypopharyngeal squamous cell carcinoma between 2006 and 2015 were retrospectively analyzed. All patients received definitive radiotherapy with or without chemotherapy. Response of all treated patients were analyzed at 1, 3, and 6 months after radiotherapy. Any patients with progression before 6 months were excluded. Results: A total of 54 patients were analyzed. Complete remission (CR) rates at 1 month (CR1), 3 months (CR3) and 6 months (CR6) were 66.7%, 81.5%, and 90.7%, respectively. Non-CR at 1 month (NCR1), 3 months (NCR3), and 6 months (NCR6) showed poor locoregional recurrence-free survival rates (1-year rates of 63.7%, 66.7%, and 0.0%, respectively) compared to CR1, CR3, and CR6 (1-year rates 94.3%, 88.0%, and 91.5%, respectively). Particularly significant differences were seen between CR6 and NCR6 (p < 0.001). Of 10 patients with NCR3, 5 showed CR at 6 months (NCR3/CR6). There was no statistical difference in locoregional recurrence-free survival between CR3 and NCR3/CR6 group (p = 0.990). Conclusion: Our data suggest half of patients who did not show CR at 3 months eventually achieved CR at 6 months. Waiting until 6 months after radiotherapy may be appropriate for avoiding additional salvage therapy.

Echocardiographic Evaluation of Cardiovascular Function in Cloned Dogs (심장 초음파를 이용한 복제견의 심혈관계 기능 평가)

  • Yeo, Ju-Hwan;Kim, Jae-Hwan;Kim, So-Young;Lee, Seung-Jun;Park, Noh-Won;Oh, Hyun-Ju;Kim, Min-Jung;Kim, Geon-A;Jo, Young-Kwang;Lee, Byeong-Chun;Eom, Kidong
    • Journal of Veterinary Clinics
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    • v.32 no.4
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    • pp.301-307
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    • 2015
  • The purpose of this study was to compare echocardiographic parameters of cloned beagle dogs with the previously reported reference range. Seven cloned dogs were assessed for anatomical features and cardiac function through left- and right-sided heart and right ventricle outflow tract from M-mode, 2D-mode, pulsed wave Doppler and tissue Doppler imaging. In all the cloned dogs, there were no abnormalities in anatomical structure and measurements were within the normal reference range. In addition, left- and right-sided myocardial function was within the normal reference range. Especially, pulmonary hypertension and right-sided heart failure frequently encountered in cloned animals were not recognized in cloned dogs. In conclusion, no evidence of cardiovascular dysfunction in mature cloned dogs could be identified either at birth or the growing stage in this study. Therefore, serious adverse effects of somatic cell nuclear transfer technology including transgenesis on cardiac morphology and function were not found in cloned dogs.