• Title/Summary/Keyword: Chloride Ion

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Evaluation on Durability of High Performance Concrete with Expansive Additive and Shrinkage Reducing Admixture (팽창재와 수축저감제를 사용한 고성능 콘크리트의 내구성 평가)

  • Koh, Kyung-Taek;Kang, Su-Tae;Park, Jung-Jun;Ryu, Gum-Sung
    • Journal of the Korea Concrete Institute
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    • v.18 no.2 s.92
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    • pp.205-211
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    • 2006
  • The objective of this study was to evaluate the durability of low shrinkage high performance concrete(LSHPC), which was combined with expansive additives and shrinkage reducing admixtures. We tested for not only LSHPC but also high performance concrete(HPC) and normal concrete(NC) to be compared with the durability of LSHPC. HPC was made in the same water-binder ratio of LSHPC without expansive additives and shrinkage reducing admixture. As a result, it was found that LSHPC had higher compressive and tensile strength than that of HPC. LSHPC showed more excellent performance than HPC and NC in the case of resistance to chloride ion penetration and resistance to carbonation and also showed nearly 100 durability factor in the freeze-thawing test with 500 cycles. From the examination about the watertightness and the pore distribution, it was found that the durability of LSHPC was improved because its hardened cement paste is organized closer. So we can conclude that when LSHPC is applied to structures in field, it is possible to reduce the shrinkage and crack in concrete and improve the durability.

Chemical Forms of Ca, Mg Compounds Occuring in Perilla Leaves and Their Changes after Harvest (깻잎에 있어 Ca, Mg의 존재형태와 수확후의 변화)

  • 최영희
    • Journal of the East Asian Society of Dietary Life
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    • v.11 no.4
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    • pp.274-280
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    • 2001
  • The chemical forms of calcium compounds in perilla leaves and their changes after harvest were investigated. The four types of calcium compounds extracted were as follows: water soluble calcium(F-I: mainly water soluble organic acid salts and calcium ion), IN-sodium chloride soluble calcium(F-II: calcium-pectate and calcium-carbonate), 2%-acetic acid soluble calcium(F-III: calcium-phosphate), and 5%-hydrochloric acid soluble calcium(F-IV: calcium-oxalate). The calcium content of perilla leaves was not found to vary with their age. Relatively high levels of F-l (28.4~39.5) and F-II (34.4~47.4) were found in young and mature leaves while the F-IV constituted 15.6~21.6% of the total calcium. The F-IV calcium contents of perilla. spinach and jaso were 16.8, 42.4 and 22.3%, respectively. In contrast to calcium. magnesium existed as water soluble magnesium at the highest content of 90.6% in spinach while 62.9% and 16.8% of the total magnesium existed as water soluble magnesium in perilla and jaso, repectively. The change in vitamin C and F-IV calcium content were examined for 7 days after harvest. Vitamin C content decreased slowly at the beginning but rapidly from the 4th day after harvest. On the other hand, the F-IV calcium content increased slowly at the beginning and rapidly from the 4th day of observation. This result suggests that the increase in F-IV calcium is related to the decrease in vitamin C content. This phenomena was more distinctly observed at 2$0^{\circ}C$ than 5$^{\circ}C$.

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Effect of Microbe Control and Water Temperature on Early Growth and Yield of Soybean Sprouts (콩 종실의 미생물 제어방법과 수주온도에 따른 콩나물의 초기 생육 및 수율)

