• Bulletin of the Korean Chemical Society
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• v.33 no.6
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• pp.1949-1954
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• 2012

We have developed a novel and eco-friendly synthetic route for the preparation of a two-dimensional layered zinc hydroxide with intercalated nitrate anions. The layered zinc hydroxide nitrate, called 'zinc basic salt', was, in general, successfully synthesized, using an electron beam irradiation technique. The 2-propanol solutions containing hydrated zinc nitrate were directly irradiated with an electron-beam at room temperature, under atmospheric conditions, without stabilizers or base molecules. Under electron beam irradiation, the reactive OH radicals were generated by radiolysis of water molecules in precursor metal salts. After further radiolytic processes, the hydroxyl anions might be formed by the reaction of solvated electrons and the OH radical. Finally, the $Zn_5(OH)_8(NO_3)_2{\cdot}2H_2O$ was precipitated by the reaction of zinc cation and hydroxyl anions. Structure and morphology of obtained compounds were characterized by powder X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and high resolution transmission electron microscopy (HR-TEM). The chemical components of the products were determined by Fourier transform infrared spectroscopy (FT-IR) and elemental analysis (EA). The thermal behavior of products was studied by thermogravimetric (TG) and differential thermal analysis (DTA).

• Bulletin of the Korean Chemical Society
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• v.15 no.7
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• pp.541-545
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• 1994

A series of samples of the ${Ca_xEu_{1-x}FeO_{3-y}$ (x=0.00, 0.25, 0.50, 0.75, and 1.00) system has been prepared at $1,250^{\circ}C$ under an atmospheric air pressure. X-ray diffraction analysis of the solid solution assigns the structure of the compositions of x=0.00, 0.25, 0.50, and 0.75 to the orthoferrite-type orthorhombic system, and that of x=1.00 to the brownmillerite-type orthorhombic one. The mole ratios of $Fe^{4+}$ ion in the solid solutions or ${\tau}$ values were determined by the Mohr's salt analysis and nonstoichiometric chemical formulas of the system were formulated from x, ${\tau}$, and y values. From the result of the Mossbauer spectroscopy, the coordination and magnetic property of the iron ion are discussed. The electrical conductivities are measured as a function of temperature. The activation energy is minimum at the composition of x=0.25. The conduction mechanism can be explained by the hopping of electrons between the mixed valences of $Fe^{3+}\;and\;Fe^{4+}$ ions.

• Advances in concrete construction
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• v.3 no.1
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• pp.71-90
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• 2015

In order to investigate the feasibility and advantage of tuff used as pozzolan in cement-based composite, the representative specimens of tuff were collected, and their chemical compositions, proportion of vitreous phase, mineral species, and rock structure were measured by chemical composition analysis, petrographic analysis, and XRD. Pozzolanic activity strength index of tuff was tested by the ratio of the compression strength of the tuff/cement mortar to that of a control cement mortar. Pozzolanic reaction degree, and the contents of CH and bond water in the tuff/cement paste were determined by selective hydrochloric acid dissolution, and DSC-TG, respectively. The tuffs were demonstrated to be qualified supplementary binding material in cement-based composite according to relevant standards. The tuffs possessed abundant $SiO_2+Al_2O_3$ on chemical composition and plentiful content of amorphous phase on rock texture. The pozzolanic reaction degrees of the tuffs in the tuff/cement pastes were gradually increased with prolongation of curing time. The consistency of CH consumption and pozzolanic reaction degree was revealed. Variation of the pozzolanic reaction degree was enhanced with the bond water content and relationship between them appeared to satisfy an approximating linear law. The fitting linear regression equation can be applied to mutual conversion between pozzolanic reaction degree and bond water content.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.23 no.9
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• pp.1098-1105
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• 1999

A lifted laminar flame structure has been numerically analyzed. The present study employs the physical submodels including the detailed chemical kinetics and the variable transport properties. The validation cases Include a lifted laminar CH4/air flame with a central diluted fuel jet and a surrounding fuel-lean coflow. Numerical results indicate the present approach successfully simulate the detailed structure and mechanism of the triple flame in the lifted laminar methane flame.

