• Title/Summary/Keyword: Chloride content

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The waste reduction technology of chloride contaminated red-mud from by-product of Bayer process

  • Shin, Hee-Young;Hyun, Jong-Yeong;Masuda, Kaoru;Ohya, Hitoshi;Endoh, Shigehisa
    • 한국지구물리탐사학회:학술대회논문집
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    • 2003.11a
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    • pp.598-602
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    • 2003
  • The general red-mud minerals consist of hematite, sodalite, anatase, quartz, gibbsite and miner impurities. This gives serious environmental damage for the ocean disposal. It mixed with chloride compound and the content of chlorine is about 2,000-3,000ppm. This paper can be suggested the chloride reduction technology that is applied basically mineral processing by physical separation. Then it can be possible to produce the totally 24wt. $\%$ useful red-mud which chloride content is less then 400ppm.

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Change of Nonvolatile Amines During Fermentation of Anchovy (멸치젓 숙성중 불휘발성아민의 함량 변화)

  • 정종순;이영근;박법규;류병호
    • Journal of Food Hygiene and Safety
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    • v.4 no.1
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    • pp.37-44
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    • 1989
  • The present work was to study the changes of nonvolatile amines and microorganism in fermentation of anchovy during 12 weeks with addition of various concentration of sodium chloride. Changes of histamine occured significantly during fermentation of anchovy with 10, IS, 20% salt and 10% mixed salts (5.0% NaCl+5.0% KCl). A maximum histamine content was observed in anchovy fermented for 6 weeks while the change of histamine content was not with addition of 20% sodium chloride. Tyramine was found at highest contents in the fermented anchovy of 10% mixed salts and increased markedly in all anchovy fermented for 8 weeks. Cadaverine content was higher in fermented for all fermentation periods than in raw. During fermentation cadaverine contents increased significantly in fermented with 10% mixed salts. In contrast with that, fermented anchovy with 20% sodium chloride had very low those content and high sodium chloride concentration had influenced on amine formation. Although the highest content of putrescine was observed in fermented for 8 weeks, those content was not changed significantly during fermantation. The growth of Microflora, Achromobacter, Aeromonas and Pseudomonas were found in the in itial fermantation and Micrococus, Pediococcus, Lactobacillus and Saccharomyces were found during all fermentation periods.

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Effects of Manganese Chloride on Chlorophyll, Free Proline and SOD Activity of Rice Seedling (염화망간 처리가 벼 유묘의 엽록소, 유리 Proline 및 SOD 활성에 미치는 영향)

  • 김상국;이상철
    • Korean Journal of Plant Resources
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    • v.12 no.2
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    • pp.166-169
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    • 1999
  • The experiment was conducted to find the changes of early growth and chemical components such as chlorophyll content, superoxide dismutase(SOD) activity, free proline content on the different manganese chloride concentration(2,500, 3,500 and 4,500ppm) in rice seedling. Root growth was decreased in highest concentration, 4,500 ppm of Mn compared with the control and germination rate was also decreased 43% at 4,500 ppm of Mn. Chlorophyll content was decreased at Mn 4,500ppm with 1.16mg. Free proline content at 3 day after germination in Mn 4,500ppm was highest relative to the other manganese chloride concentrations. SOD activity was gradually increased as manganese chloride concentration was increased. As a result, it was suggested that an increment of free proline and SOD activity results from the higher manganese chloride concentration.

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Effects of Combined Attacks on Chloride Diffusivity in Concrete (콘크리트내의 염소이온 침투특성에 미치는 복합 열화작용의 영향)

  • 오병환;강의영;정상화;장승엽;인광진;서정문
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.05a
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    • pp.665-670
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    • 2001
  • The studies on chloride diffusion of concrete have been done so far by many researchers. However, there are few studies that present the effects of other attacks on chloride diffusion properties. Therefore, in this study the experiments are carried out to show the effects of combined attacks, such as carbonation, sulfate attacks, on chloride diffusivity in concrete. The specimens are made by varying cement type and replacement ratio of fly ash. The results show that cement type and replacement of fly ash do not affect greatly chloride diffusion properties. And concrete treated by combined attacks show a little higher chloride content than those treated by chloride solution only. Therefore, the effects of these factors should be taken into account in predicting the penetration of chloride ion in concrete.

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A Hydration based Model for Chloride Penetration into Slag blended High Performance Concrete

  • Shin, Ki-Su;Park, Ki-Bong;Wang, Xiao-Yong
    • Architectural research
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    • v.20 no.1
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    • pp.27-34
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    • 2018
  • To improve the chloride ingress resistance of concrete, slag is widely used as a mineral admixture in concrete industry. And currently, most of experimental investigations about non steady state diffusion tests of chloride penetration are started after four weeks standard curing of concrete. For slag blended concrete, during submerged chloride penetration tests periods, binder reaction proceeds continuously, and chloride diffusivity decreases. However, so far the dependence of chloride ingress on curing ages are not detailed considered. To address this disadvantage, this paper shows a numerical procedure to analyze simultaneously binder hydration reactions and chloride ion penetration process. First, using a slag blended cement hydration model, degree of reactions of binders, combined water, and capillary porosity of hardening blended concrete are determined. Second, the dependences of chloride diffusivity on capillary porosity of slag blended concrete are clarified. Third, by considering time dependent chloride diffusivity and surface chloride content, chloride penetration profiles in hardening concrete are calculated. The proposed prediction model is verified through chloride immersion penetration test results of concrete with different water to binder ratios and slag contents.

