• Title/Summary/Keyword: Chlorine effect

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Developing Trend of Clean Propellants (청정 추진제 개발 동향)

  • Kim In-Chul;Ryoo Baek-Neung;Kim Chang-Kee
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2005.11a
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    • pp.5-8
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    • 2005
  • In this report the developing trends of several clean and green propellants have been summarized. A low-acid clean propellant has been developed, which substantially reduced the content of hydrochloric acid(HCl) in the solid rocket exhaust. Although the chlorine-free approach is now preferred, this technology has not been proved yet. Another acid suppression effect of Magnalium(Mg-Al Alloy) was investigated. Reports says that the concentration of HCl could be reduced to approximately one-fifth of conventional propellant. Many 'green' propellants with low toxicity are being developed for next-generation post-boost propulsion systems, in which combustion research on the Al or Mg fine metal particles with hot steam in various stoichiometric conditions are being performed.

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A Study on the Refrigerant Characteristics of the HFC-l52a, and Azeotrope Mixed with $CF_3$I in Air Conditioners (에어컨용 냉매 HFC-152a와 HFC-152a에 $CF_3$I를 혼합한 공비혼합냉매 특성에 관한 연구)

  • 이종인;하옥남;홍경한;권일욱;박찬수
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.4
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    • pp.332-340
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    • 2002
  • In these days, environmental concerns have been increased throughout the industry and community worldwide. To prevent the ozone depletion, ozone depletion potential of a refrigerant must be zero. Simultaneously, a refrigerant with low GWP (global warming potential) is very demanding to induce green house effect. Chlorine-free HFC-l34a is a refrigerant widely used for automotive air-conditioning system because its destruction potential is ecologically zero. Although HFC-l34a has no ozone depletion potential, its global warming potential is so high that it is not considered as a perfect alternative refrigerant that is acceptable for long-term use. In this paper, experimental measurement has been carried out to analyze the performance characteristics of automotive air-conditioning system using HFC-152a, which has low GWP and zero ODP. Also mixed refrigerant that is composed of HFC-152a and $CF_3$ was applied to investigate an alternative possibility for the automotive airconditioning system. As a result of this study, we could draw following conclusions; With respect to the variation of the rotational speed of compressor, outside air temperature and flow rate, the heat amount of evaporator and compressor and performance coefficient was varied.

Investigation of carprine arthritis-encephalitis from dairy goat in Jeonnam province (전남지역의 유산양 관절염.뇌염 감염 실태조사)

  • Lim, Jong-Soo;Kim, Hui-Joung;O, Hyun-Yi;Lee, Tea-Uk;Park, Suk-Jun
    • Korean Journal of Veterinary Service
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    • v.31 no.3
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    • pp.273-281
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    • 2008
  • This survey was conducted to investigate the infection of caprine arthritis encephalitis virus (CAEV). From April to October 2007, we examined a total of 173 goats in 7 dairy goat-breeding farms located in Na-ju, Hae-nam, Young-am, and Young-gwang area of Jeonnam province. The results show that 41 (23.7%) goats are positive for CAEV, confirmed by nested PCR of 173 blood samples. Regional analysis revealed that a positive proportion for CAEV was 50.0% in Young-gwang, 25.6% in Young-am, 25.0% in Hae-nam, and 10.9% in Na-ju. Clinical signs were observed in 17 (9.8%) goats, of which 6 suffered from arthritis, 7 from mastitis, and 4 from pneumonia. Among the examined 173 goats, 8(4.6%) goats are positive for CAEV accompanied with CAE symptoms. There was a tendency to be much higher(p<0.05) levels of natrium(Na), chlorine(Cl) in CAEV-positive than in CAEV-negative goats. However, other serum biochemical values were no statistically significant effect.

Effect of Phase Change of $MoO_3$ on $H_2$ Spillover Kinetics over Pt/$MoO_3$ (Pt/$MoO_3$ 촉매에서 $MoO_3$ 상변화가 수소 spillover에 미치는 효과)

