• Title/Summary/Keyword: Chemical characteristics

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The Analysis and Classification of Urban Types for Potential Damage from Hazardous Chemical Accidents Using Factor and Cluster Analysis (요인 및 군집분석을 이용한 유해화학물질 사고 잠재적 피해에 대한 도시 유형 분류 및 특성 분석)

  • Lee, Seung Hoon;Ryu, Young Eun;Kim, Kyu Ri;Back, Jong In;Kim, Ho-Hyun;Ban, Yong Un
    • Journal of Environmental Health Sciences
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    • v.46 no.6
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    • pp.726-734
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    • 2020
  • Objectives: The aim of this study was to analyze and classify the characteristics of potential damage from hazardous chemical accidents in 229 administrative units in South Korea by reflecting the social and environmental characteristics of areas where chemical accidents can occur. Methods: A number of indicators were selected through preceding studies. Factor analysis was performed on selected indicators to derive factors, and cluster analysis was performed based on the factor scores. Results: As a result of the cluster analysis, 229 administrative units were divided into three clusters, and it was confirmed that each cluster had its own characteristics. Conclusions: The first cluster, "areas at risk of accident occurrence and spread of damage" was a type with a high potential for accident damage and a high density of hazardous facilities. The second cluster, "Urban infrastructure damage hazard areas" appeared to be a cluster with high urban development characteristics. Finally, the third cluster 'Urban and environmental damage hazard areas' appeared to be a cluster with an excellent natural environment. This study went further from the qualitative discussion related to existing chemical accidents to identify and respond to accident damage by reflecting the social and environmental characteristics of the region. Distinct from the previous studies related to the causes of accidents and the response system, it is meaningful to conduct empirical research focusing on the affected areas by analyzing the possibility of accident damage in reflection of the social and environmental characteristics of the community.

Agronomic Characteristics and Chemical Contents of Perique Tobacco Leaves (Perique엽의 경종 및 화학적 특성)

  • 한상빈;반유선
    • Journal of the Korean Society of Tobacco Science
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    • v.3 no.1
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    • pp.66-74
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    • 1981
  • This study was conducted to investigate the interaction between chemical compositions and agronomic characteristics of perique tobacco leaf. At the topping stage, the thickness of leaf was positively correlated with total sugar($\textrm{0.975}^{**}$), reducing sugar($\textrm{0.975}^{**}$), alkaloid($\textrm{0.518}^{*}$) and petroleum ether extract($\textrm{0.801}^{**}$) contents. The length of upper leaf was negatively correlated with its chemical contents. Total sugar contents of the harvested leaf showed a sigmoid pattern of distribution along the leaf stalk positions.

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A comparative study on thermal, mechanical and dielectric characteristics of low density polyethylene crosslinked by radiation and chemical methodes (화학적방법과 방사선으로 가교된 저밀도 폴리에티렌의 열적 기계적 및 유전적 특성의 비교연구)

  • 김봉흡;강도열;김정수
    • 전기의세계
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    • v.25 no.2
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    • pp.100-106
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    • 1976
  • A comparative study on thermal, static mechanical and dielectric characteristics were made over a temperature range of ca.20.deg.C to 320.deg.C and a frequency range of KHZ to MHZ band on low density polyethylene specimens crosslinked, respectively, by radiation and chemical method. The thermal property of both specimens shows that softening point appears to unchange by crosslinking, however, melting and liquidizing temperatures attain rapid increase at the imitiation of crosslinking. Mechanical properties show little difference to both specimens crosslinked by different method, further the behaviors were discussed in connection with the relaxation of molecular segments in amorphous phase. Dose dependent dielectric characteristics observed at ambient temperature under several fixed frequencies exhibit extremities at ca. 20 Mrad and the behaviors also were interpreted qualitatively by taking into consideration of dipole concentration change in amorphous phase together with the role of specimen geometry to the depth of oxidative layer. Observing frequency dependent dielectric characteristics, it was also proved that ionic conduction loss is appreciably greater in the specimen prepared by chemical method than that by radiation.

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Correlation Analysis Between Chemical Degradation Characteristics of Grease and Degradation Characteristics of Bearing Through Durability Test (내구시험을 통한 베어링의 열화 특성과 그리스의 화학적 열화 특성 연관성 분석)

  • Kang, Bo-Sik;Lee, Choong-Sung;Ryu, Kyung-Ha
    • Journal of the Korean Society of Industry Convergence
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    • v.25 no.6_3
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    • pp.1239-1246
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    • 2022
  • This paper introduces the effect of grease on the degradation characteristics of bearings used as key components of packaging equipment and automation systems. Bearings parts are installed to fix and support the rotating body of the system, and performance degradation of the bearings has a great effect on the life of the system too. When bearings are used in various devices and systems, the grease is applied to reduce friction and improve fatigue life. Determining the type of lubricant (grease) is important because it has a great influence on the operating environment and lifespan and ensures long lifespan of systems and facilities. However, studies that simultaneously compared and analyzed the change in mechanical degradation characteristics and the comparison of chemical degradation characteristics according to grease types under actual operating conditions are insufficient. In this paper, three types of small harmonic drive, high-load reducer, and low-load reducer grease used in power transmission joint modules are experimentally selected and finally injected into ball bearings with a load (19,500N) to improve bearing durability. Degradation characteristics were tested by attaching to test equipment. At this time, after the durability test under the same load conditions, the mechanical degradation characteristics, that is temperature, vibration according to the three greases types. In addition, the chemical degradation characteristics of the corresponding grease was compared to present the results of mutual correlation analysis.