Comparison of Diffusion Characteristic of Chloride According to the Condition of Hardened Concrete (경화된 콘크리트의 상태에 따른 염화물 확산특성 비교)

  • Leem Young-Moon;Yang Eun-Ik;Min Seok-Hong
    • Journal of the Korean Society of Safety
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    • v.19 no.3 s.67
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    • pp.89-94
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    • 2004
  • Most reinforcements in concrete are constructed by steel. Corrosion of reinforcement is the main cause of damage and early failure of reinforced concrete structures. The corrosion is mainly professed by the chloride ingress. In general, chloride in concrete can be discriminated by two components, total chloride and fire chloride. This paper provides a testing method on the coefficient of chloride diffusion in concrete and the relationship between total chloride and free chloride in concrete for the composition of predicting model on diffusion rate of chloride. In order to complete this predicting model, this study will use chloride penetration characteristic, diffusion coefficient and experiment of color change on silver nitrate solution. This predicting model is going to help that grasp special quality on salt content inclusion of concrete structure that is exposed in chloride environment. Accurate predicting model can be effectively used not only in selecting of repair time but also in preventing from various deteriorations.

Effects of Concrete Properties and Testing Method! on Coefficient of Chloride Diffusion in Hardened Concrete (콘크리트 물성 및 시험법이 콘크리트 염화물 확산 계수에 미치는 영향)

  • 김명유;양은익;최중철;이광교;민석홍;이성태
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.699-704
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    • 2003
  • Corrosion of reforcement is the main cause of damage and early failure of reinforced concrete structures. The corrosion is mainly progressed by the chloride ingress. In this paper, an experimental study is executed to investigate the effect of concrete properties and testing method on the coefficient of chloride diffusion. Also, it is compared that the relationship between total chloride and free chloride in concrete. According to this experiment results, w/c ratio and testing method effect on chloride diffusion coefficient of concrete. As w/c ratio is increased, diffusion coefficient in concrete is also increased. Diffusion coefficient obtained by each testing method show the different value, respectively. Also, the content of free chloride in 7days curing concrete is increased as w/c ratio is increased.

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Assessment of some parameters of corrosion initiation prediction of reinforced concrete in marine environments

  • Moodi, Faramarz;Ramezanianpour, Aliakbar;Jahangiri, Ehsan
    • Computers and Concrete
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    • v.13 no.1
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    • pp.71-82
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    • 2014
  • Chloride ion ingress is one of the major problems that affect the durability of concrete structures such as bridge decks, concrete pavements, and other structures exposed to harsh saline environments. Therefore, durability based design of concrete structures in severe condition has gained great significance in recent decades and various mathematical models for estimating the service life of rein-forced concrete have been proposed. In spite of comprehensive researches on the corrosion of rein-forced concrete, there are still various controversial concepts in quantitation of durability parameters such as chloride diffusion coefficient and surface chloride content. Effect of environment conditions on the durability of concrete structures is one of the most important issues. Hence, regional investigations are necessary for durability based design and evaluation of the models. Persian Gulf is one of the most aggressive regions of the world because of elevated temperature and humidity as well as high content of chloride ions in seawater. The aim of this study is evaluation of some parameters of durability of RC structures in marine environment from viewpoint of corrosion initiation. For this purpose, some experiments were carried out on the real RC structures and in laboratory. The result showed that various uncertainties in parameters of durability were existed.

On Probability Distribution of Chloride Diffusion Coefficient for Recycled Aggregate Concrete

  • Ying, Jingwei;Xiao, Jianzhuang;Meng, Qiujiang
    • International Journal of Concrete Structures and Materials
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    • v.10 no.1
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    • pp.61-73
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    • 2016
  • In predicating the probability distribution of chloride diffusion coefficient of recycled aggregate concrete ($D_{RAC}$), the morphological characteristics of three phases, i.e., the old attached mortar, the natural aggregate and the new mortar, should all be taken into account. The present paper attempts to develop a probability density evolution method (PDEM) to achieve this. After verifying the derived PDEM results with experimental results, the effects of old attached mortar to the $D_{RAC}$ are examined in a quantitative manner. It is found that (1) the variation of the attached mortar content is much sensitive to $D_{RAC}$; (2) given the probability distribution of the content and chloride diffusion coefficient of old mortar, the probability distribution of DRAC can be analysed based on the PDEM; and (3) the critical chloride diffusion coefficient at a certain assurance rate can be obtained by the PDEM. The analysis results of this investigation will be valuable to the durability design for RAC.

Miscibility and Mechanical Properties of Polycaprolactone-polyamide Block Copolymer/Poly(vinyl chloride) Blend (Polycaprolactone-폴리아미드 블록공중합체/Poly(vinyl chloride) 블렌드의 상용성과 기계적 성질)

  • 안소봉;이하용;정한모
    • Polymer(Korea)
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    • v.24 no.1
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    • pp.128-132
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    • 2000
  • The miscibility between poly(vinyl chloride) (PVC) and polycaprolactone (PCL)-polyamide block copolymer whose content of PCL block is 62.7 wt%, was studied by differential scanning calorimetry. The PCL segment in the block copolymer and PVC has the miscibility showing single glass transition temperature (T$_{g}$). The miscible PVC molecule inhibited the crystallization of PCL segment, making an amorphous homogeneous phase of PCL and PVC segments at high PVC content. The blends had rubber elasticity at the temperature range between the T$_{g}$ of amorphous homogeneous phase of PCL and PVC segments and the melting temperature of polyamide segment, when both phases coexist.ist.

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