• Title/Summary/Keyword: Chromatograph

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A Study on the Comparison of Methods for the Measurement of Hydrocarbon Dew Point of Natural Gas (천연가스의 탄화수소 이슬점 측정방법 비교 연구)

  • Lee, Kang-Jin;Ha, Young-Cheol;Her, Jae-Young;Woo, Jin-Chun;Kim, Yong-Doo;Bae, Hyun-Kil
    • Korean Chemical Engineering Research
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    • v.53 no.4
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    • pp.496-502
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    • 2015
  • Hydrocarbon dew point(HCDP), a property which is the most generally used for describing natural gas condensation, is a very important parameter of natural gas quality specifications. HCDP is strongly influenced by the concentration of the heavier hydrocarbon components, especially $C_6+$, so, along with compliance with gas quality specifications, build up of procedures for obtaining accurate HCDP is essential for gas transmission company, because hydrocarbon condensation present may cause serious operational and safety problems. This study has been carried out in an attempt to measure HCDP accurately by the automatic hydrocarbon dew point meter under the actual field conditions. Measured HCDP also has been compared with calculated HCDP using the composition determined by gas chromatograph and industry accepted equation of state at multiple pressures, along with the cricondentherm. The test results are 1) the automatic hydrocarbon dew point meter was able to measure stable HCDP continuously 2) the automatic hydrocarbon dew point meter has been performed reference measurement by pure propane with a known dew point from literature, and 3) A meaningful differences was observed when comparing the automatic hydrocarbon dew point meter and gas chromatograph results for synthetic standard gas mixtures and real gas mixtures.

A Study on Etching of Si3N4 Thin Film and the Exhausted Gas Using C3F6 Gas for LCD Process (LCD 공정용 C3F6 가스를 이용한 Si3N4 박막 식각공정 및 배출가스에 관한 연구)

  • Jeon, S.C.;Kong, D.Y.;Pyo, D.S.;Choi, H.Y.;Cho, C.S.;Kim, B.H.;Lee, J.H.
    • Journal of the Korean Vacuum Society
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    • v.21 no.4
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    • pp.199-204
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    • 2012
  • $SF_6$ gas is widely used for dry etching process of semiconductor and display fabrication process. But $SF_6$ gas is considered for typical greenhouse gas for global warming. So it is necessary to research relating to $SF_6$ alternatives reducing greenhouse effect in semiconductor and display. $C_3F_6$ gas is one of the promising candidates for it. We studied about etch characteristics by performing Reactive Ion Etching process of dry etching and reduced gas element exhausted on etching process using absorbent Zeolite 5A. $Si_3N_4$ thin film was deposited to 500 nm with Plasma Enhanced Chemical Vapor Deposition and we performed Reactive Ion Etching process after patterning through photolithography process. It was observed that the etch rate and the etched surface of $Si_3N_4$ thin film with Scanning Electron Microscope pictures. And we measured and compared the exhausted gas before and after the absorbent using Gas Chromatograph-Mass Spectrophotometry.

A Study on LNG Quality Analysis using a Raman Analyzer (라만분석기를 이용한 LNG 품질 분석 실증 연구)

  • Kang-Jin Lee;Woo-Sung Ju;Yoo-Jin Go;Yong-Gi Mo;Seung-Ho Lee;Yoeung-Chul Kim
    • Korean Chemical Engineering Research
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    • v.62 no.1
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    • pp.70-79
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    • 2024
  • Raman analyzer is an analytical technique that utilizes the "Raman effect", which occurs when light is scattered by the inherent vibrations of molecules. It is used for molecular identification and composition analysis. In the natural gas industry, it is widely used in bunkering and tank lorry fields in addition to LNG export and import terminals. In this study, a LNG-specific Raman analyzer was installed and operated under actual field conditions to analyze the composition and principal properties (calorific value, reference density, etc.) of LNG. The measured LNG composition and calorific value were compared with those obtained by conventional gas chromatograph that are currently in operation and validated. The test results showed that the Raman analyzer provided rapid and stable measurements of LNG composition and calorific value. When comparing the calorific value, which serves as the basis for LNG transactions, with the results from conventional gas chromatograph, the Raman analyzer met the acceptable error criteria. Furthermore, the measurement results obtained in this study satisfied the accuracy criteria of relevant international standards (ASTM D7940-14) and demonstrated similar outcomes compared to large-scale international demonstration cases.

