• Title/Summary/Keyword: Chloride removal

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Evaluation of Improvement on Sediment for Practical Application in Prawn Farm (새우 양식장에 적용을 위한 저질개선 평가)

  • Kim Woo-Hang;Kim Doo Hee
    • Proceedings of KOSOMES biannual meeting
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    • 2004.05b
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    • pp.81-84
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    • 2004
  • Control of Sediment is very important in prawn farm due to the eruption of toxic material such as W1ionized H2S, NH3 and NO2-. In this study, column test study, column with filter media such as activated carbon, zeolite, oyster shell and iron chloride to evaluate the reduction of toxicity from sediment ammonia-N(NH3) was effectively removed by Zeolite and oyster shell. It was indicated that ammonium ion(NH4+) was removed by ion exchange of zeolite. And the ammonia in the column of oyster shell was existed as the form of NH4+, which is not toxic for prawn because oyster shell was stably kept around pH 8. Therefore, some of ammonia(NH3) was reduced by oyster shell. Hydrogen sulfide and COD were effectively removed by adsorption of activated carbon and a partial removal of hydrogen sulfide was accomplished by Oyster shell. Phosphorous was removed by activated carbon, oyster shell and iron chloride. In prawn farm, the concentration of ammonia was increased with increase of pH by algae photosynthesis in the column of activated carbon, zeolite and iron chloride, but it was revealed that pH was stably kept in the column of oyster shell.

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An Oxidative Chloride Stripping Solution for 14K Gold Alloys

  • Kim, Kwangbae;Kim, Ikgyu;Song, Ohsung
    • Korean Journal of Materials Research
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    • v.30 no.8
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    • pp.393-398
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    • 2020
  • We propose a novel stripping solution containing acids (HCl and HNO3), an oxidant [(NH4)2S2O8], and complexing agents (NaCl and citric acid) to remove surface passivation layers from 14K gold alloys fabricated using an investment casting process. The optimized solution employing only HCl acid is determined by varying molar fractions of HCl and HNO3 on 14K yellow gold samples. Stripping properties are also identified for red and white gold alloy samples under the optimized stripping conditions. The removal of passivation layers, weight loss, and microstructure evolution are characterized using Raman spectroscopy, a precision scale, and optical microscopy. The proposed stripping solution effectively removes passivation layers more rapidly than conventional cyanide stripping. Weight loss increases linearly for up to 5 min for all 14K gold alloys. Red gold exhibits the greatest weight loss, followed by yellow gold and white gold. The results of microstructural analysis reveal that the conformal stripping occurs according to time. These results imply that the proposed oxidative chloride stripping might replace conventional cyanide stripping.

Synthesis of Hydroxyapatite Using a Cationic Surfactant (양이온성 계면활성제를 이용한 수산화인회석 합성)

  • Lee, Keunyoung;Kwon, Ki-Young
    • Applied Chemistry for Engineering
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    • v.30 no.5
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    • pp.639-642
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    • 2019
  • Hydroxyapatite (HAP) containing hexadecyltrimethylammonium chloride (CTAC) as a cationic surfactant was prepared by a precipitation method. X-ray diffraction (XRD), transmission electron microscopy (TEM) and micropore physisorption analyzer were used for characterizing the crystal phase, morphology and specific surface area of HAP and CTAC-HAP. After thermal treatment, the specific surface area of both pure HAP and CTAC-HAP were reduced. The sharp rod morphology of CTAC-HAP was changed into a round shape with a smaller aspect ratio after the heat treatment. The morphological change by thermal treatment was also observed in pure HAP. Therefore, the morphological change and decrease of the specific surface area suggested that pores from the removal of CTAC during thermal treatment were not retained.

Enhance degradation of insecticide chlorpyrifos by iron salts and potassium persulfate during zerovalent iron treatment in aqueous solution

