• 제목/요약/키워드: Chemical test

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Vapor-liquid Interface of Argon by Using a Test-area Simulation Method

  • Lee, Song-Hi
    • Bulletin of the Korean Chemical Society
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    • 제33권1호
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    • pp.167-170
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    • 2012
  • A test-area molecular dynamics simulation method for the vapor-liquid interface of argon through a Lennard-Jones intermolecular potential is presented in this paper as a primary study of interfacial systems. We found that the calculated density profile along the z-direction normal to the interface is not changed with time after equilibration and that the values of surface tension computed from this test-area method are fully consistent with the experimental data. We compared the thermodynamic properties of vapor argon, liquid argon, and argon in the vapor-liquid interface. Comparisons are made with kinetic and potential energies, diffusion coefficient, and viscosity.

FDS 열분해 모델을 이용한 콘칼로리미터(ISO 5660) 화재 시뮬레이션 (Fire Simulation by Pyrolysis Method of FDS for the Small Cone Calorimeter (ISO 5660))

  • 양성진;장정훈;강찬용
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2009년도 춘계학술대회 논문집
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    • pp.206-212
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    • 2009
  • Chemical behaviors of each surface material for interior facilities affect to fire initiation and growth in general fire situation. These chemical behaviors were characterized by thermal properties (Heat release rate, Pyrolysis rate, specific heat, etc) which could be derived from experimental test. Especially, Heat release rate which indicates aspect of fire size is one of the most important property to asses fire hazard and protection needs. The cone calorimeter test (ISO 5660) has recently assumed to a dominant role in bench scale fire testing to obtain the Heat release rate of materials. This value could be calculated by the 'Oxygen Consumption Method' under various producing irradiances to each surface of materials. In this study, Process of the cone calorimeter test was simulated by Pyrolysis model of FDS (Fire Dynamics Simulator by NIST) base on the ISO 5660 international standard. Then, we could estimate the simulation method of FDS in case of single materials through the comparative study with test results.

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Metakaolin 혼합 고강도콘크리트의 내구특성 평가 (Estimation on the Durability of High-Strength Concrete using Metakaolin)

  • 문한영;염준환;문수동;이상호
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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    • pp.217-220
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    • 2004
  • Metakaolin is a cementitious material for producing high-strength concrete. This material is now used as substitute for silica-fume. In this paper, we did the durability test such as chloride ion diffusion, chemical attack. repeated freezing and thawing, carbonation. In the chloride ion diffusion test, according to the increase of substitute of metakaolin & silica-fume for binder, the diffusion coefficient is more reduced. And in the chemical attack test, according to the increase of substitute, the resistance is more excellent. In the other durability test, the concrete using metakaolin is also compared with those of the portland cement concrete and silica fume concrete. According to these tests, we recognized that metakaolin is able to be used as a substitute for silica-fume.

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국내 쇄석골재의 화학반응성 분석 (An Analysis on the Reaction of Crushed Aggregates)

  • 이장화;김성욱;최일섭
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1993년도 가을 학술발표회 논문집
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    • pp.97-102
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    • 1993
  • In the country, due to short comings of natural aggregates of good quality, it is common to use crushed stones. However, the investigation has not been done on the chemical reaction of crushed stones. This study tested and analyzed the aggregate chemical reaction by Petrographic Examination(ASTM C 295),Chemical Metho(ASTM C 289) and Mortar-Bar Method (ASTM C 227). As a result, most of test aggregates didn't show any reaction but many have common deleterious mineral. Therefore, there exists the possibility of chemical reaction in petrographic point of view.

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Effect of a Silicone Defoamant on the Motion of Single Air Bubbles Rising in Lubricant

  • Shim, Joosup;Cho, Wonoh;Chung, Keunwoo;Kim, Woung Woon
    • KSTLE International Journal
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    • 제1권1호
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    • pp.52-58
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    • 2000
  • The velocity and motion of single air bubbles rising through lubricant have been experimentally investigated to test the effect of silicon defoamant The investigation reveals that the velocity is markedly retarded by the addition of small amount of silicone defoamant. This retardation of rising velocity of air bubbles is proposed by increasing of Drag force or reducing of Buoyancy force around the surfaces of the bubbles.

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Synthesis of Pentapeptide Containing DL-1-Aminobenzylphosphonic Acid

  • Hong, Suk-In;Kim, Yong-Joon
    • Bulletin of the Korean Chemical Society
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    • 제1권3호
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    • pp.114-115
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    • 1980
  • Six previously unreported peptides containing diethyl DL-1-aminobenzylphosphonate terminal unit were prepared. These are: Diethyl phthalyl-glycyl-gly-DL-1-aminobenzylphosphonate, diethyl gly-gly-DL-aminobenzylphosphonate, diethyl phthalyl-gly-gly-gly-DL-1-aminobenzylphosphonate , diethyl phthalyl-gly-gly-gly-gly-DL-1-aminobenzylphosphonate, diethyl phthalyl-DL-1-phenylalanyl-DL-1-aminobenzylphosphonate, diethyl phthalyl-gly-DL-phenylalanyl-DL-1-aminobenzylphosphonate. All the compounds were obtained as white crystalline powder and characterized by means of elemental analysis, IR spectroscopy, NMR spectroscopy, and ninhydrin test.

