• 제목/요약/키워드: Chemical waste disposal

검색결과 178건 처리시간 0.026초

초등학교 과학실에서 발생하는 화학폐기물에 대한 실태 (A Status on the Chemical Waste in Elementary School Science Laboratory)

  • 김성규;허승현
    • 한국환경과학회지
    • /
    • 제13권3호
    • /
    • pp.301-311
    • /
    • 2004
  • The purpose of this study was to examine teachers’ awareness of chemical waste produced in elementary school laboratory experimentation and how this awareness relates to collection and disposal of chemical waste. More specifically, the study looked at the correlation between the handling of chemical waste and factors such as years of teachers’ educational career, class size and amount of waste produced. The target population were 250 elementary school teachers in Gyeongnam area and 237 subjects were responded. Among the 237 responses, 37 cases that did not complete the questionnaire were eliminated. Therefore, 200 responses were analyzed in this study. The survey questionnaire consisted of 15 questions. The categories of the questionnaire were their skills of management and treatment of the chemical waste. The data collected were analyzed by SPSS 10.0, and the relations among variables such as class sizes and years of teaching experience were also analyzed by $x^2-test.$ The results in this study were as follows: First, there were no significant differences between the years of teaching and class sizes in the training experience of chemical waste disposal. Second, there was a significant difference between the science laboratory size and class sizes in the laboratory actual condition. In addition, in the relations between the number of times of experimentation and the years of teaching experience, there was a significant difference. Third, in terms of the discharge amount of chemical waste, there was a significant difference between the years of teaching and class sizes. Fourth, in the simple chemistry waste disposal process in the science laboratory, there also was a significant difference between the kinds of experimental equipments that used in the experimentation and the years of teaching. Based on this study, it was found that great amount of the chemical wastes produced in the science laboratory dumped into the drain and the treatment process of chemical waste was also inattentive. Even the importance of environmental education is emphasized in the elementary education, the basic problems occurred in the science laboratory is disregarded. Therefore, not only students but teachers have to pay attention to the disposal process of chemical waste in the laboratory in order to prevent environment pollution. Furthermore, the efforts of preventing environment pollution are needed such as opening the teacher training course about environment education, minimal use of chemicals, treatment of chemical waste, and so forth.

TNT 처리에 관한 연구동향 (Review on TNT Disposal)

  • 박재현;신원모;이재우
    • 한국군사과학기술학회지
    • /
    • 제19권1호
    • /
    • pp.127-143
    • /
    • 2016
  • Over the decades, TNT has been produced indiscriminately to be utilized in many fields owing to its ability to manipulate the explosion. Yet, the proper technique for disposal of TNT and the waste residues had not been developed so that the large amount of TNT waste was being piled up. Upon the agreement to demilitarization of old weapon, a study on the disposal methods for TNT and the waste treatment have been raised for their dangerous nature. Since then, from burying in landfill to utilizing supercritical fluid-based oxidation, a lot of research is actively ongoing, but little progress has been made in Korea compared to developed countries. This review paper covers all the technologies developed for TNT and its waste disposal including the concept, advantage, and disadvantage of those technologies. Also, suggested here are the future research directions.

Measuring thermal conductivity and water suction for variably saturated bentonite

  • Yoon, Seok;Kim, Geon-Young
    • Nuclear Engineering and Technology
    • /
    • 제53권3호
    • /
    • pp.1041-1048
    • /
    • 2021
  • An engineered barrier system (EBS) for the disposal of high-level radioactive waste (HLW) is composed of a disposal canister with spent fuel, a buffer material, a gap-filling material, and a backfill material. As the buffer is located in the empty space between the disposal canisters and the surrounding rock mass, it prevents the inflow of groundwater and retards the spill of radionuclides from the disposal canister. Due to the fact that the buffer gradually becomes saturated over a long time period, it is especially important to investigate its thermal-hydro-mechanical-chemical (THMC) properties considering variations of saturated condition. Therefore, this paper suggests a new method of measuring thermal conductivity and water suction for single compacted bentonite at various levels of saturation. This paper also highlights a convenient method of saturating compacted bentonite. The proposed method was verified with a previous method by comparing thermal conductivity and water suction with respect to water content. The relative error between the thermal conductivity and water suction values obtained through the proposed method and the previous method was determined as within 5% for compacted bentonite with a given water content.

Systematic investigation of heavy metals from MSWI fly ash and bottom ash samples

  • Ramakrishna., CH;Thriveni., T;Ahn, Ji Whan
    • 에너지공학
    • /
    • 제26권4호
    • /
    • pp.35-44
    • /
    • 2017
  • Disposal of municipal solid waste has become a major problem in many countries around the world. As landfill space for the disposal of ash from Municipal Solid Waste Incineration (MSWI) becomes scarce, numerous reports and researches address the various environmental issues about the municipal solid waste incineration waste management and other particulate matters with the range of 10 ~ 2.5. Although in many developing and industrialization countries landfill with the disposal of municipal solid waste, open incineration has become a common practice. Large municipal waste incinerators are major industrial facilities and have the potential to be significant sources of environmental pollution. Despite the significant volume reduction from incineration, waste recycling is important to ensuring the future welfare of mankind. The main goal of the present work is the physical and chemical characterization of the local incineration bottom ash towards its eventual re-utilization. In this paper, we reported the studies on physical and chemical characteristics of municipal solid waste incineration (MSWI) fly ash and bottom ash containing particulate matter whose particulate sizes are lower than $PM_{10}$, $PM_{2.5}$ and heavy metal were investigated.

