• 제목/요약/키워드: Chemical contents

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논토양의 이화학적 특성 및 침출성 중금속 함량을 이용한 비소의 전함량 예측 (Model Development for Estimating Total Arsenic Contents with Chemical Properties and Extractable Heavy Metal Contents in Paddy Soils)

  • 이정미;고우리;;류지혁;김지영;김두호;김원일
    • 한국토양비료학회지
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    • 제45권6호
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    • pp.920-924
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    • 2012
  • This study was performed to estimate total contents of arsenic (As) by stepwise multiple-regression analysis using chemical properties and extractable contents of metal in paddy soil adjacent to abandoned mines. The soil was collected from paddies near abandoned mines. Soil pH, electrical conductively (EC), organic mater (OM), available phosphorus ($P_2O_5$), and exchangeable cations (Ca, K, Mg, Na) were measured. Total contents of As and extractable contents of metals were analyzed by ICP-OES. From stepwise analysis, it was showed that the contents of extractable As, available phosphorus, extractable Cu, exchangeable K, exchangeable Na, and organic mater significantly influenced the total contents of As in soil (p<0.001). The multiple linear regression models have been established as Log (Total-As) = 0.741 + 0.716 Log (extractable-As) - 0.734 Log (avail-$P_2O_5$) + 0.334 Log (extractable-Cu) + 0.186 Log (exchangeable-K) - 0.593 Log (exchangeable-Na) + 0.558 Log (OM). The estimated value in total contents of As was significantly correlated with the measured value in soil ($R^2$=0.84196, p<0.0001). This predictive model for estimating total As contents in paddy soil will be properly applied to the numerous datasets which were surveyed with extractable heavy metal contents based on Soil Environmental Conservation Act before 2010.

팜유로부터 바이오디젤 연료를 합성하는 초임계유체반응에서 지방산메틸에스테르의 함량에 미치는 첨가물의 영향 (Effect of Additives on the Contents of Fatty Acid Methyl Esters of Biodiesel Fuel in the Transesterification of Palm oil with Supercritical Methanol)

  • 이홍식;최준혁;신영호;임영섭;한종훈;김화용;이윤우
    • Korean Chemical Engineering Research
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    • 제46권4호
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    • pp.747-751
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    • 2008
  • 수분이나 유리지방산 함량이 높은 폐식용유의 적용 가능성을 알아보기 위하여 초임계메탄올을 이용한 바이오디젤 연료의 합성에서 첨가물이 미치는 영향에 대해 실험하였다. 회분식 반응기를 이용하여 물, 유리지방산, 항산화물질의 함량을 달리하여 전이에스테르화반응을 진행하였고, 기체크로마토그래피를 이용해 시료에 포함된 지방산메틸에스테르의 양을 측정하였다. 수분이 증가함에 따라 생성되는 지방산메틸에스테르의 함량이 약간 감소했으나 염기촉매나 산촉매에 비해서는 그 폭이 아주 작았다. 유리지방산, 비타민 E, ${\beta}$-카로틴의 함량 변화에 따른 영향은 거의 없었다.

논 토양의 이화학적 특성 및 침출성 함량을 이용한 납과 카드뮴의 전함량 예측 모형식 개발 (Model Development for Estimating Total Soil Contents of Pb and Cd Using Chemical Properties and Extractable Contents in Paddy Soil)

  • 고우리;이지호;이은용;임성묵;류지혁;김지영;김계훈;임건재;김원일
    • 한국토양비료학회지
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    • 제44권6호
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    • pp.1080-1084
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    • 2011
  • Predictive model for estimating total contents of cadmium (Cd) and lead (Pb) was developed by stepwise multiple-regression analysis using chemical properties and extractable contents of metal in paddy soil adjacent to abandoned mines in 2009 and 2010. Soil properties, e.g. pH, electrical conductivity (EC), organic matter (OM), available phosphorus ($P_2O_5$), and exchangeable cations (i.e. Ca, Na, K, Mg) were measured. Total contents of Cd and Pb as well as extractable contents of metals were analyzed by ICP-OES. Results showed that the total and extractable contents were estimated to be 3.55 and $0.27mg\;kg^{-1}$ in Cd and 83.38 and $24.32mg\;kg^{-1}$ in Pb on the average. From stepwise analysis, it was found that the contents of extractable Cd, Zn, Cu, as well as exchangeable Na were significantly influenced on estimation of the total contents of Cd in soil. Moreover, it also showed that the contents of extractable Pb, Zn, and Cu significantly affected estimation of the total contents of Pb in soil. More significant relationship between estimated and measured value in total contents of Pb was observed than those of Cd ($R^2$=0.87, p<0.0001). This demonstrates that extractable contents of metal are influenced more on estimation of total contents of Cd and Pb in soil than soil properties.