Study on the Inhibition of anti-platelet and Anticoagulant activity from Rhus verniciflua Stokes

  • Kyung, Jeon-Won;Kim, Jung-Hee;Lee, A-Yeong;Kim, Ho-Kyoung
    • Proceedings of the PSK Conference
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    • 2003.04a
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    • pp.271.3-272
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    • 2003
  • Rhus verniciflua Stokes (RVS) is a widely used herbal plant with various biological properties. Our previous study using in vitro platelet aggregation in whole blood showed that the fractions of RVS had strong anti-aggregatory activity. In this study, using in vitro platelet aggregation in PRP and coagulation parameters, to investigate the anti-platelet activity and anticagulant effects of RVS ethyl acetate layer, the layer was subsequently fractionated by ODS columm chromatograph (50% MeOH). (omitted)

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Study on the Effect of Washing with Water and Detergent on the Vitamin C Content in Fruit and Vegetable (세정 및 세제사용이 야채 및 과일의 비타민 C 함량에 미치는 영향)

  • 이용욱
    • Journal of Environmental Health Sciences
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    • v.19 no.2
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    • pp.55-60
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    • 1993
  • This study was performed to investigate the effect of washing with water and detergent on the vitamin C content in strawberry and perilla leaf. Vitamin C was extracted with the solution of metaphosphoric acid and quantitated by high performance liquid chromatograph (HPLC). There was no significant difference of vitamin C content between the washing with distilled water and tap water. Three available detergents reduced the vitamin C content of samples to 92.5%, 92.2% and 78.5%, respectively. The content of vitamin C in samples was decreased by increasing the concentration of detergent and washing time.

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Spectrophotometric Determination of N-3-Pyridylmethyl-N'-p-nitrophenyl Urea in Rodenticide (흡광광도법(吸光光度法)에 의(依)한 살서제(殺鼠劑) N-3-Pyridylmethyl-N'-p-nitrophenyl Urea(RH-28787)의 정량(定量))

  • Kim, Bak-Kwang
    • Journal of Pharmaceutical Investigation
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    • v.6 no.2
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    • pp.83-87
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    • 1976
  • Microanalysis of rodenticide by visible absorption method was attempted. The following procedure was found to be very simple and to give accurate results. RH-28787 was added to dimethylformamide (DMF), and extracted after stirring for about 20 minutes in extractor $(30^{\circ}C)$. After extraction, the absorbance of DMF solution, was measured at 346 nm by using spectrophotometer. The result agrees closely with the experimentally determined value by means of the gas chromatograph.

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Studies on the Terpenoids in the Volatile Constituents of Liaoning Schisandra Chinensis Baillon

  • Hou, Dongyan;Zhang, Weihua;Hui, Ruihua
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.505-509
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    • 1995
  • The terpenoids in the volatile constituents of Liaoning Shcisandra Chinesis Baillon have been determined by the analytical method of GC/MS. Thirty terpenoids molecular structure were characterized. They are 11.89% monterpenes, 4.60% monoterpene oxides, 58.74% sesquiterpene hydrocarbons, and 1.62% oxygen-containing sesquiterpenoids in the total volatile constituents quantified by chromatograph. Among them, the sesquiterpene make up the characteristic constituents. Every terpenoid constituent percent content was obtained using area normalization method of HP-59970 chemstation.

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Studies on Dissolution of Lorazepam Preparation (Lorazepam 제제(製劑)의 용출(溶出)에 관한 연구(硏究))

  • Yang, Jae-Heon
    • Journal of Pharmaceutical Investigation
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    • v.14 no.4
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    • pp.161-169
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    • 1984
  • The tests of dissolution and bioavailability of six formulas of lorazepam tablet under various binders were performed. Lorazepam can be seperated in pharmaceutical preparation and biological plasma by high performance liquid chromatograph. Dissolution process of lorazepam tablet was largely influenced by binder and the dissolution rate was increased by sodium starch glycolate and microcrystalline cellulose, the slower dissolution rate in starch. Bioavailability of lorazepam tablet got relationship with dissolution rate, because tablets containing sodium starch glycolate and microcrystalline cellulose as binder maintained higher plasma level than other binders.

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Phytochemical Survey of Herb Drugs (IV) (한약의 식물화학적 조사(IV))

  • 우린근;김제훈
    • YAKHAK HOEJI
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    • v.9 no.3_4
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    • pp.34-36
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    • 1965
  • As the projects of this institute, a hundred and sixtyfive species of plants which are used currently as herb drugs in Korea were screened on the presence of alkaloids, phenolic compounds, flavonoids, chalcones, lactones, glucosides, carbohydrates, terpenoids, steroids proteins, polypeptides, saponins, and organic acids, and the most reliable presence of alkaloids was detected by paper chromatograph. In this paper, presence of alkaloids is added by screening of 45 species.

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Microquantitative Analysis of Quercetin by Gas Chromatography (Gas Chromatography법에 의한 Quercetin의 미량분석에 관한 연구)

  • 이숙연;김성경
    • YAKHAK HOEJI
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    • v.26 no.2
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    • pp.117-121
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    • 1982
  • This investigation was intended to develope the quantitative gas liquid chromatographic method for quercetin. The method involves derivatization of the sample with trimethylsilylimidazole containing cholesterol as an internal standard and injection into a gas chromatograph with 3% OV-17 column. The calibration curve for the quercetin was linear over a sample in the range of 4-16.mu.g. The minimum detectable amount using FID in $1.6{\times}10^{-10}$ a.f.s. was determined to be $6.64{\times}10^{-10}mol$.

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