• Journal of the Korean Institute of Telematics and Electronics
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• v.27 no.5
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• pp.716-723
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• 1990

Transmission electron microscopy (TEM) and anger electron microscopy(AES) studies of GaAs/AlxGa1-xAs(x=0.58) quantum wells grown by low pressure metalorganic chemical vapor deposition(LP-MOCVD) are carried out. Isolated quantum well structure having the well width as small as 15 \ulcornerand multiquantum well structure, which consisted of 51 alternating layers with each thickness of 10\ulcorner were suscessfully grown. TEM analyses have shown that their interfaces were almost completely coherent without any structural disorder, alloy clustering and crystal defect. AES depth resolution have shown the compositional periodicity of superlattice structure.

• Proceedings of the KIEE Conference
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• 1998.07d
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• pp.1401-1403
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• 1998

The composition, weight decrease, DTA, and surface structure of vinyl insulated wire with thermal treatment conditions have been investigated. The composition of Cu by EDX analysis indicates Cu, Cl, and O lines, and oxidation reaction results from thermal treatment. Thermal treated IV and HIV appeared chemical reaction at $269^{\circ}C$ and $265^{\circ}C$, respectively. SEM of thermal treated Cu at $250^{\circ}C$ disappears an elongation structure, and appears an original structure.

• Journal of Magnetics
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• v.9 no.2
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• pp.65-68
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• 2004

Magnetically soft nanomaterials obtained by controlled crystallisation of metallic glasses are the newest group of materials for inductive components. In particular, research is carried out in the field of alloys for high temperature applications. This kind of materials must meet two basic requirements: good magnetic properties and stability of properties and structure. In the present work the magnetic properties and structure of Fe-Co-Hf-Zr-Cu-B (HIDTPERM-type) alloys were investigated, as well as their stability. Differential thermal analysis, (DTA), X-ray diffractometry (XRD), transmission electron microscopy (TEM), magnetometry (VSM) and quasistatic hysteresis loop recording were used to characterise structure and properties of the alloys investigated. Optimisation against properties and their stability was performed, resulting in formulation of chemical composition of the optimum alloy, as well as its heat treatment.

• Journal of the Korean Magnetic Resonance Society
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• v.20 no.2
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• pp.50-55
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• 2016

Backbone $^1H$, $^{13}C$ and $^{15}N$ resonance assignments are presented for the anticodon binding domain (residues 557-674) of human glycyl-tRNA synthetase (GRS). Role of the anticodon binding domain (ABD) of GRS as an anticancer ligand has recently been reported and its role in other diseases like Charcot-Marie-Tooth (CMT) and polymyositis have increased its interest. NMR assignments were completed using the isotope [$^{13}C/^{15}N$]-enriched protein and chemical shifts based secondary structure analysis with TALOS+ demonstrate similar secondary structure as reported in X-ray structure PDB 2ZT8, except some C-terminal residues. NMR signals from the N-terminal residues 557 to 571 and 590 to 614 showed very weak or no signals exhibiting dynamics or conformational exchange in NMR timescale.

• IE interfaces
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• v.19 no.4
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• pp.281-290
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• 2006

The main objective of this study is to analyze the structure of efficiency of R&D input variables and the attributes of patent information as output of R&D activities in the major manufacturing industries (electric & electronics, machinery, chemical, textile) from the mid-1970s to the late-1990s by the development of "mapping technique". To attain this objective we first have examined the attribute of time-lag which depends on the absolute, and the cumulative values between input and output. And on the basis of this result, we have made an analysis on the impact to extract the main variables affecting patent by industries. Moreover, according to time trend of the impact variables, we have analyzed the structure of R&D efficiency, and of technological progress which will be changed with time by patent information. It has been aimed at constructing technological progress patterns in the Korea industry.

• Journal of the Korean Institute of Navigation
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• v.16 no.1
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• pp.37-64
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• 1992

A study on the changes of the oceanographical environment caused by Mokpo coastal zone development was carried out. Special emphasis was placed on the clarification of the water level changes and coastal current structure and influence of the environmental factors on the coastal area. In order to understand the structure oceangraphical environemnt, such as water temperature, salinity, suspended solids, pH, dissolved oxygen, chemical oxygen demand, biochemical oxygen demand, distribution of bottom sediment, tide and current were measured. To investigated the structure of tide and current for the future development, a numerical analysis was carried out. In certain zones, it was found to be flooding problems near the lowlying commercial area.