• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.5
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• pp.66-74
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• 2016

The objective of this study is the investigation of the influence of carbonation on the penetration of chloride ions in reinforced concrete sections for different mix proportions and environmental conditions. A comprehensive numerical model based on the change of the pore structure and the chemical equilibrium was used for this combined action of carbonation and chloride ingress. The empirical formulae of some parameters in this model are estimated according to numerous experimental data. And, a set of data analysis is carried out to simplify the estimation of model variables to reduce the computational cost. A coupled simulation of the transports of carbon dioxide, chloride ions, heat and moisture is carried out. Then, the parametric analysis is given and the numerical results show that the effect of carbonation of the free chloride ingress is significant and depends on the binder types and concrete mix proportion.

• Computers and Concrete
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• v.22 no.3
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• pp.319-326
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• 2018

RC (Reinforced Concrete) members are always subjected to loading conditions and have construction joints when constructed on a big scale. Service life for RC structure exposed to chloride attack is usually estimated through chloride diffusion test in sound concrete, however the test is performed without consideration of effect of loading and joint. In the present work, chloride diffusion coefficient is measured in concrete cured for 1 year. In order to evaluate the effect of applied load, cold joint, and mineral admixtures, OPC (Ordinary Portland Cement) and 40%-replaced GGBFS (Ground Granulated Blast Furnace Slag) concrete are prepared. The diffusion test is performed under loading conditions for concrete containing cold joint. Investigating the previous test results for 91 days-cured condition and the present work, changing diffusion coefficients with applied stress are normalized considering material type and cold joint. For evaluation of service life in RC continuous beam with 2 spans, non-linear analytical model is adopted, and service life in each location is evaluated considering the effects of applied stress, cold joint, and GGBFS. From the work, varying service life is simulated under various loading conditions, and the reduced results due to cold joint and tensile zone are quantitatively evaluated. The effect of various conditions on diffusion can provide more quantitative evaluation of chloride behavior and the related service life.

• International Journal of Concrete Structures and Materials
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• v.8 no.3
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• pp.201-212
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• 2014

Sixteen reinforced concrete laboratory specimens were used to evaluate a number of corrosion prevention methods under an accelerated (6 months) testing program. The use of galvanic thermal sprayed zinc, galvanic embedded anodes, a tri-silane sealer, an acrylic coating, and an epoxy/polyurethane coating was evaluated. The specimens received various treatments prior to exposure to accelerated corrosion. The performance of the treatments was evaluated with respect to corrosion currents, chloride ingress, extent of cracking, severity of rust staining, and visual inspection of the reinforcing steel after the conclusion of testing and dissection. Results indicated that the tri-silane sealer, the conjoint use of galvanic thermal sprayed zinc and epoxy/polyurethane coating, the epoxy/polyurethane coating, and acrylic coating performed better than the other methods tested. Higher chloride concentrations were measured in the vicinity of embedded zinc anodes.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.05b
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• pp.249-252
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• 2005

Chloride ingress is a common cause of deterioration of reinforced concrete structures. Modeling the chloride ingress is an important basis for designing reinforced concrete structures and for assessing the reliability of an existing structure. The modelling is also needed for predicting the deterioration of a reinforced structure. This paper presents an approach for the probabilistic modeling of the chloride-induced corrosion of reinforcement steel in concrete structures that takes into account the uncertainties in the physical models. The parameters of the models are modeled as random variables and the distribution of the corrosion time and probability of corrosion are determined by using Monte Carlo simulation. The predictions of the proposed model is very effective to do the decision-making about initiation time and deterioration degree.

• Corrosion Science and Technology
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• v.8 no.2
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• pp.81-88
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• 2009

Chloride induced corrosion of steel reinforcement inside concrete is a major concern for concrete structures exposed to a marine environment. It is well known that transport of chloride ions in concrete occurs mainly through ionic/molecular diffusion, as a gradient of chloride concentration in the concrete pore solution is set. In the process of chloride transport, a portion of chlorides are bound in cement matrix then to be removed in the pore solution, and thus only the rest of chlorides which are not bound (i.e. free chlorides) leads the ingress of chlorides. However, since the measurement of free/bound chloride content is much susceptible to environmental conditions, chloride profiles expressed in total chlorides are evaluated to use in many studies In this study, the capacity of chloride binding in cement matrix was monitored for 150 days and then quantified using the Langmuir isotherm to determine the portions of free chlorides and bound chlorides at given total chlorides and the redistribution of free chlorides. Then, the diffusion of chloride ion in concrete was modeled by considering the binding capacity for the prediction of chloride profiles with the redistribution. The predicted chloride profiles were compared to those obtained from conventional model. It was found that the prediction of chloride profiles obtained by the model has shown slower diffusion than those by the conventional ones. This reflects that the prediction by total chloride may overestimate the ingress of chlorides by neglecting the redistribution of free chlorides caused by the binding capacity of cement matrix. From the evaluation, it is also shown that the service life prediction using the free chloride redistribution model needs different expression for the chloride threshold level which is expressed by the total chlorides in the conventional diffusion model.