연산별 황색종 가공엽의 화학성분 함량 및 편차 분석 (Analysis of Contents and Deviations of Chemical Constituents of flue-cured leaf Tobacco from 1997 to 2001 Crop Years)

  • 김상범;정기택;조수헌;김용규
    • 한국연초학회지
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    • 제25권1호
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    • pp.20-26
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    • 2003
  • To investigate the effects of reduction of leaf processing factories on the uniformity of processed leaf quality, the contents and their C.V.(Coefficient of Variation) of chemical constituents of flue-cured leaf tobacco produced from 1997 to 2001 and processed at various factories were analysed. The average leaf chemical contents of 12 grades for 5 years ranged as follows ; nicotine 2.00∼0.85%. total sugar 10.7∼16.9%, total nitrogen 2.36∼2.78%, crude ash 14.6∼15.6% and chlorine 0.50∼0.75%. The variations of chemical contents among crop years was higher in total sugar content while lower in crude ash content. The C.V. of chemical content in same grade leaves was higher in chlorine content while lower in total nitrogen and crude ash contents, and the ratio of C.V. among processing factories/C.V. in total population was higher in total sugar content while lower in crude ash content. When the leaves were processed at one factory, the deviations of chemical contents reduced considerably. Particularly, the decreasing effect of deviation was higher in total sugar content.

Perique엽의 경종 및 화학적 특성 (Agronomic Characteristics and Chemical Contents of Perique Tobacco Leaves)

  • 한상빈;반유선
    • 한국연초학회지
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    • 제3권1호
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    • pp.66-74
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    • 1981
  • This study was conducted to investigate the interaction between chemical compositions and agronomic characteristics of perique tobacco leaf. At the topping stage, the thickness of leaf was positively correlated with total sugar($\textrm{0.975}^{**}$), reducing sugar($\textrm{0.975}^{**}$), alkaloid($\textrm{0.518}^{*}$) and petroleum ether extract($\textrm{0.801}^{**}$) contents. The length of upper leaf was negatively correlated with its chemical contents. Total sugar contents of the harvested leaf showed a sigmoid pattern of distribution along the leaf stalk positions.

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Relationship between Plant Species Covers and Soil Chemical Properties in Poorly Controlled Waste Landfill Sites

  • Kim, Kee-Dae;Lee, Eun-Ju
    • Journal of Ecology and Environment
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    • 제30권1호
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    • pp.39-47
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    • 2007
  • The relationships between the cover of herbaceous species and 15 soil chemical properties (organic carbon contents, total N, available P, exchangeable K, Na, Ca and Mg, HCl-extractable Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn) in nine poorly controlled waste landfill sites in Korea were examined by correlation analysis and multiple regression equations. Species showed different patterns of correlation between their cover values and soil chemical properties. The cover of Ambrosia artemisiifolia var. elatior, Aster subulatus var. sandwicensis and Erechtites hieracifolia were negatively correlated with the contents of Fe, Mn and Ni within landfill soils. Total cover of all species in quadrats was positively correlated with the contents of Cd and negatively correlated with the contents of Mn and Fe from stepwise regression analysis with 15 soil properties. Canonical correspondence analysis demonstrated that the distribution of native and exotic plants on poorly controlled landfills was significantly influenced by the contents of Na and Ca in soils, respectively.

Relationship Between Exothermic Heat and Carbon Contents of Pitch-based Carbon Fiber

  • Lee, Jae-Young;Oh, Jong-Hyun;Yang, Xiao Ping;Ryu, Seung-Kon
    • Carbon letters
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    • 제10권3호
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    • pp.202-207
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    • 2009
  • Pitch-based carbon fiber tows were prepared from naphtha cracking bottom oil by reforming and carbonization. The relationship between exothermic heat and carbon contents of the fiber was investigated by changing the carbonization conditions. The carbon contents and the crystallinities of isotropic pitch-based carbon fibers were 86.8~93.8 wt% and 33.7~40.1%, respectively, which were linearly proportional to the increase of carbonization temperature from 700 to $1000^{\circ}C$. The exothermic heat (temperature increase) of fiber tows was measured in a short time, which was also linearly proportional to the increase of carbon contents due to the increase of crystallinity, even though the crystallinity was low. Therefore, the carbon contents or carbonization degree of fibers can rapidly and indirectly be estimated by measuring the surface temperature increase of fibers.

