• Title/Summary/Keyword: Chemical shrinkage

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SUITABILITY OF SHELLFISHES FOR PROCESSING 3. Suitability of Pacific oyster for processing (패류의 가공적성 3. 굴의 가공적성)

  • LEE Eung-Ho;CHUNG Seung-Yong;KIM Soo-Hyeun;RYU Byeong-Ho;HA Jin-Hwan;OH Hoo-Gyu;SUNG Nak-Ju;YANG Syng-Tack
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.8 no.2
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    • pp.90-100
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    • 1975
  • The estimation of the pre-processing condition of oyster is of great importance for distributors and processors. This study was attempted to establish the basic data for evaluating the processing suitability of oyster, which is the most important shellfish for domestic use and export. The data were analysed by measuring the condition index, chemical composition and heavy metal content of oysters. In order to eliminate the manual work that has to be done on a tightly closed oyster shell and avoid shrinkage in the oyster meat which is attendant on the steaming process, chemical means to open oyster were examined. finding the method of pretreatment of polyphosphate for frozen oysters were attempted to improve the product quality. The prevention of undesirable color change of the canned oyster meat is another problem to solve. The important results are as follows : 1. The ratio of meat volume and meat weight to the holding capacity by shells may be useful as an index to measure the condition index of oysters. 2. As a whole, monthly changes of moisture and fat content in oysters were reversely correlated. Protein content slightly decreased from April and rapidly decreased in July, and again rapidly increased in August but from September to November decreased slightly. In April, the content of glycogen was 4 percent. From this period to September, glycogen was rapidly decreased. From July to September, it was only 0. 7 to 1 percent but increased from October. There were little seasonal changes in pH value. The pH value of oyster meat was 6.0 to 6.2. The crude ash content was slightly decreased from June to August. 3. The range of monthly change of heavy metal content are as follows: Total mercury was 0 to 0.019 ppm, cadmium was 0.026 to 0.053 ppm, copper was 0.111 to 0.594 ppm, and lead_was 0.061 to 0.581 ppm. 4. By the results of condition index, chemical composition and heavy metal content of oysters, the suitable harvest season as raw materials for processing was the end of December to the end of May of next year. 5. The pretreatment of 10 percent polyphosphate in 5 percent salt solution of oyster meat appeared effective to reduce thawing drip during cold storage. 6. The pretreatment of $Na_2EDTA$ and BHA did not show the color prevention effect to the canned oyster meat during storage. 7. Magnesium chloride affected to open the valves of oysters.

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Influence of Mixtures and Curing Conditions on Strength and Microstructure of Reactive Powder Concrete Using Ternary Pozzolanic Materials (배합 및 양생조건이 3성분계 포졸란재를 이용한 RPC의 강도발현 특성에 미치는 영향)

  • Janchivdorj, Khulgadai;Choi, Seung-Hoon;So, Hyoung-Seok;Seo, Ki-Seog;So, Seung-Young
    • Journal of the Korea Concrete Institute
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    • v.25 no.4
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    • pp.457-465
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    • 2013
  • This study discussed the influence of mixtures and curing conditions on the development of strength and microstructure of RPC using ternary pozzolanic materials. Through pilot experiment, various RPC was manufactured by adding single or mixed ternary pozzolanic materials such as silica fume, blast furnace slag and fly ash by mass of cement, up to 0~65%, and cured by using 4 types of method which are water and air-dried curing at $20^{\circ}C$, steam and hot-water curing at $90^{\circ}C$. The results show that the use of ternary pozzolanic materials and a suitable curing method are an effective method for improving development of strength and microstructure of RPC. The unit volume of cement was greatly reduced in RPC with ternary pozzolanic materials and unlike hydration reaction in cement, the pozzolanic reaction noticeably contributes to a reduction in hydration heat and dry shrinkage. A considerable improvement was found in the flexural strength of RPC using ternary pozzolanic materials, and then the utilization of a structural member subjected to bending was expected. The X-ray diffractometer (XRD) analysis and Scanning Electronic Microscope (SEM) revealed that the microstructure of RPC was denser by using the ternary pozzolanic materials than the original RPC containing silica fume only.