Chinese buffer material for high-level radiawaste disposal --Basic features of GMZ-l

  • WEN Zhijian
    • 한국방사성폐기물학회:학술대회논문집
    • /
    • 한국방사성폐기물학회 2005년도 Proceedings of The 6th korea-china joint workshop on nuclear waste management
    • /
    • pp.236-244
    • /
    • 2005
  • Radioactive wastes arising from a wide range of human activities are in many different physical and chemical forms, contaminated with varying radioactivity. Their common feature is the potential hazard associated with their radioactivity and the need to manage them in such a way as to protect the human environment. The geological disposal is regarded as the most reasonable and effective way to safely disposal high-level radioactive wastes in the world. The conceptual model of geological disposal in China is based on a multi-barrier system that combines an isolating geological environment with an engineered barrier system. The buffer is one of the main engineered barriers for HLW repository. The buffer material is expected to maintain its low water permeability, self-sealing property, radio nuclides adsorption and retardation property, thermal conductivity, chemical buffering property, overpack supporting property, stress buffering property over a long period of time. Benotite is selected as the main content of buffer material that can satisfy above. GMZ deposit is selected as the candidate supplier for Chinese buffer material of High Level Radioactive waste repository. This paper presents geological features of GMZ deposit and basic property of GMZ Na bentonite. GMZ bentonite deposit is a super large scale deposits with high content of Montmorillonite (about $75\%$) and GMZ-l, which is Na-bentonite produced from GMZ deposit is selected as reference material for Chinese buffer material study.

  • PDF

Application of a Novel Carbon Regeneration Process for Disposal of APEG Treatment Waste

  • 류건상;Shubender Kapila
    • Bulletin of the Korean Chemical Society
    • /
    • 제18권8호
    • /
    • pp.814-818
    • /
    • 1997
  • The chemical waste treatment, APEG (alkali/polyethylene glycol) process has been shown to be effective for the dechlorination of PCBs in transformer oil. Considerable amount of PCBs, however, still remains in the waste exceeding the 25-50 ppm limit set by regulatory agency. A new thermal regeneration technology has been developed in our laboratory for disposal of hazardous organic wastes. Due to the limited oxidation of carbon surface through the reverse movement of flame front to oxidant flow, this technology was termed counterflow oxidative system (COS). Specially, the oxidant flow in the COS process is a principal parameter which determines the optimum conditions regarding acceptable removal and destruction efficiency of adsorbed organic wastes at minimal carbon loss. The COS process, under optimum conditions, was found to be very effective and the removal and destruction efficiency of 99.99% or better was obtained for residual PCBs in the waste while bulk (≥90%) of carbon was recovered. Any toxic formation of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzo furans (PCDFs) were not detected in the regenerated carbon and impinger traps. The results of surface area measurement showed that the adsorptive property of regenerated carbon is mostly reclaimed during the COS process.

방사성폐기물인증프로그램 개발 방안 (Plan to Develop the Radioactive Waste Certification Program)

  • 정희준;이재민;황주호;김헌;정의영
    • 한국방사성폐기물학회:학술대회논문집
    • /
    • 한국방사성폐기물학회 2005년도 춘계 학술대회
    • /
    • pp.205-210
    • /
    • 2005
  • 개정예정인 중${\cdot}$저준위 방사성폐기물 처분시설 인도규정에서는 방사성폐기물 처분을 위해 폐기물 발생자가 방사성폐기물의 처분요건 적합성을 입증하도록 권고하고 있다. 이에 따르면 중${\cdot}$저준위 방사성폐기물의 처분을 위해서는 폐기물의 핵종농도, 물리화학적 특성 및 그 건전성 등이 확보 되어야하며 폐기물 발생자는 이러한 정보를 처분사업자에게 전달하도록 규정되어 있다. 또한 처분 사업자는 처분시설의 안전성 평가를 통해 부지특성을 고려한 방사성폐기물 인수기준(Site Specific Waste Acceptance Criteria, SWAC)을 규정하며, 발생자는 이 기준에 따라 중${\cdot}$저준위 방사성폐기물을 관리, 처리, 인도하도록 규정되어 있다. 상기 규정과 기준을 준수하기위해 폐기물 발생자는 처분대상이 되는 폐기물을 처분시설로 운반하기 이전에 처분적합성을 사전에 입증하여야 하며 이를 위하여 관련 제도 및 절차인 방사성폐기물인증프로그램을 개발하여야 한다. 본 연구에서는 원자력 선진국들에서 시행하고 있는 방사성폐기물인증프로그램에 대한 심층 분석을 통해 국내 원전에 적용 가능한 인증프로그램 초안을 개발하였고, 그 적용성을 검증하기 위하여 현재 울진 1, 2 발전소에서 시범 적용하고 있다. 앞으로 시범적용 결과분석을 통해 국내 여건에 부합하는 방사성폐기물인증프로그램을 개발하고자 한다.

