• Title/Summary/Keyword: Chloride threshold

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Prediction of Corrosion Threshold Reached at Steel Reinforcement Embedded in Latex Modified Concrete with Mix Proportion Factor (배합변수에 따른 라텍스 개질 콘크리트 내에 정착된 보강철근의 부식개시시기 예측)

  • Park, Seung-Ki;Won, Jong-Pil;Park, Chan-Gi;Kim, Jong-Ok
    • Journal of The Korean Society of Agricultural Engineers
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    • v.50 no.6
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    • pp.49-60
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    • 2008
  • This study were predicted the corrosion threshold reached at steel reinforcement in latex modified concrete(LMC) which were applied the agricultural hydraulic concrete structures. Accelerated testing was accomplished to the evaluate the diffusion coefficient of LMC mix, and the time dependent constants of diffusion. Also, the average chloride diffusion coefficient was estimated. From the average chloride ion diffusion coefficient, the time which critical chloride contents at depth of reinforcement steel was estimated. Test results indicated that the corrosion threshold reached at reinforcement in LMC were effected on the mix proportion factor including cement contents, latex content, and water-cement ratio. Especially, the average chloride diffusion coefficient, the corrosion threshold reached at reinforcement in LMC were affected by the all mix proportion factor.

Threshold Chloride Contents of Steel Corrosion in Concrete Containing Chloride (염화물 혼입 콘크리트 중의 철근부식 임계 염화물량)

  • 문한영;김성수;김홍삼;이승태;김은호
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10a
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    • pp.395-398
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    • 2000
  • Recently, increasement of usage contents of sea sand in constructing concrete structures due to insufficiency of high quality river sand, led to many studies for steel corrosion and control methods on it in concrete. But, domestic studies for threshold chloride contents of steel corrosion are not so many as those of foreign states. In this study, the electrochemical test as half cell potential measurement and linear polarization method to estimate the corrosion of steel in contents mixed with several levels chloride contents was performed, thereby, pre-mixed chloride were compared with results measured quantitatively for steel corrosion. And, based on these data, a trial to determine threshold chloride contents of steel corrosion was made.

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Estimation of Critical Chloride Threshold Value Using Corrosion Monitoring (부식 모니터링을 이용한 콘크리트 내의 임계 염화물량 평가)

  • Bae Su Ho;Lee Kwang Myong;Chung Young Soo;Kim Jee Sang
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.801-804
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    • 2004
  • It should be noted that the critical chloride threshold level is not considered to be a unique value for all conditions. This value is dependent on concrete mixture proportions, cement type and constituents, presence of admixtures, environmental factors, steel reinforcement surface conditions, and other factors. In this study, the accelerated corrosion test for reinforcing steel was conducted by electrochemical and sea water-circulated method, respectively and during the test, corrosion monitoring by half cell potential method was carried out to estimate the critical chloride threshold value when corrosion for reinforcing steel in concrete was perceived. For this purpose, lollypop and beam test specimens were made for $31.4\%,\;41.5\%\;and\;49.7\%$ of w/c. respectively and then the accelerated corrosion test for reinforcing steel was executed. It was observed from the test that the time to initiation of corrosion was found to be different with water-cement ratio and the critical chloride threshold value was found to range from 0.91 to $1.27kg/m^3$.

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Study on the Critical Threshold Chloride Content for Steel Corrosion in Concrete with Various Cement Contents (단위시멘트량이 다른 콘크리트 중에서의 철근부식 임계염화물량에 관한 연구)

  • Yang, Seung-Kyu;Kim, Dong-Suck;Um, Tai-Sun;Lee, Jong-Ryul;Kono, Katsuya
    • Journal of the Korea Concrete Institute
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    • v.20 no.4
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    • pp.415-421
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    • 2008
  • Reinforced concrete starts to corrode when the chloride ion concentration which is the sum of included in concrete and penetrated from environments exceeds a certain level of critical chloride concentration. Therefore each country regulates the upper bounds of chloride amount in concrete and the regulations are different for each country due to its circumstances. In this study, the critical threshold chloride content according to unit cement amount is empirically calculated to propose a reasonable regulation method on the chloride amount. As a result, the critical threshold chloride content increases considerably according to cement content and it agrees with the established theories. The present regulations on total chloride amount 0.3 or 0.6 kg chloride ions per $1\;m^3$ of concrete does not reflect the influences of mix design, environmental conditions and etc. So it can be said that it is more reasonable to regulate the critical threshold chloride content by the ratio of chloride amount per unit cement content than by the total chloride content in $1\;m^3$ of concrete.

