• Title/Summary/Keyword: Chemical pulp

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Reinforcing Efficiencies of Two Different Cellulose Nanocrystals in Polyvinyl Alcohol-Based Nanocomposites

  • Park, Byung-Dae;Causin, Valerio
    • Current Research on Agriculture and Life Sciences
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    • v.31 no.4
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    • pp.250-255
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    • 2013
  • As a renewable nanomaterial, cellulose nanocrystal (CNC) isolated from wood grants excellent mechanical properties in developing high performance nanocomposites. This study was undertaken to compare the reinforcing efficiency of two different CNCs, i.e., cellulose nanowhiskers (CNWs) and cellulose nanofibrils (CNFs) from hardwood bleached kraft pulp (HW-BKP) as reinforcing agent in polyvinyl alcohol (PVA)-based nanocomposite. The CNWs were isolated by sulfuric acid hydrolysis while the CNFs were isolated by 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO)-mediated oxidation. Based on measurements using transmission electron microscopy, the individual CNWs were about $6.96{\pm}0.87nm$ wide and $178{\pm}55nm$ long, while CNFs were $7.07{\pm}0.99nm$ wide. The incorporation of CNWs and CNFs into the PVA matrix at 5% and 1% levels, respectively, resulted in the maximum tensile strength, indicating different efficiencies of these CNCs in the nanocomposites. Therefore, these results suggest a relationship between the reinforcing potential of CNCs and their physical characteristics, such as their morphology, dimensions, and aspect ratio.

First Description of Wood Decay Fungi, Hypoxylon moriforme, in Korea

  • Lee, Yang-Soo
    • Applied Microscopy
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    • v.29 no.3
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    • pp.275-280
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    • 1999
  • The genus of Hypoxylon, well known wood degrading fungi, is a member of the Xylariales, which has woody to carbonaceous, brown to dark brown stromata. Hypoxylon moriforme, which was isolated from heavily decayed hardwood, is fairly described by electron microscope. The isolation of H. moriforme will be the first record and the first description in Korea. The species collected, having small size of ascospores $7.5\sim9.0\times2.5\sim4.0{\mu}m$ and asci $75\sim130\times3\sim5{\mu}m$, are taxonomically compared with H. truncatum, which is well known as a popular species in Northeast Asia. And H. bovei and H. annulatum, which are the tropic to subtropic species and also compared with other temperate species of H. moriforme.

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Cushioning Performance Analysis of Cushioning Materials for Vibration and Impact Condition (진동 및 충격조건에 대한 완충재별 완충성능 분석)

  • Oh, Jae-Young
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.15 no.1
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    • pp.1-6
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    • 2009
  • The impact absorption materials made of synthetic organic chemical product like Expanded Polystyrene(EPS), Expanded Polyethylene(EPE), Expanded Polyurethane(EPU), etc. have been used with general packaging material until the present. But nowadays, the use of these materials is intended to be decreased and to be recycled in connection with environmental pollution. In addition, it has been tried to substitute these materials with non-pollution materials(natural materials) like pulp mould, paper protectors, etc. At the same time, it is required to evaluate and analyze these cushioning materials for cushioning properties based on impact and vibration, in order to make an efficiency on the overall packaging system because they are generally being used by a random choice regardless of the properties of contents and cushioning materials. Therefore, this study provides analyzed data on cushioning properties of various cushioning materials against impact and vibration, and is intended to provide more efficient model for packaging system by minimizing their using amount through choosing an optimal cushioning material as well as intended to lead to the use of nonpollution materials in case these cushioning materials have same cushioning properties.

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Utilization of Pine Bark(III) - Characterization of Spent Liquor Obtained from Bisulfite Cooking of Pine Bark - (소나무 수피(樹皮)의 총합적(總合적) 이용(利用)(III) - 수피(樹皮) 중아황산염(重亞黃酸鹽) 증해폐액(蒸解廢液)의 특성(特性) -)

