• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1999년도 학회창립 10주년 기념 1999년도 가을 학술발표회 논문집
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• pp.747-750
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• 1999

Chloride ions are considered to be the major cause of steel corrosion in concrete structures exposed to seashore environments. Thus, estimating chloride ion concentrations by ages is needed to predict service life of seashore structures. Experimentally measured chloride profiles were used in this study for estimating chloride diffusion coefficients, and a relationship between mixing properties and chloride diffusion coefficients is proposed for predicting chloride penetrations.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 봄 학술발표회 논문집
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• pp.985-990
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• 2001

Chloride permeability of high strength concrete(HSC) was investigated using saltwater pending test and rapid chloride permeability test by electrical potential(ASTM C 1202). The lower water-cement ratio concrete showed the lower diffusion coefficient of chloride. The relationship between the diffusion coefficient of chloride and charge passed by the rapid chloride permeability test could be obtained. This relationship appears to be an effective method for evaluating chloride permeability of low water-cement HSC.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 봄 학술발표회 논문집
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• pp.731-736
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• 2002

The degradation of reinforced concrete (RC) structures due to physical and chemical attacks has been a major issue in construction engineering. Deterioration of RC structures due to chloride attack followed by reinforcement corrosion is one of the serious problems. The objective of this study is to develop a form of mathematical model of chloride ingress into concrete. In order to overcome some limits of the previous approaches, a mathematical model of chloride ingress into concrete consisting of chloride solution intrusion through the capillary pore and chloride ion diffusion through the pore water was proposed. Moreover, the variability of diffusivity of chloride ion due to degree of hydration of concrete, relative humidity in pore, exposure condition, and variation of chloride binding was considered in the chloride ingress model.

• Computers and Concrete
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• 제6권5호
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• pp.391-401
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• 2009

This paper presents a study of the strength and chloride penetration of blended Portland cement mortar containing ground palm oil fuel ash (POA) and ground river sand (GS). Ordinary Portland cement (OPC) was partially replaced with POA and GS. Compressive strength, rapid chloride penetration test (RCPT) and chloride penetration depth of mortars were determined. The GS only asserted the packing effect and its incorporation reduced the strength and the resistance to chloride penetration of mortar. The POA asserted both packing and pozzolanic effects. The use of the blend of equal portion of POA and GS also produced high strength mortars, save cost and excellent resistance to chloride penetration owing to the synergic effect of the blend of POA and GS. For chloride depth, the mathematical model correlates well with the experimental results. The computer graphics of chloride depth of the ternary blended mortars are also constructed and can be used to aid the understanding and the proportioning of the blended system.

• Ocean and Polar Research
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• 제26권1호
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• pp.43-50
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• 2004

The diffusion model, which considers diffusion and sorption, is proposed. The FEM program developed on the basis of the diffusion model provides the estimation of chloride concentration according to cyclic humidity and sorption. After the humidity diffusion analysis is carried out, the chloride ion diffusion and sorption analysis are conducted on the basis of the preestimated humidity data in each element. Each element has different analysis variables at different ages and locations. At early ages, the difference between inner and outer relative humidity causes the chloride ion penetration by sorption. As the humidity diffusion reduces the difference with age, the effect of sorption on the chloride ion penetration decreases. By the way, the cyclic humidity increases the effect of sorption on the chloride ion penetration at early ages, and the quantity of chloride ion around steel at later ages. Therefore, the in situ analysis of chloride ion penetration for marine concrete structures must be performed considering the cyclic humidity condition and the long term sorption.

