• 제목/요약/키워드: Chemical component analysis

검색결과 704건 처리시간 0.034초

자동차용 스틸휠 디스크부품의 성형불량 및 파손사례분석 (Analysis of Damaged Instance and Forming Fault for Disc Part in Automotive Steel Wheel)

  • 이성희;김무연;김태규;윤호영;강석우
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2006년도 춘계학술대회 논문집
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    • pp.234-238
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    • 2006
  • In this research, an analysis of damaged instance and forming fault for disc part in automotive steel wheel was performed. Rolled steel material, which had been used in the manufacturing of the damaged disc part, was prepared for tensile test, quantitative analysis of chemical component and acquirement of scanning electron microscope images. Although the results of mechanical properties and chemical component ratio for the material satisfied the suggested specification, some material inherent problem was found in the scanning electron microscope images. Finally, in an analysis of chemical component for the damaged disc part used in road condition, mismatching of chemical component ratio between the suggested specification and test result was found.

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중온형 연료전지를 위한 다성분계 세라믹 수소이온 전도체 제조 (Preparation of multi-component ceramic proton conductors for intermediate temperature fuel cell)

  • 임병무;서동호;박상선;이홍연;설용건
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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    • pp.410-411
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    • 2009
  • The multi-component ceramic proton conductor, $BaZr(Y)O_3-SiO_2-TiO_2-ZrO_2$ (BZY-STZ) and $LaPO_4-SiO_2-TiO_2-ZrO_2$ (LP-STZ), were synthesized by micro-emersion and sol-gel technique. The characterization of proton conductors were carried out using X-ray diffraction(XRD), thermogravimetric analysis(TGA), differential thermal analysis(DTA), impedance analysis. The proton conductors indicate the possibility of application for the intermediate temperature up to $700^{\circ}C$.

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Moving Window Principal Component Analysis for Detecting Positional Fluctuation of Spectral Changes

  • Ryu, Soo-Ryeon;Noda, Isao;Jung, Young-Mee
    • Bulletin of the Korean Chemical Society
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    • 제32권7호
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    • pp.2332-2338
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    • 2011
  • In this study, we proposed a new promising idea of utilizing moving window principal component analysis (MWPCA) as a sensitive diagnostic tool to detect the presence of peak position shift. In this approach, the moving window is constructed from a small data segment along the wavenumber axis. For each window bound by a narrow wavenumber region, separate PCA analysis was applied. Simulated spectra with complex spectral feature variations were analyzed to explore the possibility of MWPCA technique. This MWPCA-based detection of the peak shift, potentially coupled with 2D correlation analysis to provide additional verification, may offer an attractive solution.

국내 원자력 발전소 및 화학공장의 기기 신뢰도 데이터베이스 구축 (Development of Component Reliability Database for Korean Nuclear Power Plants and Chemical Plants)

  • 최선영;한상훈
    • 한국신뢰성학회:학술대회논문집
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    • 한국신뢰성학회 2000년도 추계학술대회
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    • pp.269-277
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    • 2000
  • The component reliability database is required in PSA (Probabilistic Safety Analysis) for NPP (Nuclear Power Plant). We have applied a generic database to the PSA for the Korean NPPs, since there is no specific component reliability database. Therefore we are developing the plant-specific component reliability database for domestic NPPs. We also extend the experience and knowledge of PSA and component reliability database for NPP to chemical industry We collect the raw data like component operation history and maintenance history and then input the required data for the component reliability database through failure analysis. With the database, we can not only perform PSA with real data but also perform maintenance optimization.

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Principal Component Analysis Based Two-Dimensional (PCA-2D) Correlation Spectroscopy: PCA Denoising for 2D Correlation Spectroscopy

  • Jung, Young-Mee
    • Bulletin of the Korean Chemical Society
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    • 제24권9호
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    • pp.1345-1350
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    • 2003
  • Principal component analysis based two-dimensional (PCA-2D) correlation analysis is applied to FTIR spectra of polystyrene/methyl ethyl ketone/toluene solution mixture during the solvent evaporation. Substantial amount of artificial noise were added to the experimental data to demonstrate the practical noise-suppressing benefit of PCA-2D technique. 2D correlation analysis of the reconstructed data matrix from PCA loading vectors and scores successfully extracted only the most important features of synchronicity and asynchronicity without interference from noise or insignificant minor components. 2D correlation spectra constructed with only one principal component yield strictly synchronous response with no discernible a asynchronous features, while those involving at least two or more principal components generated meaningful asynchronous 2D correlation spectra. Deliberate manipulation of the rank of the reconstructed data matrix, by choosing the appropriate number and type of PCs, yields potentially more refined 2D correlation spectra.