Properties of Eco-Construction Material Using Recycled Sewage Sludge Ash (하수슬러지 소각재를 재활용한 친환경 건설 소재의 재료적 특성)

  • Jo, Byung-Wan;Lee, Jea-Ik;Park, Seung-Kook;Lee, Jae-Seung
    • Journal of the Korea Concrete Institute
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    • v.19 no.6
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    • pp.667-676
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    • 2007
  • As the 21st century began, cement and concrete that are representatives of modem building materials became a major factor in global warming, air pollution and environmental pollution. Also, the problems that are generated while pursuing high performance and high strength became social issues. Therefore, it has become urgent to prepare counter plans. This study has aimed at the recycling of sewage sludge ash and developing it as a new concept in building material which serves the environmental considerations for long-lasting developmental purpose. Also, the study aimed to find a substitute for scarce natural resources and to secure high techniques for waste recycling. The purpose of this study was also to solve fundamentally secondary environmental pollution. The results revealed that the chemical components of sewage sludge ash are mainly $SiO_2\;and\;Al_2O_3$ which are similar to the components of pozzolan. Also, it was identified that sewage sludge ash can be utilized as a hardened specimen with an alkali activated pozzolan reaction. Considering the possibility of appropriate strength development and the advantage of drying shrinkage, compared with that of cement, it was believed that sewage sludge ash can demonstrate a function as a substitute for cement given.

Development of High Performance Curing Agent and Effective Dispersion Method of Nanomaterials (고성능 피막양생제 개발 및 나노물질의 분산방안 평가)

  • Son, Ho-Jung;Yoo, Byung-Hyun;Lee, Dong-Gyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.12
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    • pp.230-236
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    • 2019
  • Recently, issues related to the quality of concrete have continuously resulted in surface quality problems, such as the exfoliation of concrete surfaces due to the cost reduction of cement and poor quality fine aggregate, scaling of surfaces caused by laitance, and plastic shrinkage cracks. Prompted by social issues, the application of a photo catalyst to road structures is being attempted to solve the environmental problems caused by fine dust and automobile exhaust. In this study, chemical admixtures were developed to improve the surface quality of concrete and to apply and distribute titanium dioxide in nanoscale sizes to provide basic data for the development of a photocatalyst-curing agent. As a result of the experiment, silicon and silane were reviewed as a raw material as a curing agent to develop a high performance curing agent with better film performance than conventional curing agents because they could form a film quickly on a fresh concrete surface. The distributed stability of the ultrasonic disperser showed the best performance through an outdoor test for four weeks to review the dispersion measures for the application of nanomaterials.

Characteristics of Concrete Polymer Composite Using Atomizing Reduction Steel Slag (I) (Use of PMMA as a Shrinkage Reducing Agent) (아토마이징 제강 환원슬래그를 사용한 폴리머 콘크리트 복합재료의 특성 (I) (PMMA 수축저감재를 사용))

  • Hwang, Eui Hwan;Kim, Jin Man
    • Applied Chemistry for Engineering
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    • v.25 no.2
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    • pp.181-187
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    • 2014
  • In order to use the spherical atomizing reduction steel slag (ladle furnace slag, LFS) instead of the fine aggregate of polymer concrete composites, various specimens were prepared with various replacement ratios of atomizing reduction steel slag and the addition ratios of polymer binder. Physical properties of these specimens were investigated through the absorption test, the compressive strength test, the flexural strength test, the hot water resistance test, the pore analysis and the micro-structure using scanning electron microscope. Results showed that the compressive strength and flexural strength of specimens with 7.5% of polymer binders increased with the increase of replacement ratios of atomizing reduction steel slag, but those of the specimens with 8.0% or more of polymer binders showed a maximum strength at a certain replacement ratio due to the material segregation causing the increase of fluidity. By hot water resistance tests, the compressive strength, flexural strength, average pore diameter, and bulk density decreased but the total pore volume and pore diameter increased. It was concluded that the amount of polymer binders could be reduced by maximum 23.8%, because the workability of the polymer concrete was remarkably improved by using the atomizing reduction steel slag instead of fine aggregate. However, since the use of atomizing reduction steel slag decreased the resistance of the polymer concrete to hot water, further studies are required.

