• Title/Summary/Keyword: Chemical flow control

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Analysis of sewage treatment process for the improvement of T-N removal process (T-N 제거공정 개선을 위한 하수처리장 공정 분석)

  • Shin, Choon Hwan
    • Journal of Environmental Science International
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    • v.27 no.2
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    • pp.99-107
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    • 2018
  • In order to design the improvement process for T-N removal, the treatment process of Suyoung, Gangbyeon, and Noxan sewage treatment plants (STP) in Busan was anlayzed. Suyoung STP shows a T-N removal efficiency of about 69.8% with MLE(Modified Ludzack ettinger) and A2O+MBR. However, it is necessary to improve the process to maintain over DO of 1 mg/L and is required to install a flow control tank to minimize the rainfall effect. Gangbyun STP shows a about 70.2% T-N removal efficiency with A2O+GFF(gravity fiber filtration). However, in order to improve T-N removal efficiency, it is needed to install MLE process to treat recycle water. Noksan STP shows a T-N removal efficiency of about 71.0% with MLE+Chemical treatment and shows stable T-N concentration in effluent. However, it is required a toxic chemical management process because bad wastewater flows into the STP, also is necessary a process improvement in order to increase internal recycling ratio. Especially, it is required a process improvement to increase HRT of nitrification tank because Suyoung and Gangbyeon STPs shows low nitrification efficiency during winter season.

Temperature and diameter effect on hydrodynamic characteristic of surfactant drag-reducing flows

  • Indartono Y.S.;Usui H.;Suzuki H.;Komoda Y.
    • Korea-Australia Rheology Journal
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    • v.17 no.4
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    • pp.157-164
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    • 2005
  • Hydrodynamic characteristic of surfactant drag-reducing flows is still not fully understood. This work investigated the temperature and diameter effect on hydrodynamic characteristic of cationic surfactant drag reducing flows in pipes. Solution of oleyl bishydroxyethyl methyl ammonium chloride (Ethoquad O/12), 900 ppm, as a cationic surfactant and sodium salicylate (NaSal), 540 ppm, as a counter-ion was tested at 12, 25, 40, and $50^{\circ}C$ in pipes with diameter of 13, 25, and 40 mm. Drag reduction effectiveness of this surfactant solution was evaluated in 25 mm pipe from 6 to $75^{\circ}C$. Rheological characteristic of this solution was measured by stress control type rheometer with cone-and-plate geometry. Scale-up laws proposed by previous investigators were used to evaluate the flow characteristic of the solution. It was found that this surfactant solution has clear DR capability until $70^{\circ}C$. Result of this work suggested that temperature has a significant influence in changing the hydrodynamic entrance length of surfactant drag reducing flows. From rheological measurement, it was found that the solution exhibits Shear Induced Structure at all temperatures with different degree of peak viscosity and critical shear rate.

Study on the Reduction Kinetics of In2O3 with Hydrogen (수소에 의한 In2O3의 환원반응속도론 연구)

  • Nahm, Kee-Suk;Kim, Youn-Sop;Lee, Wha-Young
    • Applied Chemistry for Engineering
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    • v.3 no.2
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    • pp.305-311
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    • 1992
  • The experimental study on the reduction of $In_2O_3$ was performed by using thermogravimetric analyzer. The reduction of $In_2O_3$ was occurred at above $300^{\circ}C$. The reduction rates were rapidly increased with the reaction temperature, whilehardly affectedby the flow rate of hydrogen gas. It was found that the unreacted core model could be applied for the analysis of the reduction data and the rate control step was the chemical reaction of $In_2O_3$ with hydrogen on the surface of unreacted $In_2O_3$. The apparent activation energy for this reaction was 20kcal/g-mol $H_2$ and the rate equation of $In_2O_3$ reduction with hydrogen could be expressed in the following equation. ${\frac{dX}{dt}}=1.6{\times}10^5e^{-20000/RT}(1-X)^{2/3}$

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A Simple, Rapid, and Automatic Centrifugal Microfluidic System for Influenza A H1N1 Viral RNA Purification

