• Title/Summary/Keyword: Chemical component analysis

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Comparison of hydrochemical informations of groundwater obtained from two different underground storage systems

  • Lee, Jeonghoon;Kim, Jun-Mo;Chang, Ho-Wan
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.110-113
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    • 2002
  • Statistical- based, principal component analysis (PCA) was applied to chemical data from two underground storage systems containing LPG to assess the usefulness of such technique at the initial stage (Pyeongtaek) or middle stage (Ulsan) of hydrochemical studies. For the first case, both natural and anthropogenic contamination characterize regional groundwater. Saline water buffered by Namyang lake affects as a natural factor, whereas cement grouting influence as an artificial factor. For the second study area, contaminations due to operation of LPG caverns, such as disinfection activity and cement grouting effect, deteriorate groundwater quality. This study indicates that principal component analysis would be particularly useful for summarizing large data set for the purpose of subsurface characterization, assessing their vulnerability to contamination and protecting recharge zones.

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Characteristics of Soil Groups Basd on the Development of Root Rot of Ginseng Seedlings (인삼 유묘 뿌리썩음병 진전에 따른 토양군별 특성)

  • 박규진;정후섭
    • Korean Journal Plant Pathology
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    • v.13 no.1
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    • pp.46-56
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    • 1997
  • Based on the principal component analysis (PCA) of Richards' parameter estimates, ginseng field soils were grouped as the principal component 1 (PC1) and the principal component 2 (PC2). The microflora and physico-chemical characteristics of each soil group were compared to elucidate soil environmental factors affecting the disease development of root rot of ginseng seedling. Among 3 soil groups by PC1, there were differences in the populations of total fungi (TF) and Cylindrocarpon plus Fusarium (C+F), and the population ratio of Cylindrocarpon plus Fusarium to total fungi or total bacteria (C+F/TF, C+F/TB) in rhizoplane of ginseng seedlings, the population of total actinomycetes (TA) and the population ratio of total Fusarium to total actinomycetes (Fus/TA) in soil, and soil chemical properties (EC, NO3-N, K, Mn, ect.). Among 4 soil groups by PC2, there were differences in TF, C+F, TB, C+F/TF and C+F/TB in the rhizoplane, Trichoderma plus Gliocladium (T+G) in soil, and P2O5 content in soil. Especially, EC, NO3-N, K, K/Mg and Mn were positively correlated to PC1, and TA was negatively to PC1; however, TF, C+F, TB, C+F/TF and C+F/TB in the rhizoplane were significantly correlated to PC2 positively. On the other hand, microbes in the rhizoplane were not significantly correlated to the stand-missing rate (SMR), although TA and Fe/Mn were negatively correlated, and pH and Ca were positively correlated to SMR.

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Preparation and Characterization of Surface Energy of BPDA-BAPP Polyimide

  • Kim, Kyung-Hoe;Kim, Yong-Gwon;Kwon, Young-Hwan
    • Macromolecular Research
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    • v.17 no.6
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    • pp.388-396
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    • 2009
  • The surface properties (water sorption and repellency, adhesion) are closely related to the surface tension of polymer solids. The critical surface tension (${\gamma}_c$) and surface tension (${\gamma}_s$) of a polymer solid were estimated by the contact angle method by our quantitative imaging system. BPDA (3,3',4,4'-biphenyl tetracarboxylic dianhydride)-BAPP (1,3-Bis(4-aminophenoxy) propane) polyimide was successfully synthesized. The ${\gamma}_c$ values were analyzed by a Zisman plot, a Young-$Dupr\acute{e}$-Good-Girifalco plot, and a log ($1+cos{\theta}$) vs log ${\gamma}_L$ plot. The ${\gamma}_s$ value of BPDA-BAPE polyimide was evaluated using the geometric mean equation and our multiple regression analysis. The calculated values of ${{\gamma}_s^d$ (a dispersion component), ${{\gamma}_s^p$ (a polar component), ${{\gamma}_s^h$ (a hydrogen bonding component), and ${\gamma}_s$ were 30.79, 9.32, 0.20, and 40.31 $mN{\cdot}m^{-1}$, respectively. The ${\gamma}_s$ of BPDA-BAPP polyimide containing both a methylene group and an ether group was larger than that of the polyimide containing only a methylene group.

Transcriptome Analysis of Phosphate Starvation Response in Escherichia coli

  • Baek, Jong-Hwan;Lee, Sang-Yup
    • Journal of Microbiology and Biotechnology
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    • v.17 no.2
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    • pp.244-252
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    • 2007
  • Escherichia coli has a PhoR-PhoB two-component regulatory system to detect and respond to the changes of environmental phosphate concentration. For the E. coli W3110 strain growing under phosphate-limiting condition, the changes of global gene expression levels were investigated by using DNA microarray analysis. The expression levels of some genes that are involved in phosphate metabolism were increased as phosphate became limited, whereas those of the genes involved in ribosomal protein or amino acid metabolism were decreased, owing to the stationary phase response. The upregulated genes could be divided into temporarily and permanently inducible genes by phosphate starvation. At the peak point showing the highest expression levels of the phoB and phoR genes under phosphate-limiting condition, the phoB- and/or phoR-dependent regulatory mechanisms were investigated in detail by comparing the gene expression levels among the wild-type and phoB and/or phoR mutant strains. Overall, the phoB mutation was epistatic over the phoR mutation. It was found that PhoBR and PhoB were responsible for the upregulation of the phosphonate or glycerol phosphate metabolism and high-affinity phosphate transport system, respectively. These results show the complex regulation by the PhoR-PhoB two-component regulatory system in E. coli.