Characteristics of Concrete Polymer Composite Using Atomizing Reduction Steel Slag as an Aggregate (II) (Use of Polystyrene as a Shrinkage Reducing Agent) (아토마이징 제강 환원슬래그를 골재로 사용한 폴리머 콘크리트 복합재료의 특성(II) (폴리스티렌 수축저감재 사용))

  • Hwang, Eui-Hwan;Kim, Jin-Man
    • Applied Chemistry for Engineering
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    • v.25 no.4
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    • pp.380-385
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    • 2014
  • Spherical atomizing reduction steel slag was prepared by atomizing technology using reduction steel slag (ladle furnace slag, LFS) generated from steel industry. In order to develop the mass-recycling technology of atomizing reduction steel slag, polymer concrete composite was prepared using spherical atomizing reduction steel slag instead of fine aggregate (river sand) and coarse aggregate (crushed aggregate), depending on the grain size. Different polymer concrete specimens were prepared with the various proportions of polymer binder and replacement ratios of atomizing reduction steel slag in order to investigate the characteristics of polymer concrete composite. Results showed that compressive strengths of polymer concrete specimens decreased with the increase of replacement ratios of atomizing reduction steel slag, but flexural strengths of the specimens showed a maximum strength at the 50% of replacement ratios of atomizing reduction steel slag. It was concluded that addition ratio of polymer binder, which affect greatly on the prime cost of production of polymer concrete, could be reduced by maximum 18.2 vol% because the workability of the polymer concrete was remarkably improved by using the atomizing reduction steel slag. However, further study is required because the mechanical strength of the specimen using atomizing reduction steel slag was greatly reduced in hot water resistance test.

Optical properties of $Ag_2CdSnSe_4$ and $Ag_2CdSnSe_4:CO^{2+}$ single crystals ($Ag_2CdSnSe_4$$Ag_2CdSnSe_4:Co^{+2}$단결정의 광학적 특성)

  • 이충일
    • Journal of the Korean Vacuum Society
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    • v.10 no.1
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    • pp.16-21
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    • 2001
  • Optical properties of $Ag_2CdSnSe_4$ and $Ag_2CdSnSe_4:Co^{+2}$ quaternary semiconductor single crystals grown by the chemical transport reaction method were investigated. The analysis of the X - ray powder diffraction measurements showed that these crystals have a wurtzite structure with lattice constants a = 4.357 $\AA$, c = 7.380 $\AA$, for $Ag_2CdSnSe_4$ and a = 4.885 $\AA$, c = 7.374 $\AA$, for $Ag_2CdSnSe_4:CO^{2+}$. The direct band gap at 298K, obtained from the optical absorption measurement, is found to be 1.21 eV for $Ag_2CdSnSe_4$ and 1.02 eV for $Ag_2CdSnSe_4:CO^{2+}$. The shrinkage of the band gap due to Co-doping is observed and is about 190 meV, We observed four absorption bands of $Co^{2+}$ ions in two near infrared regions of optical absorption spectra of $Ag_2CdSnSe_4$:$Co^{+2}$. These absorption bands were assigned as due to electronic transitions between the split energy levels of $Co^{2+}$ ions in $T_d$ crystal field under spin-orbit interactions.

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Development for Penetrative Performance Improving Agent to In Prevent Deterioration of Concrete Structures (콘크리트 구조물의 내구성능 저하를 방지하는 침투형 성능개선제 개발)

  • Ryu Gum-Sung;Koh Kyoung-Taek;Kim Sung-Wook;Kim Do-Gyeum
    • Journal of the Korea Concrete Institute
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    • v.17 no.4 s.88
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    • pp.489-498
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    • 2005
  • Recently, the deterioration of concrete structures have been increased by the damage from salt, carbonization, freezing & thawing and the others. Therefore, the measures for the deterioration of concretes have been taken. Among them, it has been often used that surface treatment which cut off the deterioration factors of durability by protecting the surface of concrete. The water proof and repair materials for concrete mainly use organic materials such as epoxy, these materials excel in intial bonding force and resistance to chemical agents. But they cause difference in the modulus of elasticity and the rate of shrinkage and expansion of concrete, and thus result in such problems as scaling and spatting in the progress of time. Therefore in this study it develop the performance Improving agent of concrete surface that can block a deterioration cause such as $CO_2$ gas, chloride ion and water from the outside and enhance waterproofing ability by reinforcing the concrete surface when applying it to concrete structures.