  • Park, Byung Hyun;Jung, Jae Hwan;Oh, Seung Jun;Seo, Tae Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.277.1-277.1
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    • 2013
  • Molecular diagnostics consists of three processes, which are a sample pretreatment, a nucleic acid amplification, and an amplicon detection. Among three components, sample pretreatment is an important process in that it can increase the limit of detection by purifying nucleic acid in biological sample from contaminants that may interfere with the downstream genetic analysis such as nucleic acid amplification and detection. To achieve point-of-care virus detection system, the sample pretreatment process needs to be simple, rapid, and automatic. However, the commercial RNA extraction kits such as Rneasy (Qiagen) or MagnaPure (Roche) kit are highly labor-intensive and time-consuming due to numerous manual steps, and so it is not adequate for the on-site sample preparation. Herein, we have developed a rotary microfluidic system to extract and purify the RNA without necessity of external mechanical syringe pumps to allow flow control using microfluidic technology. We designed three reservoirs for sample, washing buffer, and elution buffer which were connected with different dimensional microfluidic channels. By controlling RPM, we could dispense a RNA sample solution, a washing buffer, and an elution buffer successively, so that the RNA was captured in the sol-gel solid phase, purified, and eluted in the downstream. Such a novel rotary sample preparation system eliminates some complicated hardwares and human intervention providing the opportunity to construct a fully integrated genetic analysis microsystem.

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Decomposition of Ethylene by Using Dielectric Barrier Discharge Plasma (유전체 배리어 방전 플라즈마를 이용한 에틸렌의 분해)

  • Jang, Doo Il;Lim, Tae Hun;Lee, Sang Baek;Mok, Young Sun;Park, Hoeman
    • Applied Chemistry for Engineering
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    • v.23 no.6
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    • pp.608-613
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    • 2012
  • Dielectric barrier discharge plasma reactor was applied to the removal of ethylene from a simulated storage facility ($1.0m^3$) of fruits and vegetables. The system operated in a closed-loop mode by feeding the contaminated gas to the plasma reactor and recirculating the treated gas back to the storage facility. The experiments were carried out with parameters such as discharge power, circulation flow rate, initial ethylene concentration and treatment time. The rate of ethylene decomposition was mainly controlled by the discharge power and the treatment time. With the other conditions kept constant, the ethylene decomposition rate in the presence of the manganese oxide ozone control catalyst installed downstream from the plasma reactor was lower than that in the absence of it. The suggests that unreacted ozone from the plasma reactor accumulated in the storage facility where it additionally decomposed ethylene. On the basis of an initial ethylene concentration of 50 ppm, the energy requirement for completing the decomposition was about 60 kJ.

CFD Simulation of Combustion and Extinguishment of Solid Propellants by Fast Depressurization (고체 추진제의 연소 및 빠른 감압에 의한 소화 모델 CFD 모사)

  • Lee, Gunhee;Jeon, Rakyoung;Jung, Minyoung;Shim, Hongmin;Oh, Min
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.1
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    • pp.15-23
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    • 2019
  • In this study, an extinguishment model of a three-dimensional solid propellant rocket was developed by combustion and fast depressurization to control the thrust of a solid rocket. Computational fluid dynamics simulation was carried out to ascertain the change in flow patterns in the combustion chamber and the extinguishment process by using a pintle. An ammonium perchloride was used as the target propellant and the dynamic behavior of its major parameters such as temperature, pressure, and burning rate was predicted using the combustion model. The dynamic behavior of the combustion chamber was confirmed by fast depressurization from an initial pressure of 7 MPa to a final pressure of 2.5 MPa at a depressurization rate of approximately -912 MPa/s.

Optimal DO Setpoint Decision and Electric Cost Saving in Aerobic Reactor Using Respirometer and Air Blower Control (호흡률 및 송풍기 제어 기반 포기조 최적 DO 농도 설정과 전력 비용 절감 연구)

  • Lee, Kwang Su;Kim, Minhan;Kim, Jongrack;Yoo, Changkyoo
    • Korean Chemical Engineering Research
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    • v.52 no.5
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    • pp.581-586
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    • 2014
  • Main objects for wastewater treatment operation are to maintain effluent water quality and minimize operation cost. However, the optimal operation is difficult because of the change of influent flow rate and concentrations, the nonlinear dynamics of microbiology growth rate and other environmental factors. Therefore, many wastewater treatment plants are operated for much more redundant oxygen or chemical dosing than the necessary. In this study, the optimal control scheme for dissolved oxygen (DO) is suggested to prevent over-aeration and the reduction of the electric cost in plant operation while maintaining the dissolved oxygen (DO) concentration for the metabolism of microorganisms in oxic reactor. The oxygen uptake rate (OUR) is real-time measured for the identification of influent characterization and the identification of microorganisms' oxygen requirement in oxic reactor. Optimal DO set-point needed for the micro-organism is suggested based on real-time measurement of oxygen uptake of micro-organism and the control of air blower. Therefore, both stable effluent quality and minimization of electric cost are satisfied with a suggested optimal set-point decision system by providing the necessary oxygen supply requirement to the micro-organisms coping with the variations of influent loading.