  • 배경근;남승우;김경남;황영현
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.47 no.6
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    • pp.453-458
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    • 2002
  • High temperature sterilization method (30min. at $40^{\circ}C$longrightarrow30 min. at $70^{\circ}C$longrightarrow30 min. cooling at $20^{\circ}C$) was evaluated better than that of chloride, ion water, $O_3$ water, and salt water for the controling of micro-organisms at the early stage of sprout culture. Due to the improved germination rate and effective control of micro-organisms at early stage, the method resulted in much lower in the number of micro-organisms, higher in sprout yield, and 2 days longer in quality keeping at market than sprouts prepared by conventional method. There are two methods related with water temperature; constant temperature method (18.5$\pm$ $0.5^{\circ}C$) which keeps the same water temperature during the culture and 3-stage temperature method which changes the water temperature depending on the days after culture. Three-stage temperature method set the temperature at 21$\pm$ $1^{\circ}C$) in the second and third days after the initial acceleration of germination (about 4 hours), at 18.5$\pm$0.5$^{\circ}C$ in the fourth and fifth days, and at 17.0$\pm$ $0.5^{\circ}C$) in the sixth and seventh days. Three-stage temperature method could enhance the resistance power to diseases at the early growth stage, control the growth to standard goods (8-9cm in length and 2.15-2.30mm in width), and keep good body color at the middle or final stage. This method also increased the sprout yield by 6% compared with the conventional method, constant temperature method.

Ettringite/Thaumasite Formation, Stability and Their Effect on Deterioration of Concrete (에트린자이트/사우마사이트의 형성 및 안정도와 콘크리트 성능저하에 미치는 영향)

  • 이효민;황진연
    • Journal of the Mineralogical Society of Korea
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    • v.16 no.1
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    • pp.75-90
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    • 2003
  • Ettringite and thaumasite were observed in some concrete. The morphology and occurrence of these minerals were closely examined by performing SEM/EDAX analyses. We also experimentally induced the concrete deterioration using $Na_2SO_4$ solution with application of various environmental conditions. The stability of these minerals and deterioration characteristics under applied experimental conditions were determined. Abundant ettringite formed by“through solution reaction”occurred in many open spaces, and some microscopic ettringite formed by "tophochemical replacement" of calcium aluminate also occurred in cement paste. Severe cracking of cement paste causing premature deterioration was often associated with ettringite location. Under specific condition, ettringite was transformed to thaumasite, tricthloroaluminate, or decomposed. Thaumasite occurred with association of ettrinsite in concrete containing carbonate aggregate being subject to dedolomitization or in some concrete being subject to carbonation. Thaumasite appears to be formed under the similar condition to the general ettringite forming condition, but it formed solid solution with ettringite by substituting pre-existing ettringite. Ettringite can also be transformed to trichloroaluminate in the presence of abundant chlorides, but trichloroaluminate changed back to ettringite in late sulfate attack. It is considered that the substitution reaction direction solely depend on the concentration of chloride and sulfate ion.

Evaluation of Application of High Quality Recycled Fine Aggregate Manufacturing System by the Drying Specific Gravity Separation Method (건식비중분리법에 의한 고품질 재생잔골재 제조생산 시스템의 적용성 평가)

  • Kim Moo-Han;Kim Jae-Hwan;Kim Yong-Ro;Na Chul-Sung
    • Journal of the Korea Concrete Institute
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    • v.17 no.1 s.85
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    • pp.69-76
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    • 2005
  • In this study, the high qualify recycled fine aggregate manufacturing system by the drying specific gravity separation method was evaluated. For the evaluation of the performance of the recycled aggregate, the engineering properties and durability of recycled aggregate has been tested. From the test results, the quality of recycled fing aggregates was improved by high quality recycled fine aggregate manufacturing system and satisfied with the quality standards of KS and JASS 5. Also, compressive and tensile strengths of recycled concrete show no critical difference caused by recycled fine aggregate replacement ratio. However, durability such as carbonation depth chloride ion penetration depth and drying shrinkage shows more deterioration than the concrete without recycled fine aggregate

A Study on the Resistance to Sea Water and High Flowing Properties of Concrete Using Blended Low Heat Cement (혼합형 저발열 시멘트를 사용한 콘크리트의 초유동성 및 내해수성에 관한 연구)

