• 제목/요약/키워드: Chemical factors

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Anisotropic Phase Transitions of Hard-Spheres Confined in Hard Walls

  • 윤병집
    • Bulletin of the Korean Chemical Society
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    • 제22권12호
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    • pp.1375-1379
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    • 2001
  • Monte Carlo simulations of hard-spheres confined in parallel hard walls have been carried out extensively at various densities and for various wall distances. The compressibility factors in the directions parallel and normal to the wall have been calculated from the radial free space distribution function (RFSDF) with the results showing that the compressibility factors normal to the wall are smaller than those in parallel direction and that a solid phase is formed in the direction normal to the wall while a fluid phase remains in the parallel direction. An order parameter is found to classify the phases whether a system (or a molecule) is in a fluid or a solid state. The compressibility factors of narrow wall are very small compared to those when the wall is put away. A plausible mechanism of the rise of sap in xylem vessel has been proposed.

마산만 표층수에서 물리-화학적 수질요인과 엽록소-$a$ 농도 사이의 관계: 격일 관측 자료 (Relationship between Physico-Chemical Factors and Chlorophyll-$a$ Concentration in Surface Water of Masan Bay: Bi-Daily Monitoring Data)

  • 정승원;임동일;신현호;정도현;노연호
    • 환경생물
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    • 제29권2호
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    • pp.98-106
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    • 2011
  • 마산만의 수질변화와 chlorophyll-$a$의 관계를 밝히고자 이 해역을 대표할 수 있는 4개 정점에서 2010년 2월부터 2010년 11월까지 강우와 기온을 포함한 기후학적 요인, 물리 화학적 요인, 그리고 chlorophyll-$a$의 변화를 집중 조사하였다. 그 결과, 수온, 염분, SS, 규산염은 정점별 차이를 보이지 않았으며, COD 및 DIN은 마산만 내만으로 갈수록 증가하였다. 시계열적으로는 여름철 집중 강우 시 마산만 지류 하천 및 낙동강을 통해 담수가 유입되면서 염분의 급강하 및 SS량과 COD의 증가가 나타났다. 영양염류 중 DIN은 여름철 집중강우 시 일시적으로 증가하는 양상을 제외하고는 낮은 농도를 보였고 DIP와 규산염 또한 DIN과 유사한 양상을 보였다. 마산만에서 식물플랑크톤 성장에 영향을 주는 영양염류는 봄철 중반까지 규소와 인이 성장제한인자로 작용하고, 늦봄부터 가을까지는 질소원이 주 성장제한요인으로 작용할 것으로 판단된다. 다중회귀분석을 실시한 결과, 늦겨울부터 봄철까지 chlorophyll-$a$ 농도는 수온, 염분, COD, DIP의 변화에 의해 영향을 받고 있었다. 여름철에는 봄철과 달리, 염분 및 COD, 강수량이 영향을 주고 있어, 여름철 집중강우에 따른 영향인자들에 의해 chlorophyll-$a$가 빠르게 변화됨을 알 수 있었다. 따라서 마산만 해역의 chlorophyll-$a$의 변화는 영양염류와 같은 화학적 인자의 영향과 함께, 수온 및 강수와 같은 물리적 인자에 의해 크게 영향을 받고 있다.

생산연도 및 지역별 본엽 2등 잎담배의 주요 화학성분 함량 변이 (The Variations of Some Chemical Constituents of Leaf Tobacco(Leaf, Grade 2) Produced in Various Growing Areas from 1999 to 2003 Crop Years)

  • 김상범;정기택;조수헌;복진영;정열영;이종률
    • 한국연초학회지
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    • 제26권1호
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    • pp.17-26
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    • 2004
  • This study was conducted to get the informations for reducing the variation of chemical contents of leaf tobacco. The contents and variations of some chemical constituents of leaf(Leaf, Grade 2) produced in various growing areas from 1999 to 2003 and the effects of meteorological factors on the chemical constituents of leaf were analysed. The contents of analysed constituents of leaf showed high significant differences among crop years in flue-cured and burley, particularly the variation among crop years were higher in chlorine and nicotine contents while lower in total nitrogen content. There were significant differences among growing areas in nicotine and total sugar contents of flue-cured leaf and chlorine content of burley leaf. The total sugar content were negatively correlated to the nicotine and total nitrogen contents in flue-cured leaf. The average air temperature in June and July were positively correlated to the nicotine content of leaf while negatively to total sugar, and the precipitation in May were negatively correlated to the nicotine while positively to total sugar.