Low Temperature Deposition a-SiNx:H Using ICP Source (ICP Source를 이용한 저온 증착 a-SiNx:H 특성 평가)

  • Kang, Sung-Chil;Lee, Dong-Hyeok;So, Hyun-Wook;Jang, Jin-Nyoung;Hong, Mun-Pyo;Kwon, Kwang-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.7
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    • pp.532-536
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    • 2011
  • The silicon nitride films were prepared by chemical vapor deposition using inductively coupled plasma. During the deposition, the substrate was heated at $150^{\circ}C$ and power 1,000 W. To evolution low temperature manufacture, we have studied the role of source gases, $SiH_4$, $NH_3$, $N_2$, and $H_2$, to produce Si-N and N-H bond in a-SiNx:H film growth. $SiH_4$, $NH_3$, and $N_2$ flow rate fixed at 100, 10, and 10 sccm, $H_2$ flow rate varied from 0 to 10 sccm by small scale. To get the electrical characteristics, we makes MIM structure, and analysis surface bonding state. Experimental data show that Si-N and N-H bond is increased and hence electrical characteristics is showed 3 MV/cm breakdown-voltage, and leakage-current $10^{-7}\;A/cm^2$.

Evaluation of Water Quality Prediction Models at Intake Station by Data Mining Techniques (데이터마이닝 기법을 적용한 취수원 수질예측모형 평가)

  • Kim, Ju-Hwan;Chae, Soo-Kwon;Kim, Byung-Sik
    • Journal of Environmental Impact Assessment
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    • v.20 no.5
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    • pp.705-716
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    • 2011
  • For the efficient discovery of knowledge and information from the observed systems, data mining techniques can be an useful tool for the prediction of water quality at intake station in rivers. Deterioration of water quality can be caused at intake station in dry season due to insufficient flow. This demands additional outflow from dam since some extent of deterioration can be attenuated by dam reservoir operation to control outflow considering predicted water quality. A seasonal occurrence of high ammonia nitrogen ($NH_3$-N) concentrations has hampered chemical treatment processes of a water plant in Geum river. Monthly flow allocation from upstream dam is important for downstream $NH_3$-N control. In this study, prediction models of water quality based on multiple regression (MR), artificial neural network and data mining methods were developed to understand water quality variation and to support dam operations through providing predicted $NH_3$-N concentrations at intake station. The models were calibrated with eight years of monthly data and verified with another two years of independent data. In those models, the $NH_3$-N concentration for next time step is dependent on dam outflow, river water quality such as alkalinity, temperature, and $NH_3$-N of previous time step. The model performances are compared and evaluated by error analysis and statistical characteristics like correlation and determination coefficients between the observed and the predicted water quality. It is expected that these data mining techniques can present more efficient data-driven tools in modelling stage and it is found that those models can be applied well to predict water quality in stream river systems.

Topical Formulation and Antimicrobial Activity of Ketonic Fraction from Leptospermum scoparium (Leptospermum scoparium의 케톤체 분획물을 함유한 외용제제의 항균력)

  • Kim, Eun-Hee;Hwang, Sung-Joo;Park, Song-Hee;Park, Seung-Youg;Rhee, Gye-Ju
    • Journal of Pharmaceutical Investigation
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    • v.30 no.3
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    • pp.151-158
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    • 2000
  • Gel and cream containing 5% and 10% ketonic fraction (KF) of Leptospermum scoparium, respectively were formulated. Antimicrobial activity, stability, anti-inflammatory effect, rheological properties, drug release and acute toxicity for these topical efficacy were evaluated. Gel and cream containing neomycin or gentamycin in combination with KF has potent antimicrobial activity. Gel and cream were physically stable and did not show any creaming for 6 months storage. Gel showed plastic flow with yield value and cream showed pseudoplastic flow with hysteresis loop. The gel and cream containing KF showed higher viscosity than control or commercial one. The viscosity increased as the concentration of KF increased. Both 10% gel and cream showed a significant decrease in swelling when applied to the carrageenan- injected paw, suggesting local antiinflammatory activity. Particularly, 10% gel preparation showed similar antiinflammatory activity when compared with commercially available drugs. Percent of drug released and diffusion coefficient were in the order of 5% gel, 10% gel, 5% cream, and 10% cream, respectively. There were no significant changes of body weight in rats percutaneously administered with 10% cream and gel when compared with control. There were no induced acute toxicity when 10% cream or gel was applied to rats. Leptospermum scoparium could be practicaly used in topical preparations.

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