• Title/Summary/Keyword: Chemical waste disposal

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Hydrogeochemistry and Statistical Analysis for Low and Intermediate Level Radioactive Waste Disposal Site in Gyeongju (경주 중·저준위 방폐장의 수리지화학 및 통계 분석)

  • Soon-Il Ok;Sieun Kim;Seongyeon Jung;Chung-Mo Lee
    • Journal of the Korean earth science society
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    • v.44 no.6
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    • pp.629-642
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    • 2023
  • Currently, low and intermediate level radioactive waste is being disposed of at the Gyeongju disposal site for permanent isolation. Since 2006, the Korea Radioactive Waste Agency has been conducting site characteristics surveys continuously verifying changes in the site based on the site monitoring and investigation plan. The hydrogeochemical environment of the disposal site is considered for the evaluation of natural barriers. However, the seawater must be considered because of the regional characteristics of Gyeongju, which is near the East Sea. Therefore, this study, collected 30 samples for deriving the groundwater quality data from seven wells and compared with two seawater samples collected from October 2017 to June 2022. Additionally, the study explores the groundwater monitoring method using statistical tools such as clustering and background concentration analysis. The groundwater samples in the study area were classified into two to four clusters depending on their chemical constituents-especially, EC, HCO3, Na, and Cl-using statistical analysis, molar ratio, and K-means clustering.

Earth and Environmental Sciences with Synchrotron Radiation (방사광의 원리와 지구환경과학에의 응용)

  • 김영호
    • The Journal of the Petrological Society of Korea
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    • v.10 no.3
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    • pp.212-221
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    • 2001
  • This paper introduces the characteristics and generation of the synchrotron radiation (SR). SR has the very high spectral brilliance, broad spectral range, X-ray wavelength tunability, high degree of polarization and collimation, and pulsed time structure. Also describes the technologies to apply in the fields of geology and environmental sciences. These include X-ray tomography, XRF, EXAFS, XANES, DAC, IVP experiments. Further, nuclear power generation and nuclear waste disposal methods are mentioned relating to energy. Using these, analyses of the chemistry, crystal structure and chemical combining states of minerals and rocks can be carried out. Applications in the fields of the economic geology, paleontology and environmental sciences are open too. Informations of the Earth interior materials' behavior under high pressure-temperature can be acquired.

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Comparison of Numerical Analysis Methods of APro for the Total System Performance Assessment of a Geological Disposal System

  • Hyun Ho Cho;Hong Jang;Dong Hyuk Lee;Jung-Woo Kim
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.21 no.1
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    • pp.165-173
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    • 2023
  • Various linear system solvers with multi-physics analysis schemes are compared focusing on the near-field region considering thermal-hydraulic-chemical (THC) coupled multi-physics phenomena. APro, developed at KAERI for total system performance assessment (TSPA), performs a finite element analysis with COMSOL, for which the various combinations of linear system solvers and multi-physics analysis schemes should to be compared. The KBS-3 type disposal system proposed by Sweden is set as the target system and the near-field region, which accounts for most of the computational burden is considered. For comparison of numerical analysis methods, the computing time and memory requirement are the main concerns and thus the simulation time is set up to one year. With a single deposition hole problem, PARDISO and GMRES-SSOR are selected as representative direct and iterative solvers respectively. The performance of representative linear system solvers is then examined through a problem with an increasing number of deposition holes and the GMRES-SSOR solver with a segregated scheme shows the best performance with respect to the computing time and memory requirement. The results of the comparative analysis are expected to provide a good guideline to choose better numerical analysis methods for TSPA.

