• Title/Summary/Keyword: Chloride Ion

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Mechanical Properties and Durability of Asphalt Emulsion-Modified Cement Mortars

  • Song Hun;Do Jeong-Yun;Soh Yang-Seob
    • Journal of the Korea Concrete Institute
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    • v.17 no.3 s.87
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    • pp.467-472
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    • 2005
  • Asphalt emulsion is manufactured by the emulsification of asphalt, and is considered as an energy-saving, ecologically safe material because it does not need any heating processes with gas emission and fire hazard in its use. This study is concerned with evaluating the feasibility of the use of an asphalt emulsion as a poly-meric admixture. Asphalt-modified mortars using an experimentally manufactured asphalt emulsion were prepared with various polymer-cement ratios, and tested far the mechanical properties such as strengths and adhesion and the properties related to durability such as water absorption, permeation, carbonation and chloride ion penetration. As a result, the waterproofness, carbonation resistance and chloride ion penetration resistance of the asphalt-modified mortars were markedly improved with an increase in the polymer-cement ratio, but their compressive strength and adhesion to mortar substrates were reduced with increasing polymer-cement ratio. Therefore, it is recommended to control their polymer-cement ratio to be $10\%$ or lower in their practical applications. Further study to improve their compressive strength and adhesion is needed.

Analysis of physical properties of high-performance concrete using domestic low-cost silica fume (국산 저가형 실리카퓸을 이용한 고성능 콘크리트의 물리적 특성 분석)

  • Kim, Sang Do;Yun, Kyung Ku;Ham, Seung Yeon;Lee, Kyeo Re
    • Journal of Industrial Technology
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    • v.37 no.1
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    • pp.32-36
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    • 2017
  • In this study, as part of a research on the development of economical high-performance concrete with high strength and high quality, the physical properties of high-performance concrete were analyzed by substituting a certain amount of low-cost domestic silica fume exempted from the re-importation type distribution structure of the domestic production and the existing high-priced silica fume distribution structure. Performing tests to identify the physical properties of the fresh and hardened concrete and durability analogy of the concrete which use low-cost domestic silica fume and imported silica fume, the chloride ion penetration resistance test result showed that the strength difference between the low-cost silica fume and the imported silica fume is not big but the strength of the low-cost silica fume was measured higher than the imported silica fume. The chloride ion penetration resistance of all variables was measured as "very low". Since the low-cost domestic silica fume can be used as a high-performance admixture of concrete, the results suggest that it is possible to produce a more economical high-performance concrete.

Effects of Hafnium Addition on the Pitting Corrosion Behavior of Ti Alloys in Electrolyte Containing Chloride Ion (염소이온 함유된 용액에서 Ti합금의 부식특성에 미치는 Hafnium함량의 영향)

  • Kim, Sung-Hwan;Choe, Han-Cheol
    • Corrosion Science and Technology
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    • v.11 no.5
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    • pp.191-195
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    • 2012
  • The aim of this study was to investigate effects of hafnium content on the corrosion behavior of Ti alloys in electrolyte containing chloride ion. For this study, Ti-Hf binary alloys contained 10 wt%, 20 wt% and 30 wt% Hf were manufactured in a vacuum arc-melting furnace and subjected to heat treatment for 12h at $1000^{\circ}C$ in an argon atmosphere. The pitting corrosion behavior of the specimens was examined through potentiodynamic and potentiostatic tests in 0.9 wt% NaCl electrolyte at $36.5{\pm}1^{\circ}C$. The corrosion morphology of Ti-xHf alloys was investigated using optical microscopy (OM) and X-ray diffractometer (XRD). From the optical microstructures and XRD results, needle-like martensite ($\alpha$') phases of the Ti-xHf alloys increased with an increase of Hf addition. Corrosion current density $(I_{corr})$ and current density $(I_{300mV})$ in passive region decreased, whereas, corrosion potential increased with Hf content. At the constant potential ($300mV_{SCE}$), current density decreased as time increased.