Chemical Properties of Korean Orchard Soils in Main Apple, Pear, Graph and Peach Producing Area (우리나라 사과, 배, 포도 및 복숭아 주산지 토양의 화학적 특성)

  • Lee, Ju-Young;Jung, Jae-Hoon;Kim, Seok-Cheol;Hwang, Seon-Woong;Lee, Choon-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.33 no.2
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    • pp.79-84
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    • 2000
  • The aim of this study was to evaluate the chemical properties of orchard soils through which their soil fertilities were discriminated. Total 877 soil samples in major orchard area, i.e. from 239 apple, 369 pear, 168 grape, 101 peach orchards, were examed on the basis of temporary optimal range for each component. The levels of fertility were ranged from 3.0 to 65.2% compared to optimum fertility, suggesting that almost orchard soils contained inadequately soil components. The contents of chemical component have a tendency to decrease with soil depth gradually from surface to subsoil. This meaned that the contents of various components in subsoil could be estimated on the basis of analysis of surface soil, using the linearly fitted equations of the relationship between component in subsoil and in surface at least to which fertility were samely managed. Furthermore, even when only the content of components in 20cm depth surface soil was analyzed, it could be determined whether the amount of each component in the surface soil is surplus or deficient.

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Characterization of In-Situ Film Thickness and Chamber Condition of Low-K PECVD Process with Impedance Analysis

  • Kim, Dae Kyoung;Jang, Hae-Gyu;Kim, Yong-Tae;Kim, Hoon-Bae;Chae, Hee-Yeop
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.461-461
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    • 2010
  • For a low dielectric constant inter-metal dielectric application, the low-k SiCOH film with a dielectric constant of 2.8-3.2 has been deposited by plasma-enhanced chemical vapor deposition with decamethylcyclopentasiloxane, cyclohexane, and helium which is carrier gas. In this work, we investigated chemical deposition rate, dielectric constant, characterization of plasma polymer films according to temperature(25C-200C) of substrate and change of component concentration. We measured impedance by using V-I prove during process. From experimental result, deposition rate decrease with increasing temperature. Through real time impedance analysis of chamber, we find corelation between film thickness and impedance by assuming equivalent circuit.

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A Study on the General Characteristics and Instrumental Analysis of Natural Omija Extract

  • Sung, Ki-Chun;Kim, Ki-Jun;Kim, Yong-Ryul;Nam, Sang-Sung
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.2
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    • pp.225-232
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    • 2013
  • Omija component was known to possess natural odor, taste, color, and various general characteristics. Omija extraction was extracted using ethanol as a solvent. Omija extract showed a red-purple color of some viscous liquid state. Some conclusions from natural Omija extract were obtained as follow. The result of antimicrobial experiment to add Omija extract, the number of microbial population showed negative reaction from 3 days after it cultivated. This phenomenon could confirm that Omija component affected to antimicrobial effect. The result of dyeing experiment to add Omija extract, fiber dyeing effect showed with some ivory color after dyed to cotton and silk. Also, this phenomenon could confirm that Omija component affected to natural dyeing effect from observated dye state with biological microscope(BM). The result of instrumental analysis, inorganic components of K(109.60ppm), Na(3.500ppm), Ca(1.205ppm), Mg(0.900ppm), Li(0.350ppm), Si(0.380ppm), Cu(0.250ppm), Fe(0.125ppm), Zn(0.090ppm), etcs from Omija were ascertained with ICP/OES, and organic components of benzene(10.808), borny lacetate(11.289), phenol(14.183), ${\beta}$-terpinene(15.840), ${\alpha}$-terpinolene(17.616) etcs from Omija were ascertained with GC/MSD.

Development of Monitoring System for the LNG plant fractionation process based on Multi-mode Principal Component Analysis (다중모드 주성분분석에 기반한 천연가스 액화플랜트의 성분 분리공정 감시 시스템 개발)

  • Pyun, Hahyung;Lee, Chul-Jin;Lee, Won Bo
    • Journal of the Korean Institute of Gas
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    • v.23 no.4
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    • pp.19-27
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    • 2019
  • The consumption of liquefied natural gas (LNG) has increased annually due to the strengthening of international environmental regulations. In order to produce stable and efficient LNG, it is essential to divide the global (overall) operating condition and construct a quick and accurate monitoring system for each operation condition. In this study, multi-mode monitoring system is proposed to the LNG plant fractionation process. First, global normal operation data is divided to local (subdivide) normal operation data using global principal component analysis (PCA) and k-means clustering method. And then, the data to be analyzed were matched with the local normal mode. Finally, it is determined the state of process abnormality through the local PCA. The proposed method is applied to 45 fault case and it proved to be more than 5~10% efficient compared to the global PCA and univariate monitoring.

A Study on Chemical Composition of Dustfall Sampled in Cheju Area: 2. Identification of Source (제주지역 강하먼지의 조성에 관하여 : 2. 오염원 추정)

  • 이기호;허철구
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.2
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    • pp.101-111
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    • 1999
  • In previous study, the local trends in dustfall chemistry and deposition were determined and the characteristics of chemical compositions among dustfall, TSP and rainwater were also compared. Based on the previous results, in this study, the effects of sea salts and soil and soil on the chemical composition of dustfall were studied and then the sources of dustfall in Cheju area were tentatively identified by principal component analysis(PCA)

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