• Korean Chemical Engineering Research
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• 제60권1호
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• pp.51-61
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• 2022

Gas separation via hollow fibre membrane modules (HFMM) is deemed to be a promising technology for natural gas sweetening, particularly for lowering the level of carbon dioxide (CO₂) in natural gas, which can cause various problems during transportation and process operation. Separation performance via HFMM is affected by membrane properties, module specifications and operating conditions. In this study, a mathematical model for HFMM is developed, which can be used to assess the effects of the aforementioned variables on separation performance. Appropriate boundary conditions are imposed to resolve steady-state values of permeate variables and incorporated in the model equations via an iterative numerical procedure. The developed model is proven to be reliable via model validation against experimental data in the literature. Also, the model is capable of capturing axial variations of process variables as well as predicting key performance indicators. It can be extended to simulate a large-scale plant and identify an optimal process design and operating conditions for improved separation efficiency and reduced cost.

• 자원환경지질
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• 제55권6호
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• pp.617-632
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• 2022

In recent years, environmental pollution and determining the main factors causing this pollution have become an important issue. This study investigates the relationship between the agricultural sector and environmental pollution in Azerbaijan for 1992-2018. The dependent variable in the study is the agricultural greenhouse gas emissions (CO₂ equivalent). Eight variables were selected as explanatory variables: four agricultural inputs and four agricultural macro indicators. Unit root tests, ARDL boundary test, FMOLS, DOLS and CCR long-term estimators, Granger causality analysis, and variance decomposition analyses were used to investigate the effect of these variables on agricultural emissions. The results show that chemical fertilizer consumption, livestock number, and pesticide use positively and statistically significantly affect agricultural emissions from agricultural input variables. In contrast, agricultural energy consumption has a negative and significant effect. From agricultural macro indicator variables, it was found that the crop and animal production index had a positive and significant effect on agricultural emissions. According to the Granger causality test results, it was concluded that there are a causality relationship from chemical fertilizer consumption, livestock number, crop and livestock production index variables towards agricultural emissions. Considering all the results obtained, it is seen that the variables that have the most effect on the increase in agricultural emissions in Azerbaijan are the number of livestock, the consumption of chemical fertilizers, and the use of pesticides, respectively. The results from the research will contribute to the information on agricultural greenhouse gas emissions and will play an enlightening role for policymakers and the general public.

• 한국안전학회지
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• 제31권3호
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• pp.162-167
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• 2016

As the simple empirical and phenomenological model applied to the analysis of leakage and explosion of chemical substances does not regard numerous variables, such as positional density of installations and equipment, turbulence, atmospheric conditions, obstacles, and wind effects, there is a significant gap between actual accident consequence and computation. Therefore, the risk management of a chemical plant based on such a computation surely has low reliability. Since a process plant is required to have outcomes more similar to the actual outcomes to secure highly reliable safety, this study was designed to apply the CFD (computational fluid dynamics) simulation technique to analyze a virtual prediction under numerous variables of leakages and explosions very similarly to reality, in order to review the computation technique of the practical safety distance at a process plant.

• 한국수소및신에너지학회논문집
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• 제34권6호
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• pp.712-721
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• 2023

While hydrogen is widely used, it has a low minimum ignition energy, raising safety concerns when using it. This research studied which parameters are the key variables in the hydrogen release and diffusion. These parameters were divided into six process variables in the initial release and two environmental variables in the dispersion. One hundred and twenty cases were selected through design of experiment, and the end-point in each case were analyzed using PHAST. Afterwards, an end-point prediction model was developed using RSM and ANOVA, and the impact of each variable on the endpoint was analyzed. As a result, the influence of eight variables was graded. The nozzle diameter had the greatest influence on the end-point, while the pipe roughness coefficient had no effect on the end-point. It is expected that these results will be used as basic data to improve safety across all fields of hydrogen handling facilities.