Sustainability in PET Packaging

  • Shin, Yang-Jai;Kang, Dong-Ho
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.15 no.3
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    • pp.105-111
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    • 2009
  • In this work, source reduction of poly ethylene terephthalate (PET) packaging are discussed as aspect of sustainability, such as reuse, refill and recycling through the various treatment methods and historical studies for municipal solid waste (MSW) disposal. Since PET has good chemical, physical and mechanical properties, and provides good oxygen and carbon dioxide barrier properties, PET is one of the most widely used thermoplastic polyester in the U.S. and around the world. As the demand for non-renewable PET is increasing, several approaches have been developed to meet economical feasibility and environmental responsibility without degrading material performance. Several companies, such as Coca-Cola Co., Easterform Packaging Co. and Kraft, have tried to develop lightweight PET bottle, and some of lightweight PET bottles are already commercialized. Reuse and refilling for PET container is well developed in Europe, such as Denmark, German and Netherland by supportive legislation and policies. Recycling process is the best way to economically reduce PET waste. In consequence, advanced technique and further development must be provided due to increasing PET packaging waste.

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The State of the Technology: Application of Cementitious Materials to Deep Repository Tunnels for Radioactive Waste Disposal (방사성폐기물의 심지층 처분터널에서의 시멘트 물질 적용에 관한 기술현황)

  • Kim, Jin-Seop;Kwon, Sang-Ki;Cho, Won-Jin;Cho, Gye-Chun
    • Tunnel and Underground Space
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    • v.19 no.5
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    • pp.373-387
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    • 2009
  • Considering the current construction technology and research status of deep repository tunnels for radioactive waste disposal, it is inevitable to use cementitious materials in spite of serious concern about their long-term environmental stability. Thus, it is an emerging task to develop low pH cementitious materials. This study reviews the state of the technology on low pH cements developed in Sweden, Switzerland, France, and Japan as well as in Finland which is constructing a real deep repository site for high-level radioactive waste disposal. Considering the physical and chemical stability of bentonite which acts as a buffer material, a low pH cement limits to $pH{\leq}11$ and pozzolan-type admixtures are used to lower the pH of cement. To attain this pH requirement, silica fume, which is one of the most promising admixtures, should occupy at least 40 wt% of total dry materials in cement and the Ca/Si ratio should be maintained below 0.8 in cement. Additionally, selective super-plasticizer needs to be used because a high amount of water is demanded from the use of a large amount of silica fume.

Chemical Recycling Technology from Polyester Wastes (폴리에스터 폐자원의 화학적 재활용기술)

  • Han, Myung-Wan;Kang, Kyung-Suk;Song, Jae-Kyung
    • Elastomers and Composites
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    • v.47 no.2
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    • pp.96-103
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    • 2012
  • This paper reviews recent technologies for recycling poly (ethylene terephthalate) wastes. Wide application and non-biodegradability of the PET creates huge amounts of waste and disposal, leading to an environmental problem and economic loss. Chemical recycling can be a promising technology to deal with these problems by converting the waste into useful feedstock material for polyester production. Chemical recycling of polyethylene terephthalate are processes where the PET polymer chain is destructed by the impact of glycol (MEG) causing glycolysis, methanol causing methanolysis or water causing hydrolysis. After intensive purification polyester oligomers or the monomers MEG, dimethyl telephthalate (DMT) or purified terephthalic acid (PTA) are received which are re-used to produce polyester products.

A Study on the Lifetime Prediction of Lithium-Ion Batteries Based on the Long Short-Term Memory Model of Recurrent Neural Networks

  • Sang-Bum Kim
    • International Journal of Internet, Broadcasting and Communication
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    • v.16 no.3
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    • pp.236-241
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    • 2024
  • Due to the recent emphasis on carbon neutrality and environmental regulations, the global electric vehicle (EV) market is experiencing rapid growth. This surge has raised concerns about the recycling and disposal methods for EV batteries. Unlike traditional internal combustion engine vehicles, EVs require unique and safe methods for the recovery and disposal of their batteries. In this process, predicting the lifespan of the battery is essential. Impedance and State of Charge (SOC) analysis are commonly used methods for this purpose. However, predicting the lifespan of batteries with complex chemical characteristics through electrical measurements presents significant challenges. To enhance the accuracy and precision of existing measurement methods, this paper proposes using a Long Short-Term Memory (LSTM) model, a type of deep learning-based recurrent neural network, to diagnose battery performance. The goal is to achieve safe classification through this model. The designed structure was evaluated, yielding results with a Mean Absolute Error (MAE) of 0.8451, a Root Mean Square Error (RMSE) of 1.3448, and an accuracy of 0.984, demonstrating excellent performance.

