• Title/Summary/Keyword: Chemical instability

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Gasification of Surface Carbon Contaminant during Discharge in Plasma Display Panel (PDP)

  • Soh, Hyun;Cho, Sung-Ho;Kim, Young-Chai
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.795-798
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    • 2003
  • Inside of working PDP, there exist highly reactive conditions in the gap between two glass panels. MgO layer and phosphor have been investigated as a function of discharge and temperature. A drastic reduction in carbon impurity was observed on the surfaces after discharging and heat treatment. Carbon composition on the MgO and phosphor is a dominant factor for their instability

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Combustion Stability Characteristics of the Model Chamber with Various Configurations of Triplet Impinging-Jet Injectors

  • Sohn Chae-Hoon;Seol Woo-Seok;Shibanov Alexander A.
    • Journal of Mechanical Science and Technology
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    • v.20 no.6
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    • pp.874-881
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    • 2006
  • Combustion stability characteristics in actual full-scale combustion chamber of a rocket engine are investigated by experimental tests with the model (sub-scale) chamber. The present hot-fire tests adopt the combustion chamber with three configurations of triplet impinging-jet injectors such as F-O-O-F, F-O-F, and O-F-O configurations. Combustion stability bound-aries are obtained and presented by the parameters of combustion-chamber pressure and mixture (oxidizer/fuel) ratio. From the experimental tests, two instability regions are observed and the pressure oscillations have the similar patterns irrespective of injector configuration. But, the O-F-O injector configuration shows broader upper-instability region than the other configurations. To verify the instability mechanism for the lower and upper instability regions, air-purge acoustic test is conducted and the photograph or the flames is taken. As a result, it is found that the pressure oscillations in the two regions can be characterized by the first impinging point of hydraulic jets and pre-blowout combustion, respectively.

Rheological behavior and wall slip of dilute and semidilute CPyCl/NaSal surfactant solutions

  • Kibum Sung;Han, Min-Soo;Kim, Chongyoup
    • Korea-Australia Rheology Journal
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    • v.15 no.3
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    • pp.151-156
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    • 2003
  • In this research, experimental studies were performed to examine the rheological behavior of equimolar solutions of cetylpyridinium chloride (CPyCl) and sodium salicylate (NaSal) solutions with concentration. The surfactant solutions were prepared by dissolving 2 mM/2 mM - 80 mM/80 mM of surfactant/counterion in double-distilled water. It has been observed that the zero shear viscosity shows abrupt changes at two critical values of C^*$ and C^{**}$. These changes are caused by the switching of relaxation mechanism with concentration of CPyCl/NaSal solutions at those concentrations. The wall slip velocities of dilute and semidilute CPyCl/NaSal solutions show a dramatic increase with shear rate where the shear viscosity exhibits shear thickening behavior for dilute solutions and shear thinning behavior for semi-dilute solutions, respectively. Considering that the dramatic increase in wall slip velocity should be related to the formation of shear-induced structure (SIS) in the surfactant solution, the shear thickening behavior of semi-dilute solutions is caused by elastic instability unlike the case of dilute solutions.

Stability analysis of a three-layer film casting process

  • Lee, Joo-Sung;Shin, Dong-Myeong;Jung, Hyun-Wook;Hyun, Jae-Chun
    • Korea-Australia Rheology Journal
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    • v.19 no.1
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    • pp.27-33
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    • 2007
  • The co-extrusion of multi-layer films has been studied with the focus on its process stability. As in the single-layer film casting process, the productivity of the industrially important multi-layer film casting and the quality of thus produced films have often been hampered by various instabilities occurring in the process including draw resonance, a supercritical Hopfbifurcation instability, frequently encountered when the draw ratio is raised beyond a certain critical value. In this study, this draw resonance instability along with the neck-in of the film width has been investigated for a three-layer film casting using a varying width non-isothermal 1-D model of the system with Phan-Thien and Tanner (PTT) constitutive equation known for its robustness in portraying extensional deformation processes. The effects of various process conditions, e.g., the aspect ratio, the thickness ratio of the individual film layers, and cooling of the process, on the stability have been examined through the nonlinear stability analysis.