A Computational Study on the Adsorption Characteristics of Hydrocarbons (Propylene, n-Butane and Toluene) by uing Cation-exchanged ZSM-5 Zeolites

  • Lee, Hyun Chul;Kim, Kyung Min;Choi, Sung Il;Kim, Yong Ha;Woo, Hee Chul;Won, Yong Sun
    • Korean Chemical Engineering Research
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    • v.56 no.6
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    • pp.909-913
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    • 2018
  • A hydrocarbon trap (HT) plays an important role of controlling vehicle emissions in the so-called cold emission period by holding hydrocarbons until three way catalysts (TWCs) are thermally activated. In this study, we have investigated the adsorption characteristics of cation (H, La, K, and Ag)-exchanged ZSM-5 zeolites for hydrocarbons (propylene, n-butane, and toluene) by DFT (density functional theory)-based computational chemistry. Cation exchange is to improve the hydrothermal stability of zeolites and their adsorption capacity, thereby rendering cation-exchanged zeolites promising materials for HT. The idea of cluster approximation makes the calculation of adsorption energies superbly efficient in computation. The results showed that Ag-exchanged ZSM-5 would be the best for the adsorption of all three adsorbates, without often encountered Ag oxidation in experiments. Besides, the hydrothermal stability of La-exchanged ZSM-5 was confirmed from the change of geometrical parameters by cation exchange, and it showed good adsorption capacity for propylene and toluene. Hydrogen-exchanged ZSM-5 was also good for hydrogen adsorption, but had poor hydrothermal stability.

Sensory and Chemical Characteristics of Worts Fermented by Leuconostoc citreum and Saccharomyces cerevisiae and Consumer Acceptability with Added Flavorings

  • Shin, Jin-Yeong;Delgerzaya, Purev;Lim, Yong-Bin;Park, Jin-Byung;Kim, Kwang-Ok
    • Food Science and Biotechnology
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    • v.18 no.5
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    • pp.1109-1117
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    • 2009
  • This study was conducted to examine the chemical and sensory characteristics of fermented worts and consumer acceptability according to added flavorings. The worts were fermented by yeast (Saccharomyces cerevisiae) following fermentation by lactic acid bacteria (Leuconostoc citreum) at different aeration conditions. Chemical and sensory descriptive analyses were conducted to examine the effects of the fermentation conditions. The consumer acceptability of the worts with added flavorings was also examined. Organic acids, functional sugars, and ethanol were produced by L. citreum and S. cerevisiae, respectively. Ethanol concentrations ranged from 10 to 25 g/L depending on the fermentation conditions. The sensory characteristics of the fermented worts were clearly differentiated by the fermentation conditions. Yeast fermentation resulted in high intensities for certain sensory attributes such as 'alcohol', 'fermented barley', 'fermented white grape', and 'grassy'. Consumer acceptability changed with different levels of sugar and lemon flavoring, and the optimum levels were determined as 14.08% sugar and 0.98% lemon flavoring. Under these conditions, it was shown that a relatively acceptable fermented wort beverage containing functional materials can be produced.

Effect of Substitution of Chicken Breast for Alaska Pollack on Physico-chemical Characteristics and Quality in Surimi-like Materials Contained Different Cryoprotectants

  • Jin, Sang-Keun;Choi, Young-Jun;Hur, Sun-Jin
    • Food Science of Animal Resources
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    • v.31 no.2
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    • pp.215-223
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    • 2011
  • Surimi-like samples were divided into four groups (C, surimi-like material made from Alaska Pollack with all cryoprotectant ingredients; T1, surimi-like material made from chicken breast with sugar and a sorbitol-free cryoprotectant; T2, surimi-like material made from chicken breast with a sugar-free cryoprotectant; T3, surimi-like material made from chicken breast with all cryoprotectant ingredients). Water and protein content were lower in Alaska Pollack surimi-like material (C) than those in chicken breast surimi-like material. Centrifuge loss and cooking loss were higher in C than those in chicken breast surimi-like material. Lipid oxidation (thiobarbituric acid reactive substances) was lower in T3 than others during storage. In a sensory evaluation, overall acceptability was significantly higher in C than those in other samples during storage. As a result, we found that the raw material composition (Alaska Pollack or chicken breast) had a large influence on the physico-chemical characteristics and quality of surimi-like materials, whereas cryoprotectant composition may have less influence on the physico-chemical characteristics and quality of surimi-like materials.

Flow Characteristics Analysis for the Chemical Decontamination of the Kori-1 Nuclear Power Plant

  • Cho, Seo-Yeon;Kim, ByongSup;Bang, Youngsuk;Kim, KeonYeop
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.1
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    • pp.51-58
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    • 2021
  • Chemical decontamination of primary systems in a nuclear power plant (NPP) prior to commencing the main decommissioning activities is required to reduce radiation exposure during its process. The entire process is repeated until the desired decontamination factor is obtained. To achieve improved decontamination factors over a shorter time with fewer cycles, the appropriate flow characteristics are required. In addition, to prepare an operating procedure that is adaptable to various conditions and situations, the transient analysis results would be required for operator action and system impact assessment. In this study, the flow characteristics in the steady-state and transient conditions for the chemical decontamination operations of the Kori-1 NPP were analyzed and compared via the MARS-KS code simulation. Loss of residual heat removal (RHR) and steam generator tube rupture (SGTR) simulations were conducted for the postulated abnormal events. Loss of RHR results showed the reactor coolant system (RCS) temperature increase, which can damage the reactor coolant pump (RCP)s by its cavitation. The SGTR results indicated a void formation in the RCS interior by the decrease in pressurizer (PZR) pressure, which can cause surface exposure and tripping of the RCPs unless proper actions are taken before the required pressure limit is achieved.