겉보리 종실 성분 변이가 근적외 분광분석치에 미치는 영향 (Effects of Chemical Contents Variation in Covered Barley Seed on Near Infrared Reflectance Spectroscopy)

  • 김병주;박의호;정찬식
    • 한국작물학회지
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    • 제41권3호
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    • pp.354-361
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    • 1996
  • 신속하고 정확한 근적외선 분광분석법으로 품질분석의 효율성을 증대하기 위하여 화학성분의 변이분포가 검량식 작성과정에 미치는 영향과 측정 정확성에 미치는 관계를 구명하여, 근적외선 분광광도계의 이용 효율성 제고를 위한 기초자료를 얻고자 실시한 실험의 결과는 다음과 같다. 1. 보리 전분에 대한추정치 표준오차는 변이폭이 증대될수록 증가하는 경향을 보였으며, 상관계수도 변이폭이 증대될수록 0.872에서 0.883으로 다소 높아지는 경향을 나타내었다. 2. $eta$-glucan과 단백질은 변이폭이 증대될수록 추정치 표준오차는 낮아지고 상관계수는 높아지는 결과를 보여, 근적외선 분광분석법의 이용성 향상을 위하여서는 이들 성분의 함량변이 확대가 필요할 것으로 생각되었다. 3. 회분은 첫번째와 두번째 group에서는 유의성이 인정되지 않았으나, 세번째 group에서는 상관계수가 0.743으로 유의성이 인정되어 회분함량의 경우에는 어느 정도의 변이폭이 있어야만 근적외선 분광분석법이 가능할 것으로 생각되었다. 4. 겉보리 성분 중 전분과 회분은 재검토가 이루어져야 할 것으로 생각되었으며, $\beta$-glucan과 단백질은 근적외선 분광분석법의 적용이 가능하여 분석의 효율성이 증대될 것으로 생각되었다.

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지역별, 년도별 잎담배의 화학적 특성조사 (INVESTIGATION OF CHEMICAL CHARACTERISTICS IN EACH TOBACOO GROWING DISTRICTS AND YEAR)

  • 민영근;이경구;이완남;이상하
    • 한국연초학회지
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    • 제7권1호
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    • pp.57-65
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    • 1985
  • This study was conducted to obtain the information for the difference of chemical characteristics in each tobacco growing districts and year. The results obtained were as follows 1. Difference of chemical characteristics in 6 districts: In case of flue-cured tobacco leaves, the produced leaf tobacco from Cheong Ju and Dae Jeon districts showed middle level in nicotine and total sugar contents, on the other hand, low nicotine and high sugar contents tobacco leaves were produced in An Dong and Jin Ju districts and high nicotine and low sugar contents of tobacco leaves in Su Won and Chun Cheon , respectively. In Burley tobacco leaves, the nicotine and total nitrogen contents of Chun Cheon districts product's were lower than those of Dae Jeon , Jeon Ju and Kwang Ju district's one. 2. Comparison of each tobacco produced year : The nicotine contents of five-cured and Burley tobacco leaves were the highest in 1981 and 1979, respectively. Also, as time goes to recent year, nicotine and total nitrogen contents were decreased and total sugar contents somewhat was increased .

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汚濁河川水의 地球化學的인 硏究(第 III 報) 서울市內 河川水의 브롬舍量 (Geochemical Investigation in Contaminated River Waters(Part III) Bromine Contents of River Water in Seoul)

  • 이용근
    • 대한화학회지
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    • 제14권3호
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    • pp.243-256
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    • 1970
  • Halogen contents of the river water of Seoul city and of municipal reservoirs were investigated from June in 1969 to February in 1970. Bromine contents were ranging from 0.006 to 0.048 mg/1 of the reservoirs, 0.021 to 0.048 mg/1 of Han River, 0.051 to 0.540 mg/1 of rivers running through residential areas and 0.083 to 0.920 mg/1 of rivers running through industrial areas. Bromine contents increased as the river water became contaminated. Most of Br/Cl of Han River and the reservoirs were higher than $3.4{\times}10^{-3}$ of sea water. Bromine contents at 17 different places were the largest in November. The contents of chlorine, iodine and COD (chemical oxygen demand) were nearly correlated with that of bromine. Bromine contents of the river waters in Seoul chiefly originated from consumption of domestic and industrial salt.

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