• Title/Summary/Keyword: Chemical test

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Vapor-liquid Interface of Argon by Using a Test-area Simulation Method

  • Lee, Song-Hi
    • Bulletin of the Korean Chemical Society
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    • v.33 no.1
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    • pp.167-170
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    • 2012
  • A test-area molecular dynamics simulation method for the vapor-liquid interface of argon through a Lennard-Jones intermolecular potential is presented in this paper as a primary study of interfacial systems. We found that the calculated density profile along the z-direction normal to the interface is not changed with time after equilibration and that the values of surface tension computed from this test-area method are fully consistent with the experimental data. We compared the thermodynamic properties of vapor argon, liquid argon, and argon in the vapor-liquid interface. Comparisons are made with kinetic and potential energies, diffusion coefficient, and viscosity.

Fire Simulation by Pyrolysis Method of FDS for the Small Cone Calorimeter (ISO 5660) (FDS 열분해 모델을 이용한 콘칼로리미터(ISO 5660) 화재 시뮬레이션)

  • Yang, Sung-Jin;Jang, Jung-Hun;Kang, Chan-Yong
    • Proceedings of the KSR Conference
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    • 2009.05a
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    • pp.206-212
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    • 2009
  • Chemical behaviors of each surface material for interior facilities affect to fire initiation and growth in general fire situation. These chemical behaviors were characterized by thermal properties (Heat release rate, Pyrolysis rate, specific heat, etc) which could be derived from experimental test. Especially, Heat release rate which indicates aspect of fire size is one of the most important property to asses fire hazard and protection needs. The cone calorimeter test (ISO 5660) has recently assumed to a dominant role in bench scale fire testing to obtain the Heat release rate of materials. This value could be calculated by the 'Oxygen Consumption Method' under various producing irradiances to each surface of materials. In this study, Process of the cone calorimeter test was simulated by Pyrolysis model of FDS (Fire Dynamics Simulator by NIST) base on the ISO 5660 international standard. Then, we could estimate the simulation method of FDS in case of single materials through the comparative study with test results.

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Estimation on the Durability of High-Strength Concrete using Metakaolin (Metakaolin 혼합 고강도콘크리트의 내구특성 평가)

  • Moon Han Young;Yum Jun Hwan;Moon Su Dong;Lee Sang Ho
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.217-220
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    • 2004
  • Metakaolin is a cementitious material for producing high-strength concrete. This material is now used as substitute for silica-fume. In this paper, we did the durability test such as chloride ion diffusion, chemical attack. repeated freezing and thawing, carbonation. In the chloride ion diffusion test, according to the increase of substitute of metakaolin & silica-fume for binder, the diffusion coefficient is more reduced. And in the chemical attack test, according to the increase of substitute, the resistance is more excellent. In the other durability test, the concrete using metakaolin is also compared with those of the portland cement concrete and silica fume concrete. According to these tests, we recognized that metakaolin is able to be used as a substitute for silica-fume.

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An Analysis on the Reaction of Crushed Aggregates (국내 쇄석골재의 화학반응성 분석)

  • 이장화;김성욱;최일섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1993.10a
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    • pp.97-102
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    • 1993
  • In the country, due to short comings of natural aggregates of good quality, it is common to use crushed stones. However, the investigation has not been done on the chemical reaction of crushed stones. This study tested and analyzed the aggregate chemical reaction by Petrographic Examination(ASTM C 295),Chemical Metho(ASTM C 289) and Mortar-Bar Method (ASTM C 227). As a result, most of test aggregates didn't show any reaction but many have common deleterious mineral. Therefore, there exists the possibility of chemical reaction in petrographic point of view.

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Effect of a Silicone Defoamant on the Motion of Single Air Bubbles Rising in Lubricant

  • Shim, Joosup;Cho, Wonoh;Chung, Keunwoo;Kim, Woung Woon
    • KSTLE International Journal
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    • v.1 no.1
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    • pp.52-58
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    • 2000
  • The velocity and motion of single air bubbles rising through lubricant have been experimentally investigated to test the effect of silicon defoamant The investigation reveals that the velocity is markedly retarded by the addition of small amount of silicone defoamant. This retardation of rising velocity of air bubbles is proposed by increasing of Drag force or reducing of Buoyancy force around the surfaces of the bubbles.

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Synthesis of Pentapeptide Containing DL-1-Aminobenzylphosphonic Acid

  • Hong, Suk-In;Kim, Yong-Joon
    • Bulletin of the Korean Chemical Society
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    • v.1 no.3
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    • pp.114-115
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    • 1980
  • Six previously unreported peptides containing diethyl DL-1-aminobenzylphosphonate terminal unit were prepared. These are: Diethyl phthalyl-glycyl-gly-DL-1-aminobenzylphosphonate, diethyl gly-gly-DL-aminobenzylphosphonate, diethyl phthalyl-gly-gly-gly-DL-1-aminobenzylphosphonate , diethyl phthalyl-gly-gly-gly-gly-DL-1-aminobenzylphosphonate, diethyl phthalyl-DL-1-phenylalanyl-DL-1-aminobenzylphosphonate, diethyl phthalyl-gly-DL-phenylalanyl-DL-1-aminobenzylphosphonate. All the compounds were obtained as white crystalline powder and characterized by means of elemental analysis, IR spectroscopy, NMR spectroscopy, and ninhydrin test.