A Study on Properties of Domestic Fly Ash and Utilization as an Insulation material (국산 Fly Ash의 특성 및 단열재로의 이용에 관한 연구)

  • 박금철;임태영
    • Journal of the Korean Ceramic Society
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    • v.20 no.2
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    • pp.135-146
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    • 1983
  • This study is to investigate the properties of domestic fly ash for utilization as data in regard to fly ash which is by-product of domestic coal powder plants and the possibility of utilization as insulation material of domestic fly ash. Composition refractoriness size distribution density contents of hollow particles and crystalline phase were examined as the properties of domestic fly ash. As to the fired test pieces of fly ash by itself that varied contents of hollow particles with four kinds and of the fly ash-clay-saw dust system linear shrinkage bulk density app. porosity compressive strength thermal conductivity and structures were investigated for the possibility of utilization as an insulation material. The results are as follows : 1. The properties of the fly ash I) The constituent particle of the fly ash is spherical and it contains not a few hollow particles (floats by water 0.30-0.50 floats by $ZnCl_2$ aq.(SpG=1.71) 6.97-16.72%). ii) The chemical compositions of fly ash are $SiO_243.9-54.1%$ , $Al_2O_321.0-30.7%$ Ig loss is 7.4-24.1% and the principal of Ig loss is unburned carbon. iii) Fly ash was not suitable to use for mortar and concrete mixture because Ig. loss value is higher than 5% 2. Utilization as insulation material I) The test pieces of original fly ash floats by water floats by ZnCl2 aq(SpG=1.71) p, p t by ZnCl2 aq.(SpG=1.71) that were fired at 110$0^{\circ}C$ represented 0.11-0.18 kcal/mh$^{\circ}$ C as thermal conductivity value. ii) The test pieces which (76.5-85.5) wt% fly ash-(8.5, 9.5) wt% clay-(5.0-15.0) wt% saw dust system(68.0-72.0) wt% fly ash -(17.0-18.0)wt% clay-(10.0-15.0) wt% saw dust system and 59.5 wt% fly ash-25.5 wt% clay-15.0wt% saw dust system were fired at 110$0^{\circ}C$ the thermal conductivity was less than 0.1Kcal/mh$^{\circ}$ C. iii) In view of thermal conductivity and economic aspect insulation materials which added saw dust as blowing agent and clay as inorganic binder are better than that of fly ash as it is or separated hollow fly ash particles. iv) When the saw dust contents increased in the (59.5-90.0) wt% saw dust system and when amount of clay de-creased and firing temperature decreased under the condition of equal addition of saw dust app. porosity increased but bulk density compressive strength and thermal conductivity decreased.

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Durability Characteristics in Concrete with Ternary Blended Concrete and Low Fineness GGBFS (삼성분계 콘크리트와 저분말도 슬래그를 혼입한 콘크리트의 내구 특성)

  • Kim, Tae-Hoon;Jang, Seung-Yup;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.287-294
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    • 2019
  • GGBFS(Ground Granulated Blast Furnace Slag) has been widely used in concrete for its excellent resistance chloride and chemical attack, however cracks due to hydration heat and dry shrinkage are reported. In many International Standards, GGBFS with low fineness of 3,000 grade is classified for wide commercialization and crack control. In this paper, the mechanical and durability performance of concrete were investigated through two mix proportions; One (BS) has 50% of w/b(water to binder) ratio and 60% replacement ratio with low-fineness GGBFS, and the other (TS) has 50% of w/b and 60% replacement ratio with 4000 grade and FA (Fly Ash). The strength difference between TS and BS concrete was not great from 3 day to 91 day of age, and BS showed excellent performance for chloride diffusion and carbonation resistance. Two mixtures also indicate a high durability index (more than 90.0) for freezing-thawing since they contain sufficient air content. Through improvement of strength in low fineness GGBFS concrete at early age, mass concrete with low hydration heat and high durability can be manufactured.