• Journal of the Korea institute for structural maintenance and inspection
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• v.26 no.4
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• pp.57-64
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• 2022

Chloride, which is one of the main deterioration factors in reinforced concrete structures, can degrade the performance of the structure due to chloride-induced corrosion of steel. Chloride content at steel depth or the rate of chloride penetration is necessary to determine deterioration of reinforced concrete or to calculate initiation time of steel corrosion caused by chloride attack. Chlorides in concrete are generally identified with typical two methods including chloride profiling using potentiometric titration method and discoloration method using AgNO₃ solution. The former is advantageous to estimate chloride penetration rate (diffusion coefficient in general) with measured chloride contents directly, but it is laborious. In the case of latter, while the result is obtained easily with the range of discoloration, the error may occur depending on workmanship when the depth of chloride ingress is measured. This study shows that chloride penetrated depth is evaluated with the results obtained from discoloration method through image analysis, thereby the error is minimized by workmanship. In addition, the effect of micro-crack in concrete is studied on chloride penetration. In conclusion, the depth of chloride penetration was quantified with image analysis and as it was confirmed that chlorides can rapidly penetrate through micro-cracks, caution is especially required for cracks in concrete structure.

• Journal of the Korea institute for structural maintenance and inspection
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• v.26 no.6
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• pp.230-237
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• 2022

It is essential that service life of reinforced concrete structures in economic and safety aspects should be secured. It is well-known that chloride attack is a typical deterioration mechanism in field concrete structures. To prevent serious accidents like collapse, many studies have been conducted to increase resistance of chloride ingress using concrete mixed with GGBS. The usage of GGBS concrete is nowadays mandatory. Since most concretes in the field are unsaturated, study regarding chloride absorption is necessary, but many studies have focused on the chloride diffusion phenomenon. Methods for evaluating chloride absorption are cost and improper in the field. It is necessary to develop a simple method for evaluating chloride absorption in practice. This study evaluated resistance of chloride ingress in GGBS concretes with impedance measurement and absorption test. From the results, it was confirmed that the contents of absorbed chloride were linearly correlated with the measured electrical resistivities (or conductivities) in the concrete. At the end of the test, the electrical conductivities were 250.8 S/m (w/b=0.4) and 303.1 S/m (w/b=0.6) for PC concretes, and 2.6 S/m (w/b=0.4) and 64.4 S/m (w/b=0.6) for GGBS concretes, respectively. Considering influencing factors for chloride absorption and impedance measurement, chloride ingress into concrete is mainly affected by pore structures due to replacement of GGBS. Especially, formations of pore structure are different with binder, thereby binders should be considered in building reinforced concrete structures exposed to chloride environments.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.05a
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• pp.743-748
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• 2002

Chloride ingress into concrete followed by reinforcement corrosion and deterioration of concrete structures is a major problem for many structures under chloride attacks. Large-scale concrete structures directly exposed to seawater such as SeoHae Grand Bridge are increasingly constructed along the coast in Korea. It is necessary to investigate the environmental conditions of concrete structures exposed to chloride attacks. In this study, the air-borne chloride contents of highway bridges exposed to marine environment in Korea were measured.

• Journal of the Korea Concrete Institute
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• v.17 no.5 s.89
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• pp.679-686
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• 2005

The corrosion of reinforcement induced by chloride ingress is the main deterioration cause of coastal reinforced concrete structures. In this paper, an experimental study was executed to investigate the effect of the kinds and replacement ratios of mineral admixtures (fly-ash, ground granulated blast-furnace slag silica fume and meta-kaolin), W/B and curing time on chloride diffusion of concrete by long-time immersion test in chloride solution. According to the result, the use of mineral admixtures was effective in improving the resistant to chloride ingress. The chloride penetration depth and diffusion coefficient were decreased as replacement ratios of mineral admixture were increased. The kind and replacement ratio of the mineral admixture are more important than the W/B in reducing the chloride diffusion of concrete. Chloride binding capacity of mineral admixture, which was sequenced in the order of MK

• Smart Structures and Systems
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• v.21 no.3
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• pp.305-320
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• 2018

The second half of the 20th century was marked with a significant raise in amount of railway bridges in Austria made of reinforced concrete. Today, many of these bridges are slowly approaching the end of their envisaged service life. Current methodology of assessment and evaluation of structural condition is based on visual inspections, which, due to its subjectivity, can lead to delayed interventions, irreparable damages and additional costs. Thus, to support engineers in the process of structural evaluation and prediction of the remaining service life, the Austrian Federal Railways (${\ddot{O}}$ BB) commissioned the formation of a concept for an anticipatory life cycle management of engineering structures. The part concerning concrete bridges consisted of forming a bridge management system (BMS) in a form of a web-based analysis tool, known as the LeCIE_tool. Contrary to most BMSs, where prediction of a condition is based on Markovian models, in the LeCIE_tool, the time-dependent deterioration mechanisms of chloride- and carbonation-induced corrosion are used as the most common deterioration processes in transportation infrastructure. Hence, the main aim of this article is to describe the background of the introduced tool, with a discussion on exposure classes and crucial parameters of chloride ingress and carbonation models. Moreover, the article presents a verification of the generated analysis tool through service life prediction on a dozen of bridges of the Austrian railway network, as well as a case study with a more detailed description and implementation of the concept applied.