  • Mun, Sung-Phil
    • Journal of the Korean Wood Science and Technology
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    • v.22 no.2
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    • pp.54-60
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    • 1994
  • The pine bark from mechanical pulp industry was cooked with bisulfite liquor, and the chemical and physical properties of the spent liquor after cooking for 90 minutes, which allowed partial defibration were determined. Lignosulfonate or lignin-related materials in the spent liquor have a molecular weight of approximately 3,000, which is lower than that of commercial lignosulfonate (C-LS) prepared from wood. The sulfonic equivalent weight calculated by colloid titration was 307 for C-LS, 238~239 for spent liquor. The contents of lignosulfonic acid and phenolic hydroxyl groups on $C_9$ unit of lignin in the spent liquor were 0.98~0.99, and 1.51~1.66, respectively. These values were remarkably higher than those of C-LS. Especially the content of phenolic hydroxyl group was almost twice that of C-LS. The viscosity of spent liquor after freeze drying was very low compared to C-LS. The dispersing ability of spent liquor was almost equivalent to or more than that of C-LS.

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Causality Tests of Korean Firm's FDI and Exports toward Vietnam (한국 기업의 대(對)베트남 FDI와 수출 간 인과성 검정)

  • Jihoon Kang
    • Korea Trade Review
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    • v.45 no.4
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    • pp.107-123
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    • 2020
  • The purpose of this paper is to analyze the Granger Causality relations between Korean FDI and exports in Vietnam using time-series from 2005 to 2019. Using 15-industry semi-annual data of Korean FDI and exports toward Vietnam, the Granger Causality Tests were conducted. Var and VEC models were decided after unit-root and cointegration tests of variables. Findings and implications of the empirical tests are as follows. First, unexpectedly FDI did not Grange-cause exports only in one direction. In two industries, food & beverage and medical & chemical products, there were Granger causality relations in both directions. In eight industries including print, publishig, pulp & paper, exports did Grange-cause FDI. In the rest of five industries including automative & trailer industry, there were no Granger Causality relation in both directions. Second, we presume that the both direction-causality relations are desirable phenomenon for Korea. Because Korean FDI and exports are increasing at the same time. On the other hand, substitution relationship between Korea's exports and FDI occur in the industry that exports did Grange-cause FDI. Finally, more in-depth researches considering Vietnam's consumer demand and the oriented characteristics of FDI are needed. The results of this research will contribute to understand structural patterns of FDI and exports in Vietnam and to make investment and export decisions.

A New Sampling and SEC Method for Analysis of Underivatized Cellulose (셀룰로스의 분석을 위한 새로운 시료처리 및 크기배제크로마토그래피)

  • Lee, Seung Ho;Park, Hee Young
    • Journal of the Korean Chemical Society
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    • v.42 no.2
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    • pp.190-196
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    • 1998
  • A new sampling and size exclusion chromatography (SEC) method for the analysis of underivatized cellulose are established. In this method, cellulose materials are first dissolved in N-methylmorpholine N-oxide (NMMO) and diluted by adding dimethyl sulfoxide (DMSO) to make the sample solutions of about 0.1% in 50/50 NMMO/DMSO (w/w). Sample solutions are analyzed using a glucose-treated divinylbenzene (DVB) SEC column and DMSO containing 0.05M LiBr and 2.5 blank as the eluant. The flow rate was constant at 1 mL/min and the whole SEC system including the column was heated at $80^{\circ}C$ to reduce the viscosity of DMSO. Addition of 0.05 M LiBr eliminated SEC baseline drifting, and addition of 2.5 blank seems to reduce the interaction between the sample and the column packing. SEC molecular weights were determined using a calibration curve constructed from a series of narrow pullulan standards, and they were used to measure the degree of degradation during two different pulp-to-sponge processings.

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Electrokinetic Property and Flotation Characteristics of Scheelite (灰重石의 水溶液中에 있어서의 界面現象과 浮選特性에 關한 硏究)

  • Hyung Sup Choi;Kook Nam Han
    • Journal of the Korean Chemical Society
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    • v.7 no.1
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    • pp.17-24
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    • 1963
  • The fundamental investigations of surface properties of scheelite were made by electrophoretic mobility adsorption and contact angle measurements, and results have been correlated with its floatability obtained by Hallimond tube flotation test. The role of the interfacial electrical condition on the adsorption of collectors on mineral surfaces is discussed with the flotation of scheelite. From electrokinetic measurements made on scheelite, $Ca^{++}$ and $WO_4^{--}$ are identified to act as potential-determining ions, thus controlling the surface properties on this mineral. Therefore, at the fixed pH, the scheelite surface become to be less negatively charged with increasing $Ca^{++}$ concentration and more negatively charged with increasing $WO_4^{--}$ concentration in the pulp. Adsorption of collectors then depends strongly on the concentration of $Ca^{++}$ or $WO_4^{--}$ in the solution; anionic collectors are adsorbed on less negatively charged surfaces and cationic collectors on more negatively charged surfaces, which in turn defines the effective flotation range with respective collectors for this mineral.