Haematological Parameters Induced by Benzo(a)pyrene Exposure as a Toxicity Biomarker in the Fanned Red Sea Bream, Pagrus major

  • Choy, Eun-Jung;Jo, Qtae;Kang, Chang-Keun
    • 한국양식학회지
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    • 제18권3호
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    • pp.196-199
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    • 2005
  • Farmed red sea breams, Pagrus major, were fed for 60 days with pellets containing different concentrations of benzo(a)pyrene (0, 0.2, 2, 20 mg/kg) to generate a biomarker of the chemical toxicity in the fish. The fish exposed to the chemical concentrations did not show any significant difference in the weight gain, conditioning, factor, and hepatosomatic index. However, some haematological parameters, such as glucose, calcium, magnesium, GOT (glutamic oxalate transaminase), and GPT (glutamic pyruvate transaminase) were influenced by the chemical exposure. Of them, two enzymes, GOT and GPT, increased significantly 60 days after the exposure in a way of concentration dependence (P<0.05). In the study of ecotoxicological biomarker, sensitivity to adverse environments is one of the key available factors. The fish changes in GOT and GPT were an earlier and reliable sign of the fish response against the chemical exposure, rendering the two enzymatic factors as a useful biomarker at least to benzo(a)pyrene exposure in the farming waters.

피삭제와 공구재종의 상관관계에 근거한 절삭조건의 최적화 (Optmization of Cutting Condition based on the Relationship between Tool Grade and Workpiece Material(I))

  • 한동원;고성림
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 1997년도 춘계학술대회 논문집
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    • pp.1038-1043
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    • 1997
  • To adapt the neural network proess for the purpose of determination of optimal utting onditions (optimal cutting speed and feed rate), some selection strategies for the machining factors are necessary, which is considered planning cutting process. In this case, factors that have both nonlinearity and strong relationship must be selected. Although tool grade and chemical properties of workpiece material have strong effect to cutting speed, it's not easy to find a analytic relation between them. In this paper, a mathematical method for determining the optimal amount of cutting (depth of cut, feed rate) is presented by tool goemetry and heat generation during cutting process. And various tool grade and workpiece material groups ase classified based on its chemical properties. Thier chemical composition and hardness are used as input pattern for neural network learnig. The result of learning shows the relationship between tool grade and workpiece material and it is proved that it can be used as a sub-system for automatic process planning system.

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Non-chemical Risk Assessment for Lifting and Low Back Pain Based on Bayesian Threshold Models

  • Pandalai, Sudha P.;Wheeler, Matthew W.;Lu, Ming-Lun
    • Safety and Health at Work
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    • 제8권2호
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    • pp.206-211
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    • 2017
  • Background: Self-reported low back pain (LBP) has been evaluated in relation to material handling lifting tasks, but little research has focused on relating quantifiable stressors to LBP at the individual level. The National Institute for Occupational Safety and Health (NIOSH) Composite Lifting Index (CLI) has been used to quantify stressors for lifting tasks. A chemical exposure can be readily used as an exposure metric or stressor for chemical risk assessment (RA). Defining and quantifying lifting nonchemical stressors and related adverse responses is more difficult. Stressor-response models appropriate for CLI and LBP associations do not easily fit in common chemical RA modeling techniques (e.g., Benchmark Dose methods), so different approaches were tried. Methods: This work used prospective data from 138 manufacturing workers to consider the linkage of the occupational stressor of material lifting to LBP. The final model used a Bayesian random threshold approach to estimate the probability of an increase in LBP as a threshold step function. Results: Using maximal and mean CLI values, a significant increase in the probability of LBP for values above 1.5 was found. Conclusion: A risk of LBP associated with CLI values > 1.5 existed in this worker population. The relevance for other populations requires further study.