• 한국작물학회지
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• 제44권2호
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• pp.163-165
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• 1999

The study was conducted to find the critical concentrations of zinc toxicity and to determine the changes of the contents of free proline and organic acids with treatment of different zinc chloride concentrations during rice germination and seedlings grown for seven days. The concentration of zinc chloride, 140 ppm, inhibited root elongation as much as 46 times compared with the control, and the germination rate was also decreased in all treatments of zinc chloride, showing that the germination rate decreased more with increasing concentrations of zinc chloride. Its rate was only 13% with treatment of 140 ppm zinc chloride. The content of free proline with treatment of zinc chloride, 140 ppm, was highest about 4,873 $\mu$M at 3 days compared with the control. Malic acid concentration with treatment of zinc chloride, 140 ppm, increased to approximately 4 times compared to the control. Citric and succinic acid content were also slightly increased in all treatments of zinc chloride.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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• pp.225-228
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• 2004

In order to estimate the chloride ion penetration, the model, which considers diffusion and sorption, is proposed on the basis of Finite Element Method (FEM). The FEM program provides the estimation of chloride concentration according to cyclic humidity and sorption. After the humidity diffusion analysis is carried out, the chloride ion diffusion and sorption analysis are conducted on the basis of the preestimated humidity data in each element. Each element has different analysis variables at different ages and locations. At early ages and constant outer humidity, the difference between inner and outer relative humidity causes the chloride ion penetration by sorption. As the humidity diffusion reduces the difference with age, the effect of sorption on the chloride ion penetration decreases. By the way, the cyclic humidity increases the effect of sorption on the chloride ion penetration at early ages, and the quantity of chloride ion around steel at later ages. Therefore, the in-situ analysis of chloride ion penetration for marine concrete structures must be performed considering the cyclic humidity condition and the long term sorption.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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• pp.509-512
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• 2004

This research is targeting that estimate the effect on cement concrete pavement with type of chloride deicers. In order to this study objective, when chloride deicers were spread on road surface, thermal characteristics test was conducted. Also, skid resistance test according to types and concentration of chloride deicier, road surface conditions were investigated. As a test results, thermal characteristics with kind of chloride deicier could know that sodium chloride(NaCl) is exothermic reactive material, calcium chloride$(CaCl_2)$ is endothermic reactive material. And, in case of mixed salt of the calcium and sodium chloride, it could know that can change to the exothermic or endothermic reaction according to dosage ratios. Skid value by British Pendulum Tester(BPT) has shown that it is seldom difference between the types($CaCl_2$, NaCl, mixed salt) and solution concentrations(0.5, 0.8, 1.0, 4.0, $10\%$) of chloride deicier comparing with tap water except mixed salt($10\%$ solution concentration).

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2023년도 가을학술발표대회논문집
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• pp.123-124
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• 2023

This study successfully developed a chromium-free paper-based analytical device (µPAD) for chloride detection in fresh concrete. The sensing materials were chemically synthesized and coated to the paper through drop casting. The fabricated µPAD was thoroughly tested with various concentrations of chloride ions. Upon interaction with the µPAD, the chloride ions in the solution react with a chromium-free silver compound, exhibiting a specific coloring height proportional to the absolute chloride concentration. The height of the color change during a reaction can vary based on the chloride concentration, which allows for predicting the chloride concentration in a solution. The results reveal that µPAD has extraordinary precision in identifying chloride in fresh concrete, which highlights its immense potential for future applications.

• Computers and Concrete
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• 제3권6호
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• pp.401-422
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• 2006

A multi-species model based on the Nernst-Planck equation has been developed by using a finite volume method. The model makes it possible to simulate transport due to an electrical field or by diffusion and to predict chloride penetration through water saturated concrete. The model is used in this paper to assess and analyse chloride diffusion coefficients and chloride binding isotherms. The experimental assessment of the effective chloride diffusion coefficient consists in measuring the chloride penetration depth by using a colorimetric method. The effective diffusion coefficient determined numerically allows to correctly reproduce the chloride penetration depth measured experimentally. Then, a new approach for the determination of chloride binding, based on non-steady state diffusion tests, is proposed. The binding isotherm is identified by a numerical inverse method from a single experimental total chloride concentration profile obtained at a given exposure time and from Freundlich's formula. In order to determine the initial pore solution composition (required as initial conditions for the model), the method of Taylor that describes the release of alkalis from cement and alkali sorption by the hydration products is used here. Finally, with these input data, prediction of total and water-soluble chloride concentration profiles has been performed. The method is validated by comparing the results of numerical simulations to experimental results obtained on various types of concretes and under different exposure conditions.