Corrosion behaviors of cement mortar specimens with different cover thickness in natural sea water

  • Jeong, Jin-A;Jin, Chung-Kuk;Jeong, Eun-Seok
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.2
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    • pp.107-111
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    • 2016
  • This paper presents electrochemical corrosion behaviors of cement mortar specimens in the high salinity condition. Chloride ion is known as the most detrimental parameter to cause the corrosion in reinforced concrete. Increasing the concrete cover thickness is one of the corrosion protection methods against chloride ion; so, this study mainly focuses on the effects of mortar cover thickness on corrosion protection. In specimens, rebar, which was a height of 200 mm and a diameter of 10 mm, was installed at the center of the small size form. Later on, mortar was injected into the form, and 10, 20, 30, 40, and 50 mm of the different mortar cover thicknesses were selected. Potential measurements, linear polarization resistance tests, and cyclic potentiodynamic polarization tests were performed for specimens that were exposed to seawater. These results were compared with visual inspection results of rebar. The results show that an increase in the cover thickness contributes to corrosion protection. In addition, the result of electrochemical corrosion tests generally agreed with that of an autopsy visual inspection.

Omega Rhodopsins: A Versatile Class of Microbial Rhodopsins

  • Kwon, Soon-Kyeong;Jun, Sung-Hoon;Kim, Jihyun F.
    • Journal of Microbiology and Biotechnology
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    • v.30 no.5
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    • pp.633-641
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    • 2020
  • Microbial rhodopsins are a superfamily of photoactive membrane proteins with the covalently bound retinal cofactor. Isomerization of the retinal chromophore upon absorption of a photon triggers conformational changes of the protein to function as ion pumps or sensors. After the discovery of proteorhodopsin in an uncultivated γ-proteobacterium, light-activated proton pumps have been widely detected among marine bacteria and, together with chlorophyll-based photosynthesis, are considered as an important axis responsible for primary production in the biosphere. Rhodopsins and related proteins show a high level of phylogenetic diversity; we focus on a specific class of bacterial rhodopsins containing the '3 omega motif.' This motif forms a stack of three non-consecutive aromatic amino acids that correlates with the B-C loop orientation and is shared among the phylogenetically close ion pumps such as the NDQ motif-containing sodium-pumping rhodopsin, the NTQ motif-containing chloride-pumping rhodopsin, and some proton-pumping rhodopsins including xanthorhodopsin. Here, we reviewed the recent research progress on these 'omega rhodopsins,' and speculated on their evolutionary origin of functional diversity.

The Change of Concrete Durability under High Temperature (고온수열 전후의 콘크리트 내구성 변화에 관한 연구)

  • Park, Jae-Hong;Jeon, Bong-Min;Oh, Sang-Gyun;Park, Dong-Cheon
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.509-512
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    • 2008
  • The nitrogen adsorption method was used to evaluate the change fine pore structure of concrete under high temperature. The mechanical properties and chloride ion diffusion coefficient were also measured. Two dimension FEM model for the life expectancy of RC structure was built considering the effect of high temperature. The porosity under 0.01${\mu}m$ decreased in proportion to the temperature. However, that of $0.01{\mu}m{\sim}0.1{\mu}m$ increased. The strength decreased and the chloride ion diffusion coefficient increased in the temperature range of $200{\sim}600^{\circ}C$.

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Effect of Cingulate Cortical Ablation upon Gastric Secretion in Rats (흰쥐에서 대상회전 제거가 위액분비에 미치는 영향)

  • Park, Hyoung-Jin;Ahn, Byung-Tae;Jo, Yang-Hyeok
    • The Korean Journal of Physiology
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    • v.11 no.2
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    • pp.67-71
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    • 1977
  • This study was undertaken to investigate the effect of cingulate cortical ablation upon gastric secretion and its components in rats. 23 male rats were divided into the cingulate(N=9) and the operated control(N= 14) groups. Cingulate cortex was ablated through a slit-shaped opening(1 mm in width, 5 mm in length) which was made symmetrically on both sides of, and parallel to, the sagittal suture by removing a bone flap from frontal bone on each side. In the operated control group, the surgical procedure was ended by the removal of the bone flap. Under light ether anesthesia, experimental animals were placed in a restraining jacket of fine mesh wire and gastric juice was collected for 5 hours via a canula which had been inserted through the anterior abdominal wall into the antral portion of the lumen of the stomach. Volume of the gastric juice was measured, and total acid output and free acid output were titrated with 0.04 N NaOH solution by using phenolphthalein and Topfer's reagent at indicator, and chloride ion output was estimated by means of chloridometer. Results obtained were that volume, total acid output, free acid output and chloride ion output of the gastric juice were higher significantly in the cingulate group than in the operated control group. It is inferred from the above results that the cingulate cortex exerts a fascilitatory influence upon gastric secretion and acid output in rats.