• 한국가스학회:학술대회논문집
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• 한국가스학회 2001년도 추계학술발표회 논문집
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• pp.150-153
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• 2001

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 2001년도 ICCAS
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• pp.50.1-50
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• 2001

Dynamic optimization with partially structured model in a slurry-phase HDPE reactor is implemented by the modified hierarchical dynamic optimization. Optimal trajectories of MI and density of HDPE are calculated as controlled variables and optimal profiles of the concentrations of ethylene, hydrogen and comonomer are calculated as manipulated variables in dynamic optimization. MI, density, the concentrations of ethylene, hydrogen and comonomer are used as controlled variables and flow rates of ethylene, hydrogen and comonomer are sued as manipulated variables in control implementation. Two-level hierarchical method is applied in dynamic optimization to reduce computation time. In the upper level formulation ...

• 한국환경보건학회지
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• 제43권5호
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• pp.360-369
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• 2017

Objectives: The organizational culture of small-scale enterprises is influenced by a lack of awareness of industrial accidents and a business-oriented culture. Therefore, the purpose of this study is to establish a correlation between chemical awareness and worker safety, which is the reason why a company's safety environment is responsible for human factor accidents. Methods: The research model established the organizational culture, human relationships, organizational relationships, workplace culture, safety climate, and safety parameters, all of which affect the perception of chemical substances, then established safety rankings, communication, safety regulations, and safety support. Results: In order to derive the results of this study, the satisfaction level was mostly derived from the degree of engagement (+) depending on the number of years worked, in the hierarchical regression analysis. During work with chemicals, the number of years spent on the level of the service was determined by the influence of the chemical (-). Based on this company, the occurrence of chemical accidents caused by chemical materials was felt to be felt at the risk of causing the hazard to be felt, the absence of physical damage was excluded from the variables. The other variables detected in the variables were $62.8{\pm}24.4$. Conclusion: As a result, it is necessary to develop a statistical model for the verification of the hierarchical regression analysis, and the relationship between safety and awareness of the dangers of chemicals and biological agents requires periodic safety training. Job satisfaction was found to be higher if the level of awareness was sufficient.

• Bulletin of the Korean Chemical Society
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• 제14권5호
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• pp.631-635
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• 1993

The polarizability and the transition state energy of a cephalosporin are assumed to be theoretical indices of the permeability through the outer membrane and of reactivity of ${\beta}$ -lactam ring with penicillin binding proteins, respectively, in Gram-negative bacteria. They are computed by AM1 method and used as variables of quantitative structure-activity relationship study. The results justify quadratic dependence of the activity on the variables. The intersection of difference volumes between $\beta-lactamase$ stable cephalosporins and unstable ones manifests that the steric hindrance of 7-side chain is responsible for the ${\beta}$ -lactamase stability.

• Bulletin of the Korean Chemical Society
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• 제7권5호
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• pp.347-353
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• 1986

Fisher's discriminant method has been applied to the problem of the classification of Korean potsherds, using their elemental composition as analyzed by neutron activation analysis. A combination of analytical data by means of statistical linear discriminant analysis has resulted in removal of redundant variables, optimal linear combination of meaningful variables and formulation of classification rules.

• 한국해양학회지
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• 제16권2호
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• pp.43-48
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• 1981

To carry out baseline studies on monitoring systems for red tides in Jinhae bay, measurements and analyses were made on seawater samples from 15 sampling stations during 15 months from July, 1979. Water quality parameters studied are temperature, pH, DO, salinity, COD, SS, NO$\sub$3/, NO$\sub$2/, PO$\sub$4/, SiO$\sub$2/, Ca, Mg, Cd, Cu, Pb, Zn, Chlorophyll ${\alpha}$, diatoms and dinoflagellates. Multiple regression analyses were undertaken with chlorophyll ${\alpha}$, cell numbers of diatoms and dinoflagellates as the dependent variables and water quality parameters as the independent variables. The results showed that biomass, expressed as total cell numbers of diatoms and dinoflagellates, was largely influenced by COD, salinity and nutrients.