  • Rahman, M. Mokhlesur;Hwang, Jung-In;Kwak, Se-Yeon;Kim, Jang-Eok
    • Journal of Applied Biological Chemistry
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    • v.61 no.4
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    • pp.383-389
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    • 2018
  • Degradation of the insecticide O,O-diethyl O-3,5,6-trichloro-2-pyridyl phosphorothioate (chlorpyrifos) in aqueous solution was investigated using iron salts and potassium persulfate during ZVI treatment through a series of batch experiments. The degradation rate of chlorpyrifos increased with increases in the concentrations of iron salts and potassium persulfate in the aqueous system. Ferric chloride was found to be the most effective iron salt for the ZVI-mediated degradation of chlorpyrifos in aqueous solution. Further, the iron salts tested could be arranged in the following order in terms of their effectiveness: $FeCl_3$> $Fe_2(SO_4)_3$> $Fe(NO_3)_3$. The persulfate-ZVI system could significantly degrade chlorpyrifos present in the aqueous medium. This revealed that chlorpyrifos degradation by treatment with $Fe^0$ was promoted on adding ferric chloride and potassium persulfate. The kinetics of the degradation of chlorpyrifos by persulfate-amended $Fe^0$ was higher than that for iron-salt-amended $Fe^0$. This suggests that using a sequential $Fe^0$ reduction-ferric chloride or $Fe^0$ reduction-persulfate process may be an effective strategy to enhance the removal of chlorpyrifos in contaminated water.

Clean effect of a cetylpyridinium chloride-based mouthwash on removable orthodontic appliances (염화세틸피리디늄 계열 구강세정제의 가철성 교정장치에 대한 세정효과)

  • Da-Seul Ha;Kyung-Hee Lee
    • Journal of Korean society of Dental Hygiene
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    • v.23 no.4
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    • pp.227-234
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    • 2023
  • Objectives: Cetylpyridinium chloride CPC-based mouthwashes are well known to have no harmful ingredients in the mouth and can be used for a long time. The purpose of this study was to evaluate the effect of using CPC-based mouthwashes to suppress the biofilm formation and antibiotics for handling orthodontic appliances. Methods: To measure the antibacterial effect, Streptococcus mutans (S. mutans) cultured orthodontic appliances were precipitated in Gargreen and Polident for 5 minutes, incubated at 37℃ for 24 hours(h). In order to measure the biofilm removal effect, the degree of biofilm formation on the orthodontic appliances was stained with a methylene blue and the difference before and after was compared using image J software program (NIH Image J; NIH, Bethesda, MD). Results: The viability of S. mutans according to the concentration showed that Gargreen and Polident inhibited colony formation compared to the control, respectively (p<0.01). The degree of biofilm formation was significantly higher in the control, however both Gargreen and Polident significantly reduced it compared to the before and after condition on removable orthodontic appliances (p<0.01). Conclusions: This study suggests that the use of Gargreen, a cetylpyridinium chloride based oral cleaning cleanser, could be replaced by Polident for antibacterial effect and biofilm formation on removable orthodontic appliances.

Sodium/chloride-Dependent Transporters: Elucidation of Their Properties Using the Dopamine Transporter

  • Caron, Marc G.
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1994.04a
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    • pp.88-93
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    • 1994
  • The mechanisms controlling the intensity and duration of synaptic transmission are numerous. Once an action potential reaches a nerve terminal, the stored neurotransmitters are released in a quantum fashion into the synaptic cleft. At that point neurotransmitters can act on post-synaptic receptors to elicit an action on the post-synaptic cell or net at so-called auto-receptors that are located on the presynaptic side and which often regulate the further release of the neutotransmitter. Whereas the action of the neurotransmitter receptors is regulated by desensitization phenomenon, the major mechanism by which the intensity and duration of neurotransmitter action is presumably regulated by either its degradation or its removal from the synaptic cleft. In the central nervous system, specialized proteins located in fe plasma membrane of presynaptic terminals function to rapidly remove neurotransmitters from the synaptic cleft in a sodium chloride-dependent fashion. These proteins have been referred to as uptake sites or neurotransmitter transporters. Once taken up by the plasma membrane transporters, neurotransmitters are repackaged into secretory vesicles by distinct transporters which depend on a proton gradient.

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PCBs 오염토양의 생물학적 처리

  • Na In-Uk;Hwang Gyeong-Yeop;Choi Ji-Won;Kim Seon-Mi;Choi Su-Jin
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.49-53
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    • 2006
  • The possibility of removal of PCBs (Polychlorinated Biphenyls) in soil was studied using biological method. The effects of soil and co-substrate on both PCBs reduction rate and chloride ion concentration in soil were investigated. It was shown that PCBs concentration of all the soils used in this study were reduced from 5ppm to below 1ppm after 60days, also chloride ion concentration in slurry increased, Results showed that leaf mold and humic acid as co-substrate do not seem to be effective for biological treatment of PCBs in soil,