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An Analysis on the efficiency of Small Manufacturing Industry - before and after IMF - (IMF전후의 중소제조업의 경영효율성 분석)

  • Lee, Cham-Soo
    • Korean Business Review
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    • v.14
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    • pp.169-187
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    • 2001
  • In the recent efficiency study became accomplished generally a listed company, the efficiency study of small manufacturing industry is deficient. The purpose of this study analysis efficiency of small manufacturing industry by using the DEA model. DEA model is non-financial approach method to measure relative efficiency by input factors and output. The panel data from 1996 to 1999 are used for the analysis. The relative mean-efficiency can be summarized as follows. The wholesale trade and commission trade manufacturing industry 68.99%, communication equipment manufacturing industry 60.58%, food products and beverages manufacturing industry 91.05%, motor vehicles, trailers and semitrailers manufacturing industry 85.80%, basic metals manufacturing industry 88.96%, pulp, paper and paper products manufacturing industry 96.53%, chemical and chemical products manufacturing industry appeared with 78.67%. The results is expected to provide the empirical evidence useful to enhancing the competitiveness of manufacturing industry in korea.

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On Possible Application of Microorganism for Chemical Pulping (화학(化學)펄프 제조(製造)에 미생물(微生物)의 응용(應用) 가능성(可能性))

  • Lee, Seon-Ho;Yoon, Byong-Ho;Lee, Won-Yong
    • Journal of Forest and Environmental Science
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    • v.13 no.1
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    • pp.143-152
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    • 1997
  • The decayed wood by Fomes pini (Thore) Lloyd required a smaller H factor than the sound wood for pulping to permanganate number 20. The H factors for the decayed wood pulping by the kraft and soda processes were reduced by 15% and 17%, respectively, in the presence of 1% anthraquinone. The wood components degraded by fungi are normally more readily solubilized in alkali than the corresponding components in sound wood. The nonphenolic ${\beta}$-O-4 type lignin model compound, veratrylglycerol-${\beta}$-guaiacyl ether(I), and phenolic model compound, syringylglycerol-${\beta}$-syringyl ether(III), were degraded by the white-rot fungi to yield ${\alpha}$-guaiacoxy-${\beta}$-hydroxypropioveratrone(II) from the former and ${\alpha}$-syringyloxy-${\beta}$-hydroxypropiosyringone(IV) from the latter. Structures of the degradation products indicated that C ${\alpha}$-oxidation could occur with white-rot fungi. It has been shown that the alkaline cleavage of ${\beta}$-aryl ether bonds in the lignin units is accelerated by the presence of ${\alpha}$-carbonyl groups.

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Physico-chemical Characteristics and Utilization of Raw Materials for Mushroom Substrates (버섯 병재배 배지재료의 이화학성과 활용)

  • Cheong, Jong-Chun;Jhune, Chang-Sung;Lee, Chan-Jung;Oh, Jin-A
    • The Korean Journal of Mycology
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    • v.38 no.2
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    • pp.136-141
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    • 2010
  • To provide a basic information on the chemical concentrations of different raw materials used in mushroom cultivation, the raw materials were collected from 13 Flammulina velutipes, 14 Pleurotus eryngii, and 8 P. ostreatus farms and analyzed to calculate moisture contents, pH, total carbon(T-C), total nitrate(T-N), total phosphate(T-P) and 13 different cations. In our results, the C : N ratios of cotton seed meal, beet pulp, and corn-cob were 6~17, 12~29 and 56~127, respectively. Depending on the companies which process these materials, the range of C:N ratio of soybean curd residue was approximately either 8~9 or 14~17 with wider range of C : N ratio of the raw materials imported from other countries without the detection of heavy metals. In this study, the formula was provided to calculate the composition of mixed media for mushroom cultivation based on the ingredient chart of different raw materials.