The Patent Analysis of the Treatment Technology of Asbestos Wastes (석면 폐기물 처리 특허기술 분석)

  • Kim, Jong-Heon;Cho, Jin-Dong;Lee, Sang-Kwon;Cha, Seong-Ki
    • Economic and Environmental Geology
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    • v.44 no.5
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    • pp.451-462
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    • 2011
  • Asbestos or its applications have been used for long times and for various purposes in our life because of their merits, namely fire resistance, electric insulation and chemical resistance capacity etc. Despite of theses many merits, one of the problems of asbestos is shown toxicity according to its fiber type. So we need data to solve about this problem. In this paper, we study on the technical method of asbestos waste treatment and on the trends of asbestos researches and developments by the analysis of its patents and DWPI database materials. As a result, the asbestos-waste treatment data in the its related patents is used 267 cases to analyze. These data are divided into 86(32.5%) cases of solid waste disposal(B09B). 41(16.6%) cases of separation(B01D) and 27(10.2%) of lime, magnesia, slag, cement and their composites(C04B).

Advanced Treatment of Sewage Using Waste Plastic Vessel Media (폐플라스틱용기 미디어를 활용한 오수고도처리)

  • Kim, Jae-Yong;Um, Myeong-Heon;An, Dae-Hyun;Shim, Myeong-Jin
    • Applied Chemistry for Engineering
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    • v.17 no.1
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    • pp.58-61
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    • 2006
  • The object of this study was to develop an advanced method for fluid flow and oxygen transmission and increase adhesive property of microorganism to waste plastic vessel that was made of microorganism media. Through lab scale experiments, we found the optimum packed media volume rate and method, and when the optimum condition was applied to pilot plant, we confirmed possibility of advanced treatment. The sewage that was used in the test was the sewage disposal facility established in C and K elementary schools, which utilized waste plastic media oxidation engineering method. Analysis showed that removal efficiency of organic matter, SS, T-N and T-P was very high, that the sewage disposal facility maintained stability of treatment when changeable load of raw sewage flowed in.

Utilization of Kota stone slurry powder and accelerators in concrete

  • Devi, Kiran;Saini, Babita;Aggarwal, Paratibha
    • Computers and Concrete
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    • v.23 no.3
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    • pp.189-201
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    • 2019
  • Recent advances in the concrete technology are aiding in minimizing the use of conventional materials by substituting by-products of various industries and energy sources. A large amount of stone waste i.e., dust and slurry form both are being originated during natural stone processing and causing deadily effects on the environment. The disposal problem of stone waste can be resolved effectively by using waste in construction industries. In present work, Kota stone slurry powder, as a substitution of cement was used along with accelerators namely calcium nitrate and triethanolamine as additives, to study their impact on various properties of the concrete mixtures. Kota stone slurry powder (7.5%), calcium nitrate (1%) and triethanolamine (0.05%) were used separately as well in combination in different concrete mixtures. Mechanical Strength, modulus of elasticity and electrical resistivity of concrete specimens of different mix proportions under water curing were studied experimentally. The durability properties in terms of strength and electrical resistivity against sulphate and chloride solution attack at various curing ages were also studied experimentally. Results showed that accelerators and Kota stone slurry powder separately enhanced the mechanical strength and electrical resistivity; but, their combination decreased strength at all curing ages. The durability of concrete specimens was also affected under the exposure to chemical attack too. Kota stone slurry powder found to be the most effective material among all materials. Material characterization was also done to study the microstructural properties.