• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.2
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• pp.1188-1194
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• 2014

The purpose of this study is to estimate Chloride Attack Resistibility and mechanical properties of quaternary concrete adding fly ash, blast-furnace slag, and silica fume. Compressive strength, modulus of elasticity, chloride migration coefficient, charge passed from Rapid chloride penetration test(RCPT), and immersion testing in 3% NaCl are tested. Chloride migration coefficient and charge passed of quaternary concrete measured $0.032{\times}10^{-12}m^2/sec$ and 650 coulomb at 17 weeks, which are in a permitted limit. Also in immersion test, depth of chloride penetration and maximum chloride ion of quaternary concrete measured 3.7 mm and $10.211kg/m^3$ respectively. From the results, quaternary concrete adding fly ash, blast-furnace slag, and silica fume denotes improvement of mechanical properties and chloride attack resistibility.

• Journal of the Korea institute for structural maintenance and inspection
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• v.21 no.2
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• pp.146-154
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• 2017

Recently, self-healing concrete has been researched as maintenance and repair of concrete structures are important challenges we face. This paper focused on possibility of ion exchange resin as a novelty material directly and actively controlling harmful ions of concrete, whereas most self-healing concrete researches have been focused on methods to automatically filling and repairing internal crack of concrete. Because equilibrium properties between ion exchange resin and harmful ion is important before design of cement mixing proportion, it was conducted to remove chloride or sulfate in saturated $Ca(OH)_2$ solutions containing NaCl or $Na_2SO_4$. The removal performance was analyzed using kinetic equation and isothermal equation. Consequently, the removal properties of anion exchange resin were relatively more dependent on pseudo second reaction equation and Langmuir equation than pseudo first reaction equation and Freundlich equation. And it was concluded that each chloride and sulfate can be removed to the maximum 1068 ppm and 1314 ppm.

• Journal of the Korea Concrete Institute
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• v.17 no.5 s.89
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• pp.793-801
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• 2005

This study investigates fundamental properties of recycled aggregate concrete which incorporated 100% recycled coarse aggregate and various amount of recycled fine aggregate. In addition, for the purpose of the improvement of long term strength and durability, a part of cement was replaced with fly ash. Compressive strength and resistance to chloride ion penetration and carbonation were investigated. When the coarse aggregate was completely replaced with the recycled the replacement ratio of the fine aggregate with the recycled was recommended to be limited below 60% in the consideration of strength. The strength of the steam-cured specimen was very comparable to the wet-cured at 28 days. As fly ash content increased the resistance to chloride ion penetration was increased. The chloride ion penetrability based on the charge passed was found to be low at 21 days and very low at 56 days, respectively. Carbonation depth and carbonation velocity coefficient increased as the fly ash content increased and the relationship between the carbonation depth and recycled fine aggregate replacement ratio was not clear. Up to 28days, however, the measured carbonation depth was mostly less than 10mm which could be considered as low.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.4
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• pp.475-481
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• 2022

Recycled aggregates show high water absorption rate compared to natural aggregates due to microcrack developed during production process and adhered cement pastes at the surface of recycled aggregates. This leads to the deterioration of mechanical properties and slow work flow. Currently it is getting hard to satisfy high demand for natural aggregates. Utilizing recycled aggregate more widely may be a substitutable countermeasure for the shortage of natural resources. In this study, two-stage mixing approach(TSMA) suggested by Tam et al. is used to produce recycled aggregate concrete(RAC) with 100 % replacement of coarse natural aggregate and tests for compressive strength, elastic modulus, and chloride ion diffusion coefficient are conducted to find out the effect of TSMA compared to normal mixing method. According to experimental result compressive strength and elastic modulus of RAC with TSMA was superior to those of RAC with normal mixing irrespective of water-cement ratio, and in some cases mechanical properties of RAC with TSMA approached to those of natural aggregate concrete(NAC). However, chloride ion diffusion coefficient of RAC was higher than that of NAC. This illustrates that TSMA is not an appropriate method in reducing chloride ion diffusion coefficient, resulting in inconsequential contribution of TSMA to the durability of RAC.