  • 송용순;노재호;강석화
    • Magazine of the Korea Concrete Institute
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    • v.10 no.6
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    • pp.281-289
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    • 1998
  • This study has been performed to test the flowability and filling ability of high flowing concrete as well as distribution of aggregate and pore of core specimen, heat of hydration, compressive strength and core strength of concrete. In addition, the resistance to chloride ion penetration and chemical solutionof concrete was tested in order to evaluate the resistance to sea water of concrete and its application of high flowing concrete using blended low heat cement in the field of Seohae Grand Bridge. The properties of high flowing concrete with blended low heat cement were compared with ordinary 25-240-15 concrete using Type V cement. As the results of this study, the flowability and filling ability of high flowing concrete with blended low heat cement is satisfied without vibration. Though the cement content of high flowing concrete with blended low heat cement was 400kg/m$^2$, the rising temperature of it was relatively lower than that of the ordinary 25-240-15 concrete with Type V cement. Also, the compressive of high flowing concrete with blended low heat cement is similar to that of the ordinary 25-240-15 concrete with Type V cement.

Study on Removal of Cesium in Water Treatment System (물속의 방사성핵종(세슘) 제거율 연구)

  • Jeong, Gwanjo;Son, Boyoung;Ahn, Chihwa;Lee, Suwon;Ahn, Jaechan;Kim, Bogsoon;Chung, Deukmo
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.1
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    • pp.8-13
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    • 2016
  • This study investigated the removal of a radioactive cesium ($Cs^+$) in the water at the water treatment processes. Since cesium is mostly present as the $Cs^+$ ion state in water, it is not removed by sand filtration, and coagulation with polyaluminum chloride (PACl), powdered activated carbon (PAC) and mixture of PACl and PAC. However, it is known that the removal rate of cesium increases as the turbidity increases in raw water. As the turbidity was adjusted by 74 NTU and 103 NTU using the surrounding solids near G-water intake and yellow soils, removal rate of cesium was about 56% and 51%, respectively. In case of a GAC filtration with supernatants after jar-mixing/setting was conducted, 80% of cesium is approximately eliminated. The experimental results show that it is efficient to get rid of cesium when the turbidity of the raw water is more than 80 NTU. In case of a GAC filtration, about 60% of cesium is removed and it is considered by the effect of adsorption. Cesium is not eliminated by microfiltration membrane while about 75% of cesium is removed by reverse osmosis.

Effect of Corticosteroids on Renal Excretion of Lithium (Lithium 이온의 배설에 미치는 Corticosteroid의 영향)

  • Oh, Shin-Yul;Ha, Jeoung-Hee;Lee, Kwang-Youn;Kim, Won-Joon
    • Journal of Yeungnam Medical Science
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    • v.3 no.1
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    • pp.229-235
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    • 1986
  • Lithium salts are being used increasingly to treat patient with affective disorders, especially acute mania, or bipolar manic-depressive illness. For therapeutic effect the lithium content must be maintained at or above a particular level. Lithium poisoning due to overdosage may be seen occasionally, and its course is determined primarily by the rate of renal lithium elimination. A search is therefore indicated for procedures that could raise the lithium clearance. In a number of reports renal lithium excretion has been studied in relation to the excretion of water, sodium, potassium and hydrogen, but effects of sodium or water on the lithium excretion has not yet been clarified. Hence the present study was undertaken to investigate the effects of corticosteroid on the excretion of lithium ion. The female rat(Sprague-Dowley), weighing from 200 to 300g, was injected with 50mg/kg of lithium chloride intraperitoneally, and then injected with graded dosage of fludrocortisone and dexamethasone in each group. During the injected rats were incubated in metabolic cage, 24 hour urine of rats were collected. At 24 hours after injection, the rats were sacrificed with guillotin, the blood were collected. And then the concentratios of $Na^+$, $K^+$, $Li^+$ of collected urine and serum were checked by Flame photometer. The results are summarized as follows; 1. Fludrocortisone decreased the serum concentration of lithium and increased the urinary excretion of lithium. 2. In the group treated with low dose of dexamethasone(0.1mg/kg), the serum concentration of lithium was decreased and high dose of dexamethasone (1mg/kg) increased the urinary excretion of lithium. 3. Fludrocortisone increased the urinary $[Na^+]/[K^+]$ in serum and decreased $[Na^+]/[K^+]$ in urine, but opposite effects were occurred in dexamethasone. By above results, it may be concluded that corticosteroid increased the urinary excretion of lithium and decreased the serum concentration of lithium, but it seems to be there is no relationship between these effects of corticosteroid and of the renal $Na^+$ or $K^+$ transport.