패턴 웨이퍼의 화학기계적 연마시 패턴 밀도의 영향과 모델링에 관한 연구 (A Study on the Effect of Pattern Density and it`s Modeling for ILD CMP)

  • 홍기식;김형재;정해도
    • 한국정밀공학회지
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    • 제19권1호
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    • pp.196-203
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    • 2002
  • Generally, non-uniformity and removal rate are important factors on measurements of both wafer and die scale. In this study, we verify the effects of the pressure and relative velocity on the results of the chemical mechanical polishing and the effect of pattern density on inter layer dielectric chemical mechanical polishing of patterned wafer. We suggest an appropriate modeling equation, transformed from Preston\`s equations which was used in glass polishing, and simulate the removal rate of patterned wafer in chemical mechanical polishing. Results indicate that the pressure and relative velocity are dominant factors for the chemical mechanical polishing and pattern density effects on removal rate of pattern wafers in die scale. The modeling is well agreed to middle and low density structures of the die. Actually, the die used in Fab. was designed to have an appropriate density, therefore the modeling will be suitable for estimating the results of ILD CMP.

산업현장 적용을 위한 스테인레스 스틸의 전해연마 특성 (Electropolishing Characteristics of Stainless Steel for Industrial Application)

  • 김수한;이승헌;조재훈;김상범;최중소;박철환
    • 한국표면공학회지
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    • 제49권4호
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    • pp.363-367
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    • 2016
  • For the industrial application of electropolishing process, we investigated electropolishing characteristics of stainless steel through increasing the specimen size or electrode gap. In this study, we performed a set of experiment with the specimen size of $10cm{\times}10cm$ and the electrode gap of 1 cm or more. In the view of the electropolishing process, the electrolyte temperature and the polishing time were most important factors compared with the current density and the electrode gap. Especially, the electrolyte temperature most importantly affected surface roughness and current efficiency on electropolishing characteristics. For the industrial application of electropolishing process, it should be considered for important factors such as electrolyte temperature, polishing time, current density and electrode gap, etc.

Identification of Factors Regulating Escherichia coli 2,3-Butanediol Production by Continuous Culture and Metabolic Flux Analysis

  • Lu, Mingshou;Lee, Soo-Jin;Kim, Bo-Rim;Park, Chang-Hun;Oh, Min-Kyu;Park, Kyung-Moon;Lee, Sang-Yup;Lee, Jin-Won
    • Journal of Microbiology and Biotechnology
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    • 제22권5호
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    • pp.659-667
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    • 2012
  • 2,3-Butanediol (2,3-BDO) is an organic compound with a wide range of industrial applications. Although Escherichia coli is often used for the production of organic compounds, the wild-type E. coli does not contain two essential genes in the 2,3-BDO biosynthesis pathway, and cannot ferment 2,3-BDO. Therefore, a 2,3-BDO biosynthesis mutant strain of Escherichia coli was constructed and cultured. To determine the optimum culture factors for 2,3-BDO production, experiments were conducted under different culture environments ranging from strongly acidic to neutral pH. The extracellular metabolite profiles were obtained using high-performance liquid chromatography (HPLC), and the intracellular metabolite profiles were analyzed by ultra-performance liquid chromatography and quadruple time-of-flight mass spectrometry (UPLC/Q-TOF-MS). Metabolic flux analysis (MFA) was used to integrate these profiles. The metabolite profiles showed that 2,3-BDO production favors an acidic environment (pH 5), whereas cell mass favors a neutral environment. Furthermore, when the pH of the culture fell below 5, both the cell growth and 2,3-BDO production were inhibited.