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A Study on the Evaluation of Corrosion Resistance of Coated Steel Using Polymer Dispersion (폴리머 디스퍼션을 이용한 강재의 내식성 평가에 관한 연구)

  • Jo, Young-Kug
    • Journal of the Korea Institute of Building Construction
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    • v.3 no.4
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    • pp.103-109
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    • 2003
  • Reinforced concrete structures under sever conditions such as marine structures, bridges and structural constructed with aggregated(dredged front sea). can be deteriorated from corrosion of the reinforcing bars. The purpose of this study is to evaluate the corrosion reflectance of coated steel using polymer dispersion and polymer cement slurry. Polymer dispersion and polymer cement slurry with various polymer types were coated to the surface of bars and steel plate, and tested for accelerated corrosion tests. Tests include adhesion in tension, bending test, chloride ion spray, penetration of NaCl 10% solution and carbonation. From the test results, the corrosive resistance of steel is considerably improved by using polymer dispersion and polymer cement flurry at surface of steel. The difference of the corrosive resistance is hardly recognized according to types of polymer dispersion. The coated steel using polymer dispersion and polymer foment slurry will be improved to a great extent compared to those of plain steel when increasing content of chloride ion in cement concrete.

Solvent Extraction for the Recovery of Copper from Hydrochloric Etching Solutions by Alamine336 (염산에칭폐액으로부터 Alamine336에 의한 구리의 용매추출에 관한 연구)

  • 안재우;염재웅
    • Resources Recycling
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    • v.6 no.3
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    • pp.9-14
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    • 1997
  • A study has been made of the rccovery of copper (11) by solvent extraction with Alamine336 (Tri-n-oclylamine) as a extractant from hydrochloric etching solutions. The effect of extractant concentrations, hydrochloric acid, chloride Ion concentrations and phase ratio (organiclaqueaus) on copper extraction were studied. Experimental results showed that the concenl~atiano f extractant and the phase ratio strongly influenced the copper extraction, and the extraction percent of capper Increased at higher hydrochloric acid and chloride ion mncmhation. We proposed that the optimum extrachon stages of copper for continuous extraction process by analysidng thc McCabe-Thielc diagram. Stripping of copper from the loaded organic phases wn be accomplished by pure water (H, O) as a dripping reagent effectively. As the tcmpcrature is increased, thc stripping of copper is enhanced.

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The properties of hydrophobic concrete prepared by biomimetic mineralization method

  • Huang, Chung-Ho;Fang, Hao-Yu;Zhang, Jue-Zhong
    • Computers and Concrete
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    • v.23 no.5
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    • pp.351-359
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    • 2019
  • In this study, the calcium hydroxide, an inherent product of cement hydration, was treated using biomimetic carbonation method of incorporating stearic acid to generate the hydrophobic calcium carbonate on concrete surface. Carbonation reaction was carried out at various $CO_2$ pressure and temperatures and utilizing the Scanning Electron Microscope (SEM), chloride-ion penetration test apparatus, and compression test machine to investigate the hydrophobicity, durability, and mechanical properties of the synthesized products. Experimental results indicate that the calcium stearate may change the surface property of concrete from hydrophilicity to hydrophobicity. Increasing reaction temperature can change the particles from irregular shapes to needle-rod structures with increased shear stress and thus favorable to hydrophobicity and microhardness. The contact angle against water for the concrete surface was found to increase with increasing $CO_2$ pressure and temperature, and reached to an optimum value at around $90^{\circ}C$. The maximum static water contact angle of 128.7 degree was obtained at the $CO_2$ pressure of 2 atm and temperature of $90^{\circ}C$. It was also found that biomimetic carbonation increased the permeability, acid resistance and chloride-ion permeability of the concrete material. These unique results demonstrate that the needle-rod structures of $CaCO_3$ synthetized on concrete surface could enhance hydrophobicity, durability, and mechanical properties of concrete.