• Journal of Applied Biological Chemistry
• /
• 제49권2호
• /
• pp.62-64
• /
• 2006

• Journal of Applied Biological Chemistry
• /
• 제48권2호
• /
• pp.97-100
• /
• 2005

Chiral dienophile 5 was synthesized from D-glucose by consecutive diisopropylidenation, partial deprotection, diol cleavage, and Wittig reactions. Under thermal conditions, asymmetric Diels-Alder reaction between chiral dienophile and cyclopentadiene gave four possible chiral norbornenes stereoisomers whose absolute configurations were determined through CADD and NMR.