• Title/Summary/Keyword: Chemical treatment

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Characteristics Evaluation of Thin Films Formed on Mg-Al Alloy in Various Chemical Conversion Solution Conditions (다양한 화성처리 용액 조건에서 마그네슘-알루미늄 합금위에 형성된 박막의 특성 평가)

  • Jang Seok-Ki;Kim Seong-Jong;Kim Jeong-Il
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.1
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    • pp.98-106
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    • 2005
  • The chemical conversion film formed on magnesium alloy was investigated by using the colloidal silica with some parameters such as solution pH. temperature, solution conditions, and treatment time. Moreover. the solutions consisted of colloidal silica titanium sulfate, and cobalt ions were used for the colloidal silica film to having a good corrosion resistance and adhesion properties. It was thought that the film at 298K was made with combination of Si-O. The quantity of film formed at high temperature such as 333K and 353K is smaller than dissolved quantity during chemical conversion treatment. Adding $CoSO_4$ to the colloidal silica solution enhanced the adhesion force between the silica film and magnesium substrate, The optimum conditions for the chemical conversion treatment solution were PH 2.90 s treatment, and 298K.

Treatment of Waste Dry Etching Gas in Semiconductors Manufacturing Process

  • Yamamoto, Hideki;Kawahara, Takahiro;Shibata, Junji
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.711-714
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    • 2001
  • A new technology to make fluoride gas such as NF$_3$contained in the exhaust gas from semiconductor manufacturing plants convert directly into a harmless substance have been established and new concept on the disposal treatment of global warming gases were presented. Experimental results verify that the chemical reactions can be take place at substantially lower temperature of 80-40$0^{\circ}C$ as compared with the combustion treatment method. Reaction product is mainly metal fluoride which is a harmless and a valuable chemical material as one of new resources. The other favorable characteristics are that the continuous treatment is possible at a low temperature under atmospheric pressure. Furthermore this process is compact, easily controllable and safely operable at low running cost. This paper concerns with a new harmless disposal treatment of toxic global warming gas.

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Improvement of Plating Characteristics Between Nickel and PEEK by Plasma Treatment and Chemical Etching

  • Lee, Hye W.;Lee, Jong K.;Park, Ki Y.
    • Corrosion Science and Technology
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    • v.8 no.1
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    • pp.15-20
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    • 2009
  • Surface of PEEK(poly-ether-ether-ketone) was modified by chemical etching, plasma treatment and mechanical grinding to improve the plating adhesion. The plating characteristics of these samples were studied by the contact angle, plating thickness, gloss and adhesion. Chemical etching and plasma treatment increased wettability, adhesion and gloss. The contact angle of as-received PEEK was $61^{\circ}$. The contact angles of chemical etched, plasma treated or both were improved to the range of $15{\sim}33^{\circ}$. In the case of electroless plating, the thickest layer without blister was $1.6{\mu}m$. The adhesion strengths by chemical etching, plasma treatment or both chemical etching and plasma treatment were $75kgf/cm^2$, $102kgf/cm^2$, $113kgf/cm^2$, respectively, comparing to the $24kgf/cm^2$ of as-received. In the case of mechanically ground PEEKs, the adhesion strengths were higher than those unground, with the sacrifice of surface gloss. The gloss of untreated PEEK were greater than mechanically ground PEEKs. Plating thickness increased linearly with the plating times.

Review for Physical and Chemical Process for Heavy Metal Treatment

  • Jeon, Choong
    • Clean Technology
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    • v.18 no.4
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    • pp.341-346
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    • 2012
  • Many researchers have studied that many processes to effectively remove heavy metals in water/wastewater. Especially, among many processes, physical and chemical processes are relatively simple and obtain high treatment efficiency for removal heavy metals compared with biological treatment. Recently, interests in physical and chemical methods are sharply increasing again because of dangerousness for radioactive element. In this study, various physical and chemical processes such as chemical precipitation, ion-exchange, electrodialysis, and membrane separation are introduced.