Hybrid Corrosion Inhibitor-Based Zwitterions and Phosphate in Reinforced Concrete: Determining Chloride Threshold and Service Life (철근 콘크리트의 Zwitterion 및 인산염 기반 하이브리드 부식 억제제: 염화물 임계값 및 사용 수명 결정)

  • Tran, Duc Thanh;Jeong, Min-Goo;Lee, Han-Seung;Yang, Hyun-Min;Singh, Jitendra Kumar
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.33-34
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    • 2023
  • Corrosion of reinforcement steel is a major cause of deterioration in reinforced concrete (RC) structures. In order to protect these structures from corrosion, corrosion inhibitors are added to the concrete mix. In recent years, zwitterionic compounds have shown promising results as corrosion inhibitors in concrete due to their ability to form a protective layer on the surface of the reinforcement steel. The experimental study involves preparing concrete samples with different concentrations of adding the hybrid corrosion inhibitor at a high concentration of chloride ions. This study aims to determine the chloride threshold value and service life of hybrid corrosion inhibitors in reinforced concrete based on zwitterions. The samples are subjected to accelerated corrosion tests in a chloride environment to determine the threshold value and service life of the corrosion inhibitor. The effect of hybrid inhibitor on mechanical properties is guaranteed in allowable range. The chloride threshold concentration and service life of hybrid inhibitor containing samples perform greater than those of plain RC.

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Determination of Critical Chloride Content of Ordinary Portland Cement Concrete by Linear Polarization Technique (선형분극법을 이용한 보통프틀랜드시멘트 콘크리트의 임계염화물량)

  • Kim, Hong-Sam;Cheong, Hai-Moon;Ahn, Tae-Song
    • Journal of the Korean Ceramic Society
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    • v.44 no.9
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    • pp.524-528
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    • 2007
  • The results of evaluating steel corrosion in concrete containing chloride content of various levels indicated that the more chloride content in concrete leads to the lower potential and higher corrosion current density. However, the open circuit potential of steel varied with time and exposure condition, and the corelation between the open circuit potential and corrosion current density was not obvious. In order to determine the critical threshold content of chloride of steel corrosion in concrete, the concept of average corrosion current density was employed. The range of critical chloride content in portland cement concretes was about $1.56{\sim}1.77%$($Cl^-$, %, wt of cement content) along with water-cement ratio, and higher water-cement ratio resulted in reduction in critical threshold chloride content.

A Case Study on the Release Characteristic and Removal Efficiency of Vinyl Chloride in the Poly Vinyl Chloride Extrusion Process (PVC압출공정의 염화비닐 발생특성과 작업환경개선에 관한 사례연구)

  • Park, Dong Uk
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.3 no.1
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    • pp.91-98
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    • 1993
  • This study was carried out to investigate characteristic of vinyl chloride emissioned from poly vinyl chloride extrusion process and to evaluate the efficiency of local exhaust ventilation system. Before local ventilation facility was constructed in poly vinyl chloride extrusion process, the average worker exposure to vinyl chloride was 3.15 ppm, which exceeded Threshold Limit Value of American Conference of Gorvernmental Industrial Hygienists (ACGIH-TLV), 1 ppm. lt is possible that vinyl chloride residues in the poly vinyl chloride resin was released or degased due to extrusion heat. The larger the width of vinyl tube become, the higher worker exposure to vinyl chloride was. It is estimated that vinyl chloride from vinyl chloride resin increased as amount of poly vinyl chloride resin extruded in the extrusion process increased. Canopy hood was an appropriate type for poly vinyl chloride resin extrusion process. This local exhaust ventilation has fan static pressure of 7.65 inch wg($190mmH_2O$, total volumetric flowlate of 4,796 CFM ($135.8m^3$/min) and fan power requirement of 12 hp (8.952 Kw). After this local exhaust ventilation was constructed there, the average concentration of worker exposure to vinyl chloride was reduced to be 0.46 ppm, which was below the Threshold Limit Value, 1 ppm. Also, the removal efficiency rate of vinyl chloride attained by local exhaust ventilation was 85.3%. It was a statistically significant (p<0.01).