Petroleomic Characterization of Bio-Oil Aging using Fourier-Transform Ion Cyclotron Resonance Mass Spectrometry

  • Smith, Erica A.;Thompson, Christopher;Lee, Young Jin
    • Bulletin of the Korean Chemical Society
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    • v.35 no.3
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    • pp.811-814
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    • 2014
  • Bio-oil instability, or aging, is a significant problem for the long-term storage of fast pyrolysis oils. We investigated bio-oil aging at the molecular level using Fourier-transform ion cyclotron resonance mass spectrometry. Petroleomic analysis suggests that bio-oil aging is resulted from the oligomerization of phenolic lignin products whereas 'sugaric' cellulose/hemicellulose products have negligible effect.

Deformation and Break-up of a Drop in Contraction Flow

  • Davidson Malcolm R.;Cooper-White Justin
    • 한국전산유체공학회:학술대회논문집
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    • 2003.10a
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    • pp.17-18
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    • 2003
  • Drop deformation in a cylindrical contraction geometry, characterized here by the formation of a thread of drop fluid in the contraction, is predicted using a Volume-of-Fluid numerical technique. The predicted drop shape is found to closely follow the observed deformation. A capillary instability in the developing drop thread in the contraction was predicted, in agreement with experimental observation.

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Synthesis of L-Ascorbic Acid Derivative Including 3-Aminopropane Phosphoric Acid as a Novel Whitening Agent

  • Kang, Hak-Hee;Oh, Seong-Geun
    • Bulletin of the Korean Chemical Society
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    • v.24 no.8
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    • pp.1169-1171
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    • 2003
  • A stable derivative of L-ascorbic acid, 2-O-[(3-aminopropyl)phosphinooxy]-L-ascorbic acid (LAAP), was synthesized in moderate yield and its chemical stability and effects on melanin synthesis were investigated. LAscorbic acid was decomposed completely within about 1 hour, while 93% of LAAP remained even after 10 days. Treatment of L-ascorbic acid and LAAP decreased melanin content in normal human melanocytes to 33.8% and 49.1% of control at 2 mM, respectively. Considering chemical instability of L-ascorbic acid, LAAP is a much better whitening agent.

A Research of the Characteristics of $Hg_{1-x}Cd_{x}$Te material by using Electro - Chemical Reduction (Electro-Chemical Reduction에 의한 $Hg_{1-x}Cd_{x}$Te재료의 특성 고찰)

  • 이상돈;김봉흡;강형부
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.05a
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    • pp.38-41
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    • 1994
  • The method of passivation for protecting the $Hg_{1-x}Cd_{x}$Te surface is important device fabrication process. Because the surface components are highly reactive leading to its chemical and electrical instability. Especially. the material of detecting for infrared radiation, of which composition is x=0.2 or 0.3, is narrow bandgap semi- conductor. The narrow bandgap semi conductors are largely governed by the properties of the semiconductor surface. The narrow bandgap semi-conductors are largely governed by the properties of the semiconductor surface. The electro-chemical processing of $Hg_{1-x}Cd_{x}$Te allows rigorous control of the surface chemistry and provides an in-suit monitor of surface reaction. So electro-chemical reduction at specific potential can be selectively eliminated the undesirable species on the surface and mainpulated to reproducibly attain the desired stoichiometry. This method shows to assess the quality of chemically treated good $Hg_{1-x}Cd_{x}$Te surface.

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The Complex Formation of Gallium Bromide with i-Butyl Bromide in Nitrobenzene) (니트로벤젠용액내에서의 브롬화갈륨과 i-브롬화부틸과의 착물형성에 관한 연구)

  • Gwon, O Cheon;NamGung, Jin Hui;Choe, Gi Jun
    • Journal of the Korean Chemical Society
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    • v.38 no.3
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    • pp.208-213
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    • 1994
  • The solubility of i-butyl bromide in nitrobenzene have been measured at 19, 25 and $40^{\circ}C$ in the presence and absence of gallium bromide. In the presence of gallium bromide, 1 : 1 complex, $i-C_4H_9Br{\cdot}GaBr_3$ is formed in the solution. The instability constant K of the complex formation was evaluated from the following equilibrium equation. $i-C_4H_9Br{\cdot}GaBr_3{\rightleftharpoons}C_4H_9Br + 1/2Ga_2Br_6.$ From these result, it seems that the stabilities of the complex formation, gallium bromide with alkyl bromide, are directly related with those of the carbonium ions of alkyl bromide.

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