• Journal of environmental and Sanitary engineering
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• v.4 no.1 s.6
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• pp.7-15
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• 1989

According to the increase of population and development of industrialization air and water pollution problems are still keeping going to great nuisance to human activities. Specially man should drink 2l clean water to maintain our health every day, but we afraid of drink the city tap water because of the contaminants like heavy metals, bacteria trihalomethane, etc. In the analysis of the anions in potable water, we usually adapt the Standard methods for the Examination of Water and Wastewater. But this method is tedious and time consuming, so the Ion Chromatography method is now used in research of water quality. Author worked with Ion Chromatography in measuring the anions in drinking water by attaching conductivity dector to normal High Performance Liquid Chromatograph. Low-capacity ion-exchange coulmn and dilute eluents, 0.00M phthalic aic was used in this study. The concentration of chloride ion was 1.55 ppm$\~$3 8.81ppm, nitrate ion was 5.45 ppm$\~$18.27ppm, and sulfate ion was 19.64 ppm$\~$28.86 ppm. The phosphate ion was detected only in Apt. tap water as 167.99 ppm whose amount was supposed to be used as a water pipe cleaner.

• Journal of the Korea Institute of Building Construction
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• v.17 no.6
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• pp.483-492
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• 2017

Recently, the coastal area has become the popular place for infrastructure development. To provide a beautiful scenary of costal area to nearby facilities without any hinderance, and also to protect those facilities from the sea water overflow, it is necessary to develop a new type of wave dissipating block, which is a turning wave block. It is noticeable that the top of the turning wave block is flat and thus can provide spaces for various purposes. However, the unit weight of the block decreases due to the presence of pipeline that is installed for turning the direction of the waves. In order to mitigate such problem, a heavyweight concrete needs to be used to increase the resistance against tidal waves. The copper slag and magnetite were used as a source of fine and coarse aggregate, respectively. The 28 day compressive strength of concrete incorporating ordinary and heavyweight aggregate did not show significant differences. It should be noted that the chloride ion penetration resistance was evaluated using NT-BUILD 492 rather than ASTM C 1202 method because concrete incorporating magnetite as a coarse aggregate showed excessive current flow by ASTM C 1202 method. According to the results from NT Build 492 method, which uses the penetration depth of chlorine ions to obtain chloride ion diffusivity, the heavyweight concrete incorporating the copper slag and the magnetite showed the best resistance against the chloride ion penetration. Therefore, it is reasonable to say that heavyweight concrete made with copper slag and magnetite can be used for production of turning wave block.

• The Journal of Korean Academy of Prosthodontics
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• v.37 no.6
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• pp.717-729
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• 1999

Although many studies on the cytotoxicity of the dental cast base metal alloys and their components have been carried out, the results are rather conflicting because of the different type of cells used and the various experimental procedures taken. Recently a number of scientists have claimed that it would be preferable to focus on the use of cells from relevant specific location of the human bodies. Consequently, the primary cultured oral keratinocyte derived from oral mucous along with nickel chloride and several of widely used dental cast base metal alloys(two Ni-Cr alloys and one Co-Cr alloy)in domestic were selected for this study, from which 1) The amounts of released metal ions were determined using atomic absorption spectrometry, 2) The cytotoxicity of nickel chloride and dental cast base metal alloys was evaluated via MTT assay, and finally, 3) The amounts of released metal ions and the cytotoxicity of nickel chloride were correlated with the cytotoxicity of dental cast base metal alloys And, the results were summarized as follows; 1. Nickel ion from Ni-Cr alloys and Cobalt ion from Co-Cr alloys resulted in maximum releasing rate during first 2h hours, followed by a decrease in releasing rate with time. Chromium ion were found to be minimal in all alloys. 2. In cytotoxic test. with $40{\mu}M,\;80{\mu}M$ of nickel chloride, there were observed an increase in the relative cell number compared to control samples after 24 hours. With $160{\mu}M$, there was found to be no difference in the relative cell number with control, except that 48 hour showed a increase in relative cell number. With $320{\mu}M$, the relative cell number remained constant and decreased after 48 hours, and with $640{\mu}M$, a continuing decrease in relative cell number was observed throughout test period. 3 The sensitivity of primary cultured oral epithelium to nickel was lower compared to the cells used in other studies. 4. CB-80 Soft and Regalloy showed no cytotoxicity to primary cultured oral epithelium and New crown resulted in a slight cytotoxicity. In conclusion, it was shown that the primary cultured oral keratinocytes could be applied successfully as testing cells in cytotoxicity test. Futhermore, the dental cast base metal alloys used in this study were found to be biocompatible.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.6
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• pp.1127-1137
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• 2000