오일스네어에 대한 오일 흡착기준 정립 및 고시방향 연구 (A Study on the Evaluation of Oil-adsorption Characteristics and Policy Guideline of Oil Snare)

  • 진영민;유주영;최상선;주아람;이준혁;이순홍
    • 한국안전학회지
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    • 제34권6호
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    • pp.22-28
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    • 2019
  • In South Korea, the enact of Korean Coast Guard Act-1 manages physical and chemical oil-dispersants. Oil snare, which is made of polypropylene, is newly added to the aforementioned act, and it has advantage on the ease of recovery compare to other adsorbents. This study synthesized bunker B-oil with diesel-oil and bunker C-oil to perform an adsorption test based on three samples which were manufactured in South Korea. As a result, adsorption test revealed 5.2 g/g more adsorption than the previous results from the act. Additional toluene test revealed that all the samples satisfied 90.0%, however coloured samples could release its pigment on the marine environment. Thus, colorless samples are recommended on the risk management of marine accidents. The study on the basic direction of the calculation of the test items and the standard value for the quality control of the oil snare was also carried out.

Synthesis and Properties of Bio-Thermoplastic Polyurethanes with Different Isocyanate Contents

  • Li, Xiang Xu;Sohn, Mi Hyun;Cho, Ur Ryong
    • Elastomers and Composites
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    • 제54권3호
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    • pp.225-231
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    • 2019
  • Bio-based polyester polyol was synthesized via esterification between azelaic acid and isosorbide. After esterification, bio-based polyurethanes were synthesized using polyester polyol, 1,3-propanediol as the chain extender, and 4,4'-diphenylmethane diisocyanate, in mixing ratios of 1:1:1.5, 1:1:1.8, 1:1:2, and 1:1:2.3. The bio TPU (Thermoplastic Polyurethane) samples were characterized by using FT-IR (Fourier Transform Infrared Spectroscopy), TGA (Thermal Gravimetric Analysis), DSC (Differential Scanning Calorimetry), and GPC (Gel Permeation Chromatography). The mechanical properties (tensile stress and hardness) were obtained by using UTM, a Shore A tester, and a Taber abrasion tester. The viscoelastic properties were tested by an Rubber Processing Analyzer in dynamic strain sweep and dynamic frequency test modes. The chemical resistance was tested with methanol by using the swelling test method. Based on these results, the bio TPU synthesized with the ratio of 1:1:2.3, referred to as TPU 4, showed the highest thermal decomposition temperature, the largest molecular weight, and most compact matrix structure due to the highest ratio of the hard segment in the molecular structure. It also presented the highest tensile strength, the largest elongation, and the best viscoelastic properties among the different bio TPUs synthesized herein.

약액주입에 의한 제주도 송이지층의 지반보강에 관한 연구 (A Study on the Ground Reinforcement of Jeju Scoria Layer by Chemical Grouting)

  • 양기호;박정준;김영훈;변요셉;이은종;천병식
    • 한국지반환경공학회 논문집
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    • 제15권2호
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    • pp.75-82
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    • 2014
  • 최근 대형화되고 있는 제주도의 토목공사에 약액주입공법을 비롯한 여러 가지 종류의 지반보강공법을 실시하고 있다. 이에 본 연구에서는 지반보강공법 시에 주입효과가 탁월하고, 주입재의 강도가 우수하며, 영구적인 차수 및 보강에 적합한 재료, 주입조건 등을 실험을 통해 규명하였다. 실내시험으로는 제주도 송이 지반의 기본 물성시험을 실시하였고, 주입재의 일축압축강도시험과 내구성시험을 통해 주입재의 종류를 선정하였다. 송이의 모형지반을 조성하여 주입량 결정시험 및 모형토조를 이용한 주입범위 평가시험을 통해 선정된 재료의 주입성능을 확인하였다. 시험결과 MSG가 보통시멘트에 비해 강도, 내구성, 주입성능 모두 우수하게 나오는 것으로 분석되어 향후 약액주입공법으로 설계 및 시공 시 설계보조자료로서 가능할 것으로 판단된다.

Assessment of Seed Viability and Vigour in Neem (Azadirachta indica A. Juss.)

  • Kumar, Devendra
    • Journal of Forest and Environmental Science
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    • 제29권4호
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    • pp.282-291
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    • 2013
  • Rapid loss in viability of neem (Azadirachta indica A. Juss.) seed is a major problem. Present effort was undertaken for developing a set pattern for assessing of viability and vigour in seed of various mother tree age of neem (Age I-06 years, Age II-15 years, Age III-25 years and Age IV->30 years old). Various viability test viz. triphenyle tetrazolium chloride test, electrical conductivity, excised embryo test, and germination test have been performed on seeds obtained from mother tree age classes. Inconsistency was observed with the TTC and EC test in germination of seed in laboratory as well as nursery. While various vigour tests viz. cold test, chemical stress test (methanol stress test), and accelerated ageing test alongwith ageing index, germination test (G%, MGT and GV) and various seedling growth parameters like seedling length (cm), number of leaves, collar diameter (cm), total biomass (g) alongwith mathematical indices i.e. vigour index, sturdiness quotient, volume index, quality index, root shoot ratio in nursery as well have been taken for study and showed better consistency. On the basis present study results of various viability and vigour test indicated that mother tree age class II performed better in comparison to others and it can be recommended for seed collection. Further it is also recommended that viability of neem seed may be assessed using various laboratory tests like excise embryo test and germination test (G%, MGT and GV) and vigour test may be taken preferably by cold germination test, chemical (methanol) stress test, accelerated ageing test in laboratory and germination alongwith various seedling growth parameters seedling length (cm), number of leaves, collar diameter (cm), total biomass (g) alongwith mathematical indices like Vigour Index, Sturdiness quotient, Volume Index, Quality index, root shoot ratio in nursery as discussed in this study.