A Study on the Evaluation of Oil-adsorption Characteristics and Policy Guideline of Oil Snare (오일스네어에 대한 오일 흡착기준 정립 및 고시방향 연구)

  • Jin, Y.M.;You, J.Y.;Choi, S.S.;Joo, A.R.;Lee, J.H.;Lee, Soon-Hong
    • Journal of the Korean Society of Safety
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    • v.34 no.6
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    • pp.22-28
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    • 2019
  • In South Korea, the enact of Korean Coast Guard Act-1 manages physical and chemical oil-dispersants. Oil snare, which is made of polypropylene, is newly added to the aforementioned act, and it has advantage on the ease of recovery compare to other adsorbents. This study synthesized bunker B-oil with diesel-oil and bunker C-oil to perform an adsorption test based on three samples which were manufactured in South Korea. As a result, adsorption test revealed 5.2 g/g more adsorption than the previous results from the act. Additional toluene test revealed that all the samples satisfied 90.0%, however coloured samples could release its pigment on the marine environment. Thus, colorless samples are recommended on the risk management of marine accidents. The study on the basic direction of the calculation of the test items and the standard value for the quality control of the oil snare was also carried out.

Synthesis and Properties of Bio-Thermoplastic Polyurethanes with Different Isocyanate Contents

  • Li, Xiang Xu;Sohn, Mi Hyun;Cho, Ur Ryong
    • Elastomers and Composites
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    • v.54 no.3
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    • pp.225-231
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    • 2019
  • Bio-based polyester polyol was synthesized via esterification between azelaic acid and isosorbide. After esterification, bio-based polyurethanes were synthesized using polyester polyol, 1,3-propanediol as the chain extender, and 4,4'-diphenylmethane diisocyanate, in mixing ratios of 1:1:1.5, 1:1:1.8, 1:1:2, and 1:1:2.3. The bio TPU (Thermoplastic Polyurethane) samples were characterized by using FT-IR (Fourier Transform Infrared Spectroscopy), TGA (Thermal Gravimetric Analysis), DSC (Differential Scanning Calorimetry), and GPC (Gel Permeation Chromatography). The mechanical properties (tensile stress and hardness) were obtained by using UTM, a Shore A tester, and a Taber abrasion tester. The viscoelastic properties were tested by an Rubber Processing Analyzer in dynamic strain sweep and dynamic frequency test modes. The chemical resistance was tested with methanol by using the swelling test method. Based on these results, the bio TPU synthesized with the ratio of 1:1:2.3, referred to as TPU 4, showed the highest thermal decomposition temperature, the largest molecular weight, and most compact matrix structure due to the highest ratio of the hard segment in the molecular structure. It also presented the highest tensile strength, the largest elongation, and the best viscoelastic properties among the different bio TPUs synthesized herein.

A Study on the Ground Reinforcement of Jeju Scoria Layer by Chemical Grouting (약액주입에 의한 제주도 송이지층의 지반보강에 관한 연구)

  • Yang, Kiho;Park, Jeongjun;Kim, Younghun;Byun, Yoseph;Lee, Eunjong;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.2
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    • pp.75-82
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    • 2014
  • Recently, public works becoming bigger in Jeju are implemented various kinds of ground reinforcement method including the chemical grouting method. In this study, we have been investigated on the proper material and the injection condition for the excellent injection effect and the excellent strength of injection material and the permanent waterproof and reinforcement through the experiment. The kind of injection material has been selected through the uniaxial compression test and the endurance test of injection material as the chamber test. An experiment was performed with model ground made of scoria, the injection performance of selected material has been identified through the evaluation test of injection range using the decision test of injection amount and the calibration chamber test. As a result of test, it has been analyzed that MSG appeared to have the excellent strength, durability and injection performance all compared with the ordinary cement, this result is judged to be possible as the ancillary data of design at time of design and construction with the chemical grouting method in the future.

Assessment of Seed Viability and Vigour in Neem (Azadirachta indica A. Juss.)

  • Kumar, Devendra
    • Journal of Forest and Environmental Science
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    • v.29 no.4
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    • pp.282-291
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    • 2013
  • Rapid loss in viability of neem (Azadirachta indica A. Juss.) seed is a major problem. Present effort was undertaken for developing a set pattern for assessing of viability and vigour in seed of various mother tree age of neem (Age I-06 years, Age II-15 years, Age III-25 years and Age IV->30 years old). Various viability test viz. triphenyle tetrazolium chloride test, electrical conductivity, excised embryo test, and germination test have been performed on seeds obtained from mother tree age classes. Inconsistency was observed with the TTC and EC test in germination of seed in laboratory as well as nursery. While various vigour tests viz. cold test, chemical stress test (methanol stress test), and accelerated ageing test alongwith ageing index, germination test (G%, MGT and GV) and various seedling growth parameters like seedling length (cm), number of leaves, collar diameter (cm), total biomass (g) alongwith mathematical indices i.e. vigour index, sturdiness quotient, volume index, quality index, root shoot ratio in nursery as well have been taken for study and showed better consistency. On the basis present study results of various viability and vigour test indicated that mother tree age class II performed better in comparison to others and it can be recommended for seed collection. Further it is also recommended that viability of neem seed may be assessed using various laboratory tests like excise embryo test and germination test (G%, MGT and GV) and vigour test may be taken preferably by cold germination test, chemical (methanol) stress test, accelerated ageing test in laboratory and germination alongwith various seedling growth parameters seedling length (cm), number of leaves, collar diameter (cm), total biomass (g) alongwith mathematical indices like Vigour Index, Sturdiness quotient, Volume Index, Quality index, root shoot ratio in nursery as discussed in this study.