Advanced oxidation technologies for the treatment of nonbiodegradable industrial wastewater (난분해성 산업폐수 처리를 위한 고도산화기술)

  • Kim, Min Sik;Lee, Ki-Myeong;Lee, Changha
    • Journal of Korean Society of Water and Wastewater
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    • v.34 no.6
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    • pp.445-462
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    • 2020
  • Industrial wastewater often contains a number of recalcitrant organic contaminants. These contaminants are hardly degradable by biological wastewater treatment processes, which requires a more powerful treatment method based on chemical oxidation. Advanced oxidation technology (AOT) has been extensively studied for the treatment of nonbiodegradable organics in water and wastewater. Among different AOTs developed up to date, ozonation and the Fenton process are the representative technologies that widely used in the field. Based on the traditional ozonation and the Fenton process, several modified processes have been also developed to accelerate the production of reactive radicals. This article reviews the chemistry of ozonation and the Fenton process as well as the cases of application of these two AOTs to industrial wastewater treatment. In addition, research needs to improve the cost efficiency of ozonation and the Fenton process were discussed.

Validation of method for chemical treatment of pig carcasses for the control of livestock infectious diseases (가축 전염병 관리를 위한 돼지 사체의 화학적 처리 방법)

  • Oh, Yeonsu;Yoon, Suk Hoon;Tark, Dong-Seob;Cho, Ho-Seong
    • Korean Journal of Veterinary Service
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    • v.44 no.4
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    • pp.283-290
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    • 2021
  • This is a study on the improvement of the chemical treatment method of the livestock carcass treatment newly introduced in the livestock infectious disease prevention method in order to improve the problems of the existing burial-centered carcass treatment method when a livestock infectious disease occurs. It was conducted to establish detailed treatment standards for the chemical treatment method of pig carcasses based on the results of proof of the absence of infectious diseases in pigs. After inoculating pig carcasses with 10 pathogens (6 viruses [FMDV, ASFV, CSFV, PCV2, PRRSV, PEDV] and 4 bacteria [Lawsonia intracellularis, Clostridium perfringens type C, E. coli, Salmonella Typhimurium]) It was treated at 90℃ for 5 hours in a potassium hydroxide (KOH) liquid solution corresponding to 15% of the body weight. This method liquefies all cadaveric components and inactivates all inoculated pathogens. Based on these results, it was possible to prove that chemical treatment of pig carcasses is effective in killing pathogens and is a safe method without the risk of disease transmission. Although there are problems to be solved in the processing and operation of the chemical treatment products of livestock carcasses, the chemical treatment method of livestock carcasses can be suggested as an alternative to the current domestic burial-centered livestock carcass treatment method, preventing environmental pollution, and contributing to public health.

Effect of post-treatment routes on the performance of PVDF-TEOS hollow fiber membranes

  • Shadia R. Tewfik;Mohamed H. Sorour;Hayam F. Shaalan;Heba A. Hani;Abdelghani G. Abulnour;Marwa M. El Sayed;Yomna O. Mostafa;Mahmoud A. Eltoukhy
    • Membrane and Water Treatment
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    • v.14 no.2
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    • pp.85-93
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    • 2023
  • Membrane separation is widely used for several applications such as water treatment, membrane reactors and climate change. Cross-linked organic-inorganic hybrid polyvinylidene fluoride (PVDF) / Tetraethyl orthosilicate (TEOS) was adopted for the preparation of optimized hollow membrane (HFM) for membrane distillation or other low pressure separators for mechanical properties and permeability under varying pretreatment schemes. HFMs were prepared on semi-pilot membrane fabrication system. Novel adopted post-treatment schemes involved soaking in glycerol, magnesium sulphate (MgSO4), sodium hypochlorite (NaOCl), and isopropanol for different durations. All fibers were characterized for morphology using a scanning electron microscope (SEM), surface roughness using atomic force microscope (AFM), elemental composition by examining Energy Dispersive Spectroscopy (EDS), water contact angle (CA°) and porosity. The performance of the fibers was evaluated for pure water permeation flux (PWF). Post-treatment with MgSO4 gave the highest both tensile modulus and flux. Assessment of properties and performance revealed comparable results with other organic-inorganic separators, HF or flat. In spite of few reported data on post treatment using MgSO4 in presence of TEOS, this proves the potential of low cost treatment without negative impact on other membrane properties. The flux is also comparable with hypochlorite which manifests substantial precaution requirements in actual industrial use.The relatively high values of flux/bar for sample treated with TEOS, post treated with MgSO4 and hypochlorite are 88 and 82 LMH/bar respectively.