  • Kim, Jin-Gul;Kim, Seong-Soo;Yoo, Seung-Joon
    • Journal of Hydrogen and New Energy
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    • v.20 no.4
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    • pp.331-336
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    • 2009
  • 수소가 Pt/$MoO_3$로 흡장되는 현상을 XRD, TEM, CO 화학흡착 분석방법을 사용하여 조사하였다. 소성과정은 Pt/$MoO_3$ 촉매의 Chlorine 함유량을 감소하며 박막을 형성하였다. 소성전과 비교하여 수소 흡장량은 소성 후에 증가하였다. Orthorhombic Pt/$MoO_3$은 Hexagonal Pt/$MoO_3$보다 항상 수소 흡장량이 증가하였다. 상대적으로 Hexagonal Pt/$MoO_3$에서 수소 흡장량이 감소하는 이유는 Hexagonal 결정격자 내에 존재하는 $NH_4^+$ 이온에 기인하는 것으로 판단된다. 결정격자 내부로의 수소 침투시 암모니움 이온이 수소내부 기공에 장애물 역할을 하므로, 수소 흡장량이 감소하는 것으로 판단된다.

Germicidal Effect of Electrolyzed Seawater on Live Fish and Shellfish (전기분해 해수의 활어패류 살균 효과)

  • Lee, Hee-Jung;Yu, Hongsik;Oh, Eun-Gyoung;Shin, Soon Bum;Park, Kunbawui;Kim, Ji Hoe
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.46 no.5
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    • pp.534-539
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    • 2013
  • To secure the biological safety of live fish and shellfish for raw consumption, the germicidal effects of electrolyzed seawater were evaluated. Upon direct exposure to electrolyzed seawater, coliform group bacteria were killed and decreased to undetectable levels after 1 day. The physicochemical characteristics of the seawater were stable during the test period. A byproduct of chlorine disinfection, trihalomethane, was not generated by the electrolysis of seawater. Vibrio parahaemolyticus infection in a live fish was effectively resolved by electrolyzed seawater and became undetectable after 12-36 h of treatment. Bioaccumulation of coliform group and fecal coliform bacteria in live oysters Crassostrea gigas was removed within 18 h of treatment. This study demonstrated that electrolyzed seawater is an effective and safe germicidal agent for the traditional retail market and can help to prevent outbreaks of foodborne disease associated with the consumption of raw fish and shellfish.

A Study on the Characteristics an Azeotropic Mixture Combined with CF_{3}I and a Refrigerant for Air-Conditioner HFC-152a and HFC-152a

  • Lee, Jong-In;Kwon, Il-Wook;Ha, Ok-Nam
    • International Journal of Air-Conditioning and Refrigeration
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    • v.11 no.3
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    • pp.140-149
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    • 2003
  • In these days, environmental concerns have been increased throughout the industry and community worldwide. To prevent the ozone depletion, ozone depletion potential of a refrigerant must be zero. Simultaneously, a refrigerant with low GWP (global warming potential) is very demanding to reduce green house effect. Chlorine-free HFC-l34a is a refrigerant widely used for automotive air-conditioning system because its destruction potential is ecologically zero. Although HFC-l34a has no ozone depletion potential, its global warming potential is so high that it is not considered as a perfect alternative refrigerant that is acceptable for long-term use. In this paper, experimental measurement has been carried out to analyze the performance characteristics of automotive air-conditioning system using HFC-152a, which has low GWP and zero ODP. Also mixed refrigerant that is composed of HFC-152a and $CF_3$ was applied to investigate an alternative possibility for the automotive air-conditioning system. As a result of this study, we could draw following conclusions; With respect to the variation of the rotational speed of compressor, outside air temperature and flow rate, the heat amount of evaporator and compressor and performance coefficient was varied.

Variation of Oak Kraft Pulp Properties by Xylanase Treatment in C/D, P and Z Stage (C/D, P 및 Z단계 표백시 Xylanase처리에 의한 펄프성질의 변화)

  • Kim, Dong-Ho;Paik, Ki-Hyon
    • Journal of the Korean Wood Science and Technology
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    • v.25 no.2
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    • pp.100-109
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    • 1997
  • The objectives of this study was to decrease pollutions of bleaching effluent and was to enhanced brightness of non-chlorine bleached pulps by xylanase treatments. Xylanase cloned Esherichacoli(E. coli) capable of each of endo, exo-xylanase and acetyl-esterase were obtained from Bacillus stearothermophillus. These xylanase was maintained high activity in alkali and high temperature. Especially endo-xylanase would be more active in $60^{\circ}C$ and pH 11. Xylanase pretreatment(X) of unbleached pulp increased brightness, and decreased the degree of delignification. The degree of increase in brightness of pulp due to xylanase pretreatment was similar to non-enzyme treated pulp, regardless of the amount of enzyme added. Therefore, the addition of xylanase of 2 unit was recommended when considering costs of enzyme. The pulp bleached XO sequence had higher brightness and lower Kappa no, than O bleached pulp, while pulp bleached XP sequence had similar brightness and Kappa no. with P bleached pulp. In XOC/D, XOZ and XOP bleaching sequences, brightness and degree of delignification were improved. The C/D and Z stage bleached pulp was good effect on rate of raise in brightness and Kappa no., but P stage bleached pulp had similar level in non-enzyme treated bleaching sequence.

