• Title/Summary/Keyword: Chemical properties

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Properties of Precursor Pitch Derived from Petroleum Residue

  • Yu, Hae-Il;Lee, Gyu-Dong;Gwon, Yeong-Bae
    • 한국기계연구소 소보
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    • s.15
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    • pp.37-46
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    • 1985
  • Properties of Precursor pitch derived from petroleum residue were studied physical and chemical analysis method for investigation of production of pitch fiber. For preparing of those precursor pitches it was carried out a temperature and time variation experiment i reactor. It was demonstrated the precursor pitch prepared in this study to have a similar properties to Ashland precursor pitch capable of bulk mesophase formation from the results of the basic analysis, that is, molecular weight distribution, coking yield, carbon content, chemical composition, etc.

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Experimental Study of Bond Properties Using Coated Bars (도막재료에 따른 철근의 부착성능에 관한 실험적 고찰)

  • 김영진
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.211-216
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    • 2003
  • Coated bars are protecting reinforcing bars from corrosion and enhancing durabilities of reinforced concrete structures are tested to evaluate corrosion protection properties. Tests are performed based on the relevant standards of ACI and ASTM, such as chemical resistance, salt water spray, salt crack test and chloride permeability test with the main variable of the coating thickness. Three type materials are tested by Polyethylene, epoxy and bare bar. Test results show good chemical protection property and chloride permeability. Polyethylene coated bar is good coating material than any other materials.

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A Simple Approach to the Ionic-covalent Bond Based on the Electronegativity and Acid Strength of Cations. Part Two:Application to the Description of the Electronic Properties of Oxides

  • Josik Portier;Guy Campet
    • Journal of the Korean Chemical Society
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    • v.41 no.8
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    • pp.437-441
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    • 1997
  • The acid strngth of cations, determined with ICP (Ionic Covalent Parameter): ICP=log(P)-1.38x+2.07 where P is the polarizing power and X its electronegativity expresses the competition between the covalent and ionic forces. This concept, together with electronegativity, is used to describe the properties of oxides with various electronic properties (insulators, metals, degenerate semiconductors, superconductors).

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Sol-gel Synthesis and Properties of Phosphate Ceramics

  • Lee, Burtrand I.;Cao, Zhicheng;Samuels, Willam D.;Exarhos, Gregory J.
    • The Korean Journal of Ceramics
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    • v.6 no.4
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    • pp.390-395
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    • 2000
  • Silicon, titanium, zirconium phosphates were synthesized by starting with appropriate chemical precursors in a solution. The synthetic procedure, chemical and physical structures were examined by FT-IR, liquid and solid state NMR, TGA, SEM, XRD, etc. The phosphates were examined for thermal and electrical properties. Advantages of the synthesis technique and the data on unique structures and thermal properties are reported.

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Molecular Dynamics Simulation on thermodynamic and Structural Properties of Liquid Hydrocarbons : Normal Alkanes

  • Im, Won-Pil;Won, Young-Do
    • Bulletin of the Korean Chemical Society
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    • v.15 no.10
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    • pp.852-856
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    • 1994
  • A series of aliphatic hydrocarbons, methane to hexane in the liquid state, are modeled with the molecular mechanical potential parameters treating all hydrogen degrees of freedom explicitly. Thermodynamic properties (heat capacities and heats of vaporization) are calculated from relatively short (20ps) molecular dynamics trajectories. The liquid state structures are also examined through various radial distribution functions. Molecular dynamics simulations reproduce experimentally measured properties within a few percent errors, thus indicate that the present set of all-hydrogen parameters is suitable for simulating macromolecular systems in bulk.

Effect of the non-Coulombic Long-Range Forces and the Next Nearest Neighbor Interactions on the Lattice Properties of Alkali Halide Crystals

  • Shin, Yeon-Kyun;Kim, Yung-Sik
    • Bulletin of the Korean Chemical Society
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    • v.7 no.3
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    • pp.194-196
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    • 1986
  • The effect of the non-Coulombic long-range forces and the next nearest neighbor interactions on the lattice properties of alkali halide crystals is calculated using the Electron Gas model and Electron Gas Drude model. It is found that these often neglected interactions make changes in the lattice properties that are indeed small, but by no means negligible.

Acidity Effect on the Catalytic Properties for Phenol Isopropylation

  • Yu, Jeong Hwan;Lee, Cheol Wi;Wang, Bo;Park, Sang On
    • Bulletin of the Korean Chemical Society
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    • v.22 no.3
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    • pp.263-266
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    • 2001
  • Isopropylation of phenol with 2-propanol has been carried out over Na-exchanged ZSM-5 zeolites to determine the effect of catalyst acidity on phenol conversion and product selectivity. The acid type and strength of the catalyst such as Lewis, weak and strong Bronsted acid sites are measured by pyridine adsorbed XPS and the catalytic properties are interpreted in terms of the acid properties. The active site and mechanism for the reaction are suggested based on evidence of study from the reactant adsorbed FT-IR.

Synthesis and Properties of Ionic Liquids:Imidazolium Tetrafluoroborates with Unsaturated Side Chains

  • Min, Gwan-Hong;Yim, Tae-eun;Lee, Hyun-Yeong;Huh, Dal-Ho;Lee, Eun-joo;Mun, Jun-young;Oh, Seung M.;Kim, Young-Gyu
    • Bulletin of the Korean Chemical Society
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    • v.27 no.6
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    • pp.847-852
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    • 2006
  • Imidazolium tetrafluoroborate ionic liquids having unsaturated aliphatic side chains were synthesized and characterized. Most of them are liquid at room temperature and all of them are stable up to $300{^{\circ}C}$. Some imidazolium tetrafluoroborates with an allylic side chain showed much wider voltage windows on the platinum electrode, better conductivities, and lower viscosities compared with the corresponding ionic liquids containing the saturated side chains.

Synthesis and Physicochemical Properties of Ionic Liquids: 1-Alkenyl-2,3-dimethylimidazolium Tetrafluoroborates

  • Min, Gwan-Hong;Yim, Tae-Eun;Lee, Hyun-Yeong;Kim, Hyo-Jin;Mun, Jun-Young;Kim, Sang-Mi;Oh, Seung-M.;Kim, Young-Gyu
    • Bulletin of the Korean Chemical Society
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    • v.28 no.9
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    • pp.1562-1566
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    • 2007
  • 1-Alkenyl-2,3-dimethylimidazolium tetrafluoroborate ionic liquids having an olefinic substituent were synthesized and characterized. Among them, [AMMIm]BF4 with an allyl group showed lower viscosity, higher ionic conductivity, and a wider electrochemical window compared with its analogue having a saturated alkyl substituent. An EDLC with [AMMIm]BF4 showed better performance than that with [PMMIm]BF4, too.