데이터 기반 이상진단법을 위한 화학공정의 조업모드 판별 (Operation Modes Classification of Chemical Processes for History Data-Based Fault Diagnosis Methods)

  • 이창준;고재욱;이기백
    • Korean Chemical Engineering Research
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    • 제46권2호
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    • pp.383-388
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    • 2008
  • 화학공정의 안전하고 효율적인 운전에 관심이 커지면서 공정이상의 원인을 조기에 진단하기 위한 다양한 이상진단방법이 연구되어 왔다. 최근에는 통계적 모델 등 정량적 데이터에 기반한 이상진단방법이 많이 연구되고 있으나, 특정 조업영역에서 얻어진 통계적 모델을 다른 조업영역에 적용하면 오진단이 많아지게 된다. 따라서 공정특성상 다양한 조업영역이 존재하는 화학공정에 데이터기반 방법론을 적용하기에는 어려움이 있어 화학공정의 조업영역 판별법이 요구되고 있다. 이 연구에서는 유클리드 거리(Euclidean distance), FDA(Fisher's discriminant analysis), PCA(principal component analysis)의 통계모델과 이 모델들에 공정변수의 동특성을 반영한 모델을 제안하였다. 6개의 조업모드를 가진 TE(tennessee eastman) 공정에 대한 사례연구를 통해 동특성을 반영한 PCA 모델의 성능이 가장 우수함을 확인하였다.

Construction of Methanol-Sensing Escherichia coli by the Introduction of a Paracoccus denitrificans MxaY-Based Chimeric Two-Component System

  • Ganesh, Irisappan;Vidhya, Selvamani;Eom, Gyeong Tae;Hong, Soon Ho
    • Journal of Microbiology and Biotechnology
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    • 제27권6호
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    • pp.1106-1111
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    • 2017
  • Escherichia coli was engineered to sense methanol by employing a chimeric two-component system (TCS) strategy. A chimeric MxaY/EnvZ (MxaYZ) TCS was constructed by fusing the Paracoccus denitrificans MxaY with the E. coli EnvZ. Real-time quantitative PCR analysis and GFP-based fluorescence analysis showed maximum transcription of ompC and the fluorescence at 0.01% of methanol, respectively. These results suggested that E. coli was successfully engineered to sense methanol by the introduction of chimeric MxaYZ. By using this strategy, various chimeric TCS-based bacterial biosensors can be constructed and used for the development of biochemical-producing recombinant microorganisms.

한반도 서해안 배경지역 미세입자의 화학적 특성 연구 (Study on the Chemical Characteristics of $PM_{10}$ at Background Area in Korean Peninsula)

  • 방소영;백광욱;정진도;남재철
    • 한국환경보건학회지
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    • 제30권5호
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    • pp.455-468
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    • 2004
  • The purpose of this paper is to understand the time series and origin of a chemical component and to compare the difference during yellow sand episodes for analysis $PM_{10}$ chemical components in the region of west in Korean Peninsula, 1999-2001. An annual mean concentration of $PM_{10}$ is $29.1\;{\mu}g/m^3$. A monthly mean and standard deviation of $PM_{10}$ concentration are very high in spring but there is no remarkably seasonal variation. Also, water soluble ionic component of $PM_{10}$ be influenced by double more total anion than total cation, be included $NO_{3}^-\;and\;SO_{4}^{2-}$ for the source of acidity and $NH_{4}^+$ to neutralize. Tracer metals of $PM_{10}$ slowly increases caused by emitted for soil and ocean (Fe, Al, Ca, Mg, Na) and Zn, Pb, Cu, Mn for anthropogenic source. According to method of enrichment factor (E.F) and statistics, assuming that the origin of metal component in $PM_{10}$ most of element in the Earth's crust e.g. Mg, Ca, Fe originates soil and Cu, Zn, Cd, Pb derives from anthropogenic sources. The ionic component for $Na^{+}\;Cl^-,\;Mg^{2+}\;and\;Ca^{2+}$ and Mg, Al, Ca, Fe originated by soil component largely increase during yellow sand period and then tracer metal component as Pb, Cd, Zn decrease. According to factor analysis, the first group is ionic component ($Na^+,\;Mg^{2+},\;Ca^{2+}$) and metal component (Na, Fe, Mn and Ni) be influenced by soil. The second group, Mg, Cr also be influenced by soil particle.

Non-Invasive Plasma Monitoring Tools and Multivariate Analysis Techniques for Sensitivity Improvement

  • Jang, Haegyu;Lee, Hak-Seung;Lee, Honyoung;Chae, Heeyeop
    • Applied Science and Convergence Technology
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    • 제23권6호
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    • pp.328-339
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    • 2014
  • In this article, plasma monitoring tools and mulivariate analysis techniques were reviewed. Optical emission spectroscopy was reviewed for a chemical composition analysis tool and RF V-I probe for a physical analysis tool for plasma monitoring. Multivariate analysis techniques are discussed to the sensitivity improvement. Principal component analysis (PCA) is one of the widely adopted multivariate analysis techniques and its application to end-point detection of plasma etching process is discussed.