Sol-gel Synthesis and Properties of Phosphate Ceramics

  • Lee, Burtrand I. (Clemson University, Olin Hall Clemson) ;
  • Cao, Zhicheng (Clemson University, Olin Hall Clemson) ;
  • Samuels, Willam D. (Pacific Northwest National Laboratory Richland) ;
  • Exarhos, Gregory J. (Pacific Northwest National Laboratory Richland)
  • Published : 2000.12.01

Abstract

Silicon, titanium, zirconium phosphates were synthesized by starting with appropriate chemical precursors in a solution. The synthetic procedure, chemical and physical structures were examined by FT-IR, liquid and solid state NMR, TGA, SEM, XRD, etc. The phosphates were examined for thermal and electrical properties. Advantages of the synthesis technique and the data on unique structures and thermal properties are reported.

Keywords

References

  1. J. Mater.Res. v.11 B.I.Lee;W.D.Samuels;L.Wang;G.J.Exarbos;
  2. J.Non-Cryst.Solids v.147;148 J.Livage;P.Barboux;M.T.Vandenborre;C.Schmutz;F.Taulelle
  3. J.Non-Cryst.Solids v.143 S.P.Szu;L.C.Klein:M.Greeblatt
  4. J.Mater.Res. v.11 Y.Guo;P.Woznick;A.Barkatt
  5. J.Sol-Gel Sci. Tech v.4 J.c.Schrotter;A.Cardenas;M.Smaihi;N.Hovnanian
  6. J.Mater.Res. v.6 S.Prabakar;K.J.Rao;C.N.R.Rao
  7. J.Non-Cryst.Solids v.105 S.G.Kosinski;D.M.Krol;T.M.Duncan;D.C.Douglass;J.B.MaChesney;J.R.Simpson
  8. J.Appl. Phys. v.58 D.C.Douglass;T.M.Duncan;K.L.Walker;R.Csencsits
  9. J.Non-Cryst. Solids v.94 E.A.Hayri;M.Greenblatt
  10. J.Mater.Sci.Lett. v.4 J.P.Boilot;P.Colomban
  11. J.Mater.Res v.13 Z.Cao;B.I.Lee;W.D.Samuels;L.-Q Wang;G.J.Exarhos
  12. Inorganic Ion Exchange Materials A.Clearfield
  13. J.Inorg.Nucl. Chem v.40 A. Clearfield;T.N.Frianeza
  14. Bulletin of the Chemical Society of Japan v.52 no.10 Y.Yazawa;T.Eguchi;K.Takaguchi;I.Tomita
  15. American Ceram. Soc., Annual Meeting Z.Reitmier;B.I.Lee;Z.Cao;W.D.Samuels
  16. Nature v.28 T.L.Weeding;B.H.W.S.de Jong;W.S.Veeman;B.G.Aitken
  17. J.Mater.Sci. v.29 Y.S.Kim;R.E.Tressler
  18. Bull.Chem.Soc.Japan. v.56 E.Kobayashi;S.Yamazaki
  19. Inorganic Phosphate Materials S.Yamanaka;T.Kanazawa(ed.)
  20. J.Mater.Res. v.11 A.I.Botun;L.Bortun;A.Clearfield;M.A.Villa-Garcia;J.R.Garcia;J.Rdriguez
  21. J. Mater. Chem v.4 S.Komarneni;Q.Li;R.Roy
  22. J.Non-Cryst.Solids v.162 H.Hosono;K.Imai;Y.Abe
  23. Am. Ceram. Soc. v.28 in Ceramic Trans. Solid-State Optical Materials M.L.Elder;Y.T.Hayden;J.H.Campbell;S.A.Payne;G.D.Wilke;A.J.Bruce(ed.);B.V.Hiremath(ed.)