Saturation curves for chemical coagulation of wastewater treatment (화학 응집제 투입에 따른 수질항목별 하수처리 반응곡선)

  • Ryu, Jae-Na;Oh, Je-Ill;Lee, Kyeoung-Jong
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.5
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    • pp.537-548
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    • 2010
  • Recently the Government has announced updated water quality standards for wastewater treatment effluent (become effective in 2012). That includes highly enforced regulations for T-P, BOD and COD, and a large budget, in particular for phosphorus removal, was set by the Ministry of environment. Chemical coagulation destabilizes colloidal particles so that particles grow to larger flocs, and solid particles are removed by solid-liquid separation. The efficiency of chemical coagulation depends on a various factors, including coagulant types and costs, construction and operation costs for the treatment facilities and so on. The proper selection should be based on the treatment efficiency of coagulants and underlying costs. The current research was to evaluate the treatment efficiencies of coagulants on a variety of wastewater influents and to develop saturation curves for several water quality parameters. Typical $Al_2(SO_4)_3$ and $FeCl_3$ were tested under a range of coagulant concentrations. The pollutant removal efficiencies of chemical treatment both for the $Al_2(SO_4)_3$ and $FeCl_3$ were especially high for T-P, followed by SS, BOD and COD. Correlation test also proved the highest relationship between SS and T-P.

Effect of Cattle Slurry on the Soil Charaters and Production of Forage Crop (액상구비 시용이 사료작물의 생산성과 토양 성분에 미치는 영향)

  • 전병태;이상무;김재영;오인환
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.15 no.1
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    • pp.52-60
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    • 1995
  • This experiment was carried out to determine the effect of nitrogen application level of cattle sluny(T1:150, T3:250, T53.50 kglha) and chemical fertilizer(T2:150, T4:250, T6:350 kg/ha) on the growth characteristics, dry matter yield and chemical soil property of Sorghum-Sudangrass hybrid [Sorghum bicolor L. Moench]. The results obtained are summarized as follows: Mean stem diameter was significantly increased by increasing nitrogen application level of cattle slurry and chemical fertilizer. Especially, T6 treatment was the highest as 11.1 mm, while T1 treatment w a the lowest as 0.3 mrn. According to the same level of nitrogen application, cattle slurry treaunent(T1, T3 and T5) were showed a lower mean stem hardness than chemical fertilizer treatment(T2, T4 and T6). Especially, T3 treatment was the softest at 0.7 kg/$cm^2$. The dead stubble and tiller number were increased by increasing nitrogen level of cattle slurry and chemical fertilizer(P

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Chemical Surface Treatment of Carbon Black to Enhance Interfacial Adhesion Between Elastomer and Carbon Black (화학적 표면처리에 따른 카본블랙/고무 복합재료의 접착력 증가)

  • Kim, Jeong-Soon;Lee, Jae-Rock;Shin, Chae-Ho;Nah, Chang-Woon;Park, Soo-Jin
    • Elastomers and Composites
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    • v.34 no.3
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    • pp.222-228
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    • 1999
  • In this work, the effect of chemical treatments on the carbon blacks as-received has been studied in the context of surface, adsorption, microstructure properties, and physical surface free energetics. As an experimental result, the basic chemical treatment leads to an increase in the either dispersive or specific component without significant change the pH and specific surface area. While, acidic chemical treatment do significantly change the surface and adsorption properties, and microstructures of the carbon blacks. In particular, the result given by basic chemical treatment shows an increase of the London dispersive component of the surface free energy which is a major parameter in evaluating the dispersion or specific surface area of the carbon blacks studied. This is probably a major role in evaluating the dispersion the carbon blacks, which are reinforced in elastomer matrix in a composite system.

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