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A Study on Release Characteristics of Lake Sediments under Oxic and Anoxic Conditions (호수 퇴적물의 호기 및 혐기조건에서의 용출 특성에 대한 연구)

  • Yoon, Mi-Hae;Hyun, Jun-Taek;Huh, Nam-Soo;Kwon, Sung-Hyun;Cho, Dae-Chul
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.9
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    • pp.1003-1012
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    • 2007
  • In this study, we analyzed the release differences for some critical pollution compounds according to the surrounding conditions in order to predict water quality due to the sedimental releases and the release characteristics at different sedimental locations in Lake Leewon, in Tae-An area. COD, nitrogens and phosphates were analyzed using the standard methods for water quality, based on high chloride ion concentration(greater than 2,000 ppm). For COD, the release rate increased in the anoxic basin but almost the same in the oxic basin. For $NH_3$-N, the release rate decreased in the oxic basin as you go A through C point meanwhile, for $NO_3$-N and T-N, the tendency was reversed because of nitrification of them. In the anoxic basin, the release rates of $NH_3$-N and $NO_3$-N went up with A through C path. However, the release rate of T-N was found to decrease. Also, for $PO_4$-P and T-P, the release rates in the oxic basin were lowest at B point mainly because the phosphates were at less released in the highly $O_2$ concentrated environment. In the anoxic reactor, $PO_4$-P was released similarly regardless of the sampling points. In summary, the release rates in the oxic reactor were greater than those in the anoxic reactor for COD and $NO_3$-N. For the other components, the anoxic basin generated the higher release rates.

Influences of Divalent Cations and Membrane Phosphorylation Inhibitors on $Na^+-Ca^{++}$ Exchange in Synaptosomes (이가 양이온과 세포막 인산화 반응의 억제제가 Synaptosome에서의 소듐-칼슘 교환이동에 미치는 영향)

  • Shin, Yong-Kyoo;Lee, Chung-Soo;Lee, Kwang-Soo
    • The Korean Journal of Pharmacology
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    • v.24 no.2
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    • pp.179-187
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    • 1988
  • Verapamil, tetrodotoxin and tetraethylammonium chloride in the stated amount did not affect the $Na^{++}$ induced $Ca^{++}$ release. $Cd^{++}$ and $Zn^{++}$ significantly inhibited the $Na^{++}$ induced $Ca^{++}$ release. $Mn^{++}$ also inhibited $Na^+-Ca^{++}$ exchange. $Cd^{++}$ inhibited $Na^+-Ca^{++}$ exchange noncompetitively with an apparent inhibition constant (Ki) of $100\;{\mu}M$. $Cd^{++}$ caused loss of sulfhydryl group, whereas $Zn^{++}$ did not show any significant effect. $Cd^{++}$ and $Zn^{++}$ effectively inhibited $Na^+-Ca^{++}$ ATPase and slightly inhibited $Ca^{++}-Mg^{++}$ ATPase. Carbonyl cyanide chlorophenylhydrazone, 2,4-dinitrophenol and sodium arsenate stimulated the $Na^{++}$ induced $Ca^{++}$ release. Dibucaine and oligomycin slightly inhibited it. The results suggest that the $Na^+-Ca^{++}$ exchange on the synaptosomal plasma membrane may be not accomplished by ion channels. The $Na^+-Ca^{++}$ exchange is sensitively inhibited by $Cd^{++}$ and this transport process appears to be partially regulated by sulfhydryl groups of the synaptosomal plasma membrane. It is also postulated that $Na^+-Ca^{++}$ exchange is suppressed during the phosphorylation reaction of protein component on the neuronal membrane.

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