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EFFECTS OF DENTAL THERAPEUTIC AGENTS ON THE RESPONSE OF THE PULP NERVE (치과치료용 약물이 치수신경의 반응에 미치는 영향)

  • Kwon, Oh-Yang;Yoon, Soo-Han;Lee, Jong-Heun
    • Restorative Dentistry and Endodontics
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    • v.15 no.1
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    • pp.1-15
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    • 1990
  • The aim of this study was to investigate the effect of dental therapeutic agent on conduction velocity and threshold current of intradental A- and C-fibers in the cat. Inferior alveolar nerve of cat anesthetized with sodium pentobarbital was exposed and dissected until response of functional single pulp nerve until could be evoked by monopolar electrical stimulation of the crown of the lower left canine teeth. 10ms rectangular pulse was used to determine the threshold current and 1ms rectangular pulse was used to determine conduction velocity. After application of calcium chloride (1, 2, 6M), calcium hydroxide mixed with saline, potassium chloride (0.2, 0.8, 1.6M), eugenol, zinc oxide eugenol to the cavity on the labial surface, conduction velocity and threshold current of single pulp nerve unit were compared with the control. In 10 cats, 24 $A{\delta}$- and 11 C- pulp nerve units were recorded. The mean conduction velocities of $A{\delta}$- and C-fibers were 7.5m/sec (SD=5.8) and 1.2m/sec (SD=0.4), respectively. The mean threshold current was $12.3{\mu}A$ (SD=5.3) for $A{\delta}$-fibers and $24.9{\mu}A$ (SD=8.1) for C-fibers. 1, 2, 6M calcium chloride caused decrease of conduction velocity and remarkable increase of threshold current in $A{\delta}$- and C-fibers. The effect of calcium hydroxide mixed with saline was similar but smaller than calcium chloride solution. 0.2M potassium chloride had insignificant effect. In 0.8M potassium chloride, the threshold current was increased although conduction velocity was not affected. In 1.6M potassium chloride, the threshold current was increased and the conduction velocity was slowed down. Spontaneous activity was recorded frequently for first 5 min but gradually reduced both in $A{\delta}$- and C-fibers. Eugenol had irreversible effect on pulp nerve in that initially there were not certain changes in the conduction velocity and threshold current of $A{\delta}$- and C-fibers, but the responses to electrical stimulation were abruptly disappeared after sustained application and were not recovered. Contrary to eugenol, zinc oxide eugenol did not caused significant increase of the threhold current and caused time dependent decrease of the conduction velocity, and did not show any irreversible change.

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Influence of Binder Type on the Chloride Threshold Level for Steel Corrosion in Concrete

  • Moon Han-Young;Ann Ki-Yong;Jung Ho-Seop;Shin Dong-Gu
    • Journal of the Korea Concrete Institute
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    • v.17 no.4 s.88
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    • pp.663-670
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    • 2005
  • The present study concerns the influence of binder type on the chloride-induced corrosion being accompanied by the chloride threshold level (CTL), chloride transport and as their results the corrosion-free lift. Two levels of cement content, $30\%$ PFA and $65\%$ GGBS concrete were employed. It was found that the most dominant factor to the CTL is the entrapped air void content at the steel-concrete interface, irrespective of the chloride binding capacity, binder type and acid neutralisation capacity of cement matrix. The CTL for lower interfacial air void contents was significantly increased up to $1.52\%$ by weight of cement, whereas a same mix produced $0.35\%$ for a higher level of voids. Because of a remarkable reduction in the diffusion fur GGBS concrete, its time to corrosion ranges from 255 to 1,250 days, while the corrosion-free life for control varies from 20 to 199 days sand for $30\%$ PFA concrete from 200 to 331 days.

Estimation of Chloride Corrosion Threshold Value in Concrete by Using Electrochemical and Cyclic Wet and Dry Seawater Method (전기화학적 및 해수 건습반복 방법에 의한 콘크리트 내의 임계 염화물량 평가)

  • Bae Su Ho;Lee Kwang Myong;Chung Young Soo;Kim Jee Sang
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.245-248
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    • 2005
  • It should be noted that the critical chloride threshold level is not considered to be a unique value for all conditions. This value is dependent on concrete mixture proportions, cement type and constituents, presence of admixtures, environmental factors, steel reinforcement surface. conditions, and other factors. In this study, the accelerated corrosion test for reinforcing steel was conducted by electrochemical and cyclic wet and dry seawater method, respectively and during the test, corrosion monitoring by half cell potential method was carried out to estimate the chloride corrosion threshold value when corrosion for reinforcing steel in concrete was perceived. For this purpose, lollypop and right hexahedron test specimens were made for 31.4$\%$, 41.5$\%$ and 49.7$\%$ of w/c, respectively and then the accelerated corrosion test for reinforcing steel was executed. It was observed from the test that the time to initiation of corrosion was found to be different with water-cement ratio and accelerated corrosion test method, respectively and the chloride corrosion threshold value was found to range from 0.91 to 1.43 kg/$m^{3}$.

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