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Effect of raw water quality decrease on water treatment costs (상수원수 수질저하가 정수처리 비용에 미치는 영향)

  • Kim, Jinkeun
    • Journal of Korean Society of Water and Wastewater
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    • v.34 no.4
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    • pp.239-250
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    • 2020
  • In this study, effects of five raw water quality parameters (turbidity, odor compounds caused by algae, filter clogging caused by algae, pH increase caused by algae, and organic matter) on improvements and operations costs of typical water treatment plant (WTP) were estimated. The raw water quality parameters were assumed the worst possible conditions based on the past data and costs were subsequently estimated. Results showed that new water treatment facilities were needed, such as a selective intake system, an advanced water treatment processes, a dual media filter, a carbonation facility, and a re-chlorination facility depending on water quality. Furthermore, changes needed to be made in WTP operations, such as adding powered activated carbon, increasing the injection of chlorine, adding coagulation aid, increasing the discharge of backwashed water, and increasing the operation time of dewatering facilities. Such findings showed that to reliably produce high-quality tap water and reduce water treatment costs, continuous improvements to the quality of water sources are needed.

The Influence of Strain Rates on the $CH_4/C_2HCl_3/Air$ Counterflow Nonpremixed Flames ($CH_4/C_2HCl_3/Air$ 대향류 비예혼합 화염에서 스트레인율의 영향)

  • Lee, Ki-Yong
    • Journal of the Korean Society of Combustion
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    • v.5 no.1
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    • pp.7-18
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    • 2000
  • Numerical simulations of counterflow non-premixed $CH_4/C_2HCl_3/Air$ flames added 8%(by volume) C2HCl3 on the fuel side are conducted at atmospheric pressure using a detailed chemical reaction mechanism in order to understand the effect of strain rates. A detailed sensitivity analysis is also performed in order to assess the relative influence of each reaction on the flame established at a strain rate of 200s-1. The structure of flames (i.e., temperature, velocity, and concentration of species) established at both a strain rate of 150s-1 and 300s-1 are investigated. As the strain rate increases, the "flame zone" is restricted to a narrower range and the position of maximum temperature is shifted to the fuel side. The concentrations of major species, H2O, CO, H2, HCl, Cl2, and Cl are decreased with increased strain rate. The reaction involving chlorine, CH4 + Cl $\rightarrow$ CH3 + HCl, instead of the reaction, CH4 + H $\rightarrow$ CH3 + H2 influences the consumption of methane. C2HCl3 + OH $\rightarrow$ CHCl2 + CHOCl and HCl + OH $\rightarrow$ H2O + Cl, are major reactions, through which OH radicals are consumed.

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A Study on the Variation of HAA Precursors by Ozonation of Phenol (페놀의 오존 산화시 관찰된 HAA 전구물질 변화에 관한 연구)

  • Oh, Byung Soo;Kim, Kyoung Suk;Kang, Joon-Wun
    • Journal of Korean Society on Water Environment
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    • v.21 no.2
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    • pp.153-157
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    • 2005
  • The purpose of this study was to find out the effect of oxidation by-products for the formation of haloacetic acid (HAA) during ozonation. The phenol was used as a model precursor of HAA, and its oxidation by-products, such as hydroquinone, catechol, glyoxal, glyoxylic acid and oxalic acid were investigated to find out how much HAA formation potential (HAAFP) they have. As the result, among the phenol and its oxidation by-products, the highest reactivity with chlorine was found from the phenol, showing the highest HAAFP. Even though the tested by-products had a lower HAAFP than phenol, it was confirmed that all of them can act as the precursor of HAA. From the ozonation of phenol-containing water, it was found that the efficiency of ozone in controlling of HAAs can be reduced due to the oxidation by-products. In addition, the ozonation of HAAFP was performed under the both pH conditions (acid and base), and the result indicates that OH radical play a important role to decrease HAAFP.