• 제목/요약/키워드: Chemical structure analysis

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Systematic Analysis of Periodic Variation in Paper Structure

  • Sung, Yong-Joo;Keller, D.Steven
    • 펄프종이기술
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    • 제41권5호
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    • pp.50-58
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    • 2009
  • Periodic variation of local paper structure was evaluated using two-dimensional fast Fourier transform (FFT) and spectral analysis. Since the periodic variation could originate from various sources and have different magnitudes and patterns depending on the origins, a complete analysis of local paper structure properties such as local grammage, local thickness, local apparent density and surface topography was proposed in this study. For a commercial copy paper, the individual periodic patterns for each local structural property were identified by using inverse FFT spectrums of the filtered spectrum. The spectral analysis of newsprint sample provided the period of variation quantitatively, which was useful in comparing the origins of the individual periodic patterns of the local structural properties.

示差熱分析에 依한 Poly 酸의 熱分析의 硏究 (The Study of Thermal Decomposition of Polyacids by Differential Thermal Analysis: Ammonium Paratungstate)

  • 안영필
    • 대한화학회지
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    • 제7권1호
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    • pp.1-5
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    • 1963
  • The thermal decomposition process of ammonium paratungstate $5(NH_4)_2O{\cdot}12WO_3{\cdot}5H_2O$ was analysed by the methods of thermogravimetric analysis, differential thermal analysis, quantitative analysis of the ammonia which is released during heating and X-ray powder diffraction in air and in vacuo. There are several endothermic peaks which indicate release of ammonia and exothermic peaks which indicate crystal growth and oxidation of decomposed prodects in air. After water is driven off the ammonia is released at intervals corresponding to the endothermic peaks. The highest temperature at which ammonia is released is about $420^{\circ}C$ in air and $480^{\circ}C$ in vacuo. In air the crystal structure of paratungstate is conserved up to a temperature of $300^{\circ}C$ at which the remaining ammonia is about 4 mols. At $320^{\circ}C$ the remaining ammonia becomes less than 2 mols and the paratungstate structure changes into the amorphous state. After that ${\gamma}$ oxide is produced and is oxidized to ${\alpha}$ oxide in the temperature range of 400-$500^{\circ}C$ in air. In vacuo however the endothermic peaks and structural changes occur at lower temperatures and the structure of ${\gamma}$ oxide is conserved up to temperatures higher than $500^{\circ}C$.

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A Study on the Structural Controllability of Chemical Processes Based on Relative Order Analysis

  • Lee, Byungwoo;Kim, Yoonsik;Chang, Tae-Suk;Yoon, En-Sup
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1999년도 제14차 학술회의논문집
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    • pp.53-56
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    • 1999
  • The control performance of a chemical process is determined by process structure as well as the performance of controllers. Therefore, the concept of“controllability”should be introduced in the early design stage. Structural information makes controllability assessment possible by giving insights on the pathways of disturbances in the process. In this study, a simple procedure to evaluate controllability is suggested to screen out design alternatives using relative order analysis and structural decomposition. The effectiveness of the proposed method was validated by comparing the results with the case of dynamical simulation.

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