Applications of lanthanum ion and crude rare earth chloride to the phosphate wastewater and fluorine wastewater, respectively, as treatment agents were studied. For the investigation of phosphate removal characteristics according to the amount of lanthanum ion, initial phosphate content was decreased by about 50% when molar ratio of [$La^{3+}$]:[$PO_4{^{3-}}-P$] was 0.25 and nearly all of phosphate was removed when the molar ratio of [$La^{3+}$]:[$PO_4{^{3-}}-P$] to be doubled. The removal of phosphate by $La^{3+}$ appeared to reach equilibrium state rapidly, and it was exothermic reaction since the removed amount of phosphate was diminished somewhat when the reaction temperature was increased. The zeta potential of combined particulate compound of lanthanum ion and phosphate was located for its isoelectric point at pH 5.5 and the turbidity of treated wastewater was found to vary according to the pH in a similar manner as the absolute value of zeta potential of the combined particulate compound did. For the treatment of fluorine wastewater by crude rare earth chloride, the remaining fluorine content after treatment decreased as the dosage of crude rare earth chloride increased. Whereas, the turbidity of treated wastewater and the amount of sludge generated were shown to increase as more crude rare earth chloride was added. The remaining fluorine content and the turbidity of treated wastewater were decreased and the amount of sludge generated was observed to increase according the increase of coagulant dosage under the condition of constant input of crude rare earth chloride.

• YAKHAK HOEJI
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• v.19 no.1
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• pp.36-46
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• 1975

In the rats administered mercuric chloride (1mg/kg/48 hrs i.p.), it was found that LDH$_{1}$ and LDH$_{2}$ were increased in heart, brain and kidney as well as LDH$_{5}$ increased in liver and muscle in the duration of sixteen days. After the sixteen days of administration, the LDH isozyme patterns in the above mentioned organs were found to be irregularly changed. Considerable amount of mercury accumulation in liver and kidney were found, and especially the mercury accumulation in kidney was notable.

• Journal of Photoscience
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• v.9 no.2
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• pp.308-310
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• 2002

Bacteriorhodopsin (bR) and halorhodopsin (hR), which exist in the membrane of Halobacterium salinarum, are light-driven ion pumps. In spite of high similarity of primary and tertiary structures between bR and hR, these membrane proteins transport different ions, proton and chloride, in the opposite direction. From alignment of the amino acid sequences, Thr-89 of bR is homologous to Ser-l15 of hR from Halobacterium salinarum (shR). X-ray structure of shR has revealed that OH group of this residue directly interacts with CI$\^$-/ Thus, Ser-lI5 of shR is expected to play an important role in CI$\^$-/ binding and transport. In this study, we expressed wild type hR from Natronobacterium pharaonis (PhR) and Sl30A, which corresponds to Ser-l15 of shR, in E. coli in order to clarify binding affinity of chloride ion and photocycle reactions. From the titration with CI$\^$-/, affinity of Sl30A became quite lower than that of WT (WT 6 mM, Sl30A 89 mM). Furthermore, from the flash photolysis with pulse laser of λ$\_$max/ at 532 nm, the reaction rate of SI30A from 0 intermediate to hR ground state was found to become apparently slower than that of WT. The singular value decomposition (SVD) and global fitting analyses of the photocycles were performed to identify all photointermediates and determine the reaction rates.