  • PDF

음식물류 폐기물 퇴비 시용이 토마토 생육 및 토양특성에 미치는 영향 (The Effect of Food Waste Compost on Tomato (Lycoperscion Esculentum.L) Growth and Soil Chemical Properties)

  • 이영돈;칼리드후세인;유재홍;주진호
    • 한국환경농학회지
    • /
    • 제38권4호
    • /
    • pp.332-337
    • /
    • 2019
  • BACKGROUND: From year 2005, landfill for food waste has been prohibited. Also, according to London agreement in year 2013, ocean discharge for livestock manure, sewage sludge, and food waste has been regulated. Alternative way for food waste disposal is incineration. However, due to high moisture content, additional input for energy is needed. Therefore, effective way for food waste disposal such as application of food waste compost is needed. METHODS AND RESULTS: Seven different treatments (livestock compost, food waste compost, food waste + livestock compost, livestock compost + chemical fertilizer, food waste compost + chemical fertilizer, food waste + livestock compost + chemical fertilizer and control) were applied to tomato crop. All treatments were replicated with completely randomized design. Tomato growth treated with LC+NPK showed the highest values at 6 weeks for all parameters such as leaf length (11.80 cm), leaf width (6.88 cm), and chlorophyll (61.12 O.D.), compared to other treatments. Subsequently the FWC+LC+NPK treatment was followed (11.51 cm, 6.40 cm, 59.50 O.D. for leaf length, leaf width, and chlorophyll, respectably). EC, OM contents, and CEC in the soil treated with the composts significantly increased. CONCLUSION: To evaluate the effect of food waste compost application on tomato growth and soil chemical properties, we carried out field experiment treated with 7 treatments with 3 replicates. The LC+NPK treatment showed highest values for all parameters. Some parameters such as shoot length and total length for tomato were not significantly different between the LC+NPK and the FWC+LC+NPK treatments.

중.저준위 방사성폐기물 인증 프로그램 계획 (Low and Intermediate Level Radioactive Waste Certification Program Plan)

  • 안섬진;김태국;이영희;강일식;손종식;홍권표
    • 방사성폐기물학회지
    • /
    • 제4권2호
    • /
    • pp.187-195
    • /
    • 2006
  • 최근에 개정된 중 저준위 방사성폐기물 인도규정에서는 폐기물시설운영자는 처분 전 방사성폐기물이 인도규정에 적합함을 보장하기 위한 계획을 수립하여 운영할 것을 요구하고 있다. 앞으로 건설될 방사성폐기물 처분시설에서 방사성폐기물 인수 시에 충족되어야할 방사성폐기물인수기준이 수립될 것이며, 이 인수기준에는 물리화학적 및 방사선학적 특성규명, 물리화학적인 제한사항, 금지품목, 포장, 인식표, 라벨, 문서요건 등을 규정할 것으로 예상된다. 이들 규정을 준수하기 위하여 방사성폐기물 발생자는 방사성폐기물이 폐기물 인수기준에 만족하는지를 확인하는 폐기물 인증프로그램을 수행하여 방사성폐기물이 그 기준에 만족하는지 확인하여야 하며, 방사성폐기물에 대한 모든 인증서류를 폐기물 처분시설에 제출할 책임이 있다. 본 방사성폐기물 인증프로그램계획은 한국원자력연구소에서 발생되는 방사성폐기물의 인증프로그램에 대한 예비프로그램으로서 개발된 것이며 앞으로 처분장의 인수요건이 구체적으로 확립될 때까지 수정 보완되어야 한다.

  • PDF

고형화 폐기물의 안정적 처분과 재활용을 위한 환경위해성 평가 체계의 연구 (Risk Assessment Framework for Safe Disposal and Reuse of Solidified/Stabilized Wastes)

  • 박주양
    • 한국지반환경공학회 논문집
    • /
    • 제2권1호
    • /
    • pp.15-22
    • /
    • 2001
  • 고형화 폐기물의 처분에 대한 환경 위해성 평가의 핵심은 화학적 용출특성을 파악 후, 현장의 환경조건하에서 유해물질이 얼마나 주변환경으로 유출되는가를 예측하여 그 위해도를 산정하고, 그 위해도가 환경적으로 허용가능한 지를 판단하는 데 있다. 본 논문에서는 고형화폐기물을 매립지에 처분하거나 재활용시 다양한 현장조건하에서의 환경위해성을 평가하는 체계를 용출의 두 가지 극한적 경우에 입각하여 수립하였다. 수립된 위해성평가체계의 각 경우에 따른 폐기물 특성변수를 결정할 수 있는 두 종류의 특성평가기법을 개발하고, 시멘트 고화 처리된 도시쓰레기 소각재의 매립처분 현장에 적용하여 검증하였다.

  • PDF