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Evaluation on the Properties of Modified-sulfur Concrete as a Basic Study for Development of Anti-corrosive Concrete (내부식성 콘크리트 개발을 위한 기초연구로서 개질유황 혼합 콘크리트의 물성 평가)

  • Park, Sang-Soon;Na, Ok-Jung
    • Corrosion Science and Technology
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    • v.15 no.1
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    • pp.28-37
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    • 2016
  • Due to the increased construction of offshore concrete structures and the use of de-icing salts for the purpose of snow removal, the needs for the development of anti-corrosive concrete are increasing. To solve these problems, an evaluation of the mechanical and durability properties for concrete were conducted by mixing modified-sulfur as 0 %, 5 %, 10 %, 15 % cement weight ratio. Both strengths and the properties affecting durability such as water absorption coefficient, chloride ion permeability, accelerated carbonation resistance, rapid freezing and thawing, and chemical resistance were evaluated. All evaluations performed were according to the test specifications associated KS. The results indicate that mixing of modified-sulfur lowed chloride ion permeability and improved chemical resistance.

Decoorizatiion of Kraft Pulp Bleaching Effluent by White -rot Fungi (백색부후균에 의한 크라프트 펄프 표백폐수의 탈색)

  • 조남석;이재원;박종문;최태호;안드레레오노비치
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.4
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    • pp.58-68
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    • 1999
  • This experiment was to investigate decoloization characteristics of E1 effluents from the bleaching plant of pulp mill with three white-rot fungi(Trametes versicolor, Ganoderma appanatum and Pleurotus ostreatus).In addition, the effect of carbon and nitrogen resources was discussed on its decolorization. The color removal of E1 effluent during shaking and stationary cultures were 72% and 80%, respectively. Stationary culture was more effective on decolorization of E1 effluent compared to the shaking culture. The optimum inoculum weight was 1.0g based on dry weight of mycelia . The decolorization medium I showed 88% of the color removal of E1 effluent with in one day cultivation of T.versicolor and P.ostreatus . Color removal was increased from 87% to 90%. T.versicolor and P.ostreatus by the addition of 0.5% glucose. By addition of nitorgen sources(ammonium sulfate and ammonium choride), medium was much higher than that of carbon source. With 0.1% ammoniumm sulfate, P.ostreatus and T.versicolor showed 94% and 92% of the color removal within one day of cultivation , respectively. On decolorization medium II, T.versicolor and P.ostretus were 94% of oclor removal with addition of carbon source. The addition of nitrogen source was much more efficient than that of carbon source. With 0.1% amminium chloride, T.versicolor and P.ostreatus showed 95% of its color removal . The decolorization medium II was higher color removal than medium I, and also MnP and laccase were produced. However, the decolorization medium I produced a little MnP and laccase activity. It could be suggested that MnP and laccase may play an important role in decolorization of E1 effluent.

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Removal of Arsenic in Synthesis Method and Characteristics of Fe(III)-ettringite (비소제거를 위한 Fe(III)-ettringite 합성방법 및 특성 연구)

  • Hong, Seong-Hyeok;Park, Hye-Min;Choi, Won-Ho;Park, Joo-Yang
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.1
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    • pp.15-21
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    • 2011
  • Arsenic is one of the most abundant contaminant found in waste mine tailings, because of it's carcinogenic property, the countries like United states of America and Europe have made stringent regulations which govern the concentration of arsenic in drinking water. The current study focuses on different treatment methods for removal of arsenic from waste water. Treatment method the high strength arsenic waste water is treated with Fe(III)-ettringite by co-precipitation method. Number of experiments were carried out to decide the optimal dosage of Fe(III)-ettringite to treat arsenic waste water. The Fe(III)-ettringite was synthesized by taking appropriate equivalent ratios of calcium oxide and ferric chloride in proportion to the arsenic. The best removal efficiencies of 94% were observed at a As/(Ca: Fe) ratio of 1:3. The maximum removal of arsenic was observed in pH range of 12. But as the pH increases the arsenic removal efficiency decreases as portlandite is formed in the pH above 12. The analysis of surface of precipitate conform the needle like structure of ettringite. This treatment technique has promising features such as, the chemicals required in the treatment as well as the sludge generated can be reduced. The operating pH range is in alkaline region which is advantageous over traditional treatment process which has lower pH. Also the co-precipitation not only helps in removal of arsenic but also heavy metals.