• Title/Summary/Keyword: Chemical characteristics

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Effect of Stress on Current-Voltage Characteristics of ZnO Based Ceramics

  • Jung Ju-Yong;Kim Yeong-Cheol;Seo Hwa-Il;Chung Dong-Teak;Kim Young-Jung;Min Joon-Won
    • Journal of the Semiconductor & Display Technology
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    • v.4 no.4 s.13
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    • pp.1-4
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    • 2005
  • The chemical composition and uniaxial compressive stress are varied to observe their effect on the current-voltage characteristics of ZnO based ceramics. The variation of chemical composition produces two kinds of ceramics showing ohmic and nonohmic current-voltage characteristics. The current at a fixed voltage increased with the increase of the compressive stress for both ohmic and nonohmic ceramics. Ceramics showing nonohmic behavior exhibit better reversible return of current-voltage curve when the applied compressive stress is removed from the ceramics than those showing ohmic behavior do. We found an appropriate chemical composition showing linear relation between current and stress at a fixed voltage. The ceramic materials with an appropriate chemical composition can be used as a potential sensing material in pressure sensors.

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Preparation of Green-Light Emitting BAM:Mn Phosphor Particles by High Temperature Spray Pyrolysis (고온 분무열분해 공정에 의한 녹색 발광의 BAM:Mn 형광체 합성)

  • Ju Seo Hee;Koo Hye Young;Kim Do Youp;Kang Yun Chan
    • Korean Journal of Materials Research
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    • v.15 no.8
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    • pp.496-502
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    • 2005
  • Green-light emitting $BaMgAl_{10}O_{19}:Mn^{2+}$ (BAM:Mn) phosphor particles were prepared by spray Pyrolysis. The effect of reactor temperature and flow rate of carrier gas in the spray Pyrolysis on the morphology, crystallinity and photoluminescence characteristics under vacuum ultraviolet were investigated. The morphology of the as-Prepared Particles obtained by spray Pyrolysis had spherical shape and non-aggregation characteristics regardless of the reactor temperature. The spherical shape of the as-prepared Particles obtained by spray pyrolysis at low temperature disappeared after Post-treatment. On the other hand the as-Prepared Particles obtained by spray Pyrolysis at $1600^{\circ}C$ maintained spherical shape and non-aggregation characteristics after post-treatment at $1400^{\circ}C$ for 3 h under reducing atmosphere. The BAM:Mn Phosphor Particles Prepared by spray Pyrolysis at different reactor temperatures had pure crystal structure and high photoluminescence intensities under vacuum ultraviolet after post-treatment. BAM:Mn phosphor particles prepared by spray Pyrolysis at low How rate of carrier gas had complete spherical shape and filed morphology and high photoluminescence intensity after post-treatment under reducing atmosphere.

Mechanical and Chemical Characteristics of Bottom Ash Aggregates Cold-bonded with Fly Ash (플라이애시로 표면개질한 바텀애시 경량골재의 물리 화학적특성)

  • Kim, Hyeong-Ki;Ha, Kyung-Ae;Jang, Jeong-Gook;Lee, Haeng-Ki
    • Journal of the Korean Ceramic Society
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    • v.51 no.2
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    • pp.57-63
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    • 2014
  • Bottom ash can be used as pelletizing seeds in unsintered artificial lightweight aggregates, so it can be called as 'cold-bonded aggregates'. In the present study, the mechanical and chemical characteristics of bottom ash aggregates cold-bonded with fly ash were investigated. The crushing strength and the water transfer characteristic of the aggregates, which may affect the strength gain of the concrete, were evaluated. Moreover, the degree of hydration and the hydration products of the aggregates were analyzed to verify the chemical stability of the aggregates. Compared to commercialized artificial lightweight aggregates manufactured by sintering process, cold-bonded fly/bottom ash aggregates had similar levels of water transfer characteristics, while having lower strengths. The calcium hydroxide in the aggregates was almost completely consumed after 28 days moist curing.

Corrosion Damage Characteristics of Inconel 600 with Reduction Conditions in Chemical Decontamination Process (화학제염공정에서 환원공정조건에 따른 Inconel 600의 부식손상 특성)

  • Han, Min-Su;Jung, Kwang-Hu;Yang, Ye-Jin;Park, IL-Cho;Lee, Jung-Hyung;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.50 no.5
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    • pp.332-338
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    • 2017
  • In this study, we evaluated tendency and degree of corrosion damages of Inconel 600 after chemical decontamination treatments under three different conditions. In the decontamination processes, the oxidation and reduction were performed as one cycle. Each process was continued up to 5 cycles. Characteristics of corrosion under decontamination processes were evaluated by Tafel analysis and weight loss. Characteristics of surface damage were observed by scanning electron microscope(SEM) and three-dimensional(3D) microscope. As the cycle proceeded, weight loss and corrosion current density increased. Intergranular corrosion damage occurred on the surface of the materials. The result revealed that the surface of Inconel 600 was attacked by the strong acid solution under all chemical decontamination processes, but the degree of the corrosion damage was different depending on the processes.

Electropolishing Characteristics of Stainless Steel for Industrial Application (산업현장 적용을 위한 스테인레스 스틸의 전해연마 특성)

  • Kim, Soo Han;Lee, Seung Heon;Cho, Jaehoon;Kim, Sang Bum;Choi, Joongso;Park, Chulhwan
    • Journal of the Korean institute of surface engineering
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    • v.49 no.4
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    • pp.363-367
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    • 2016
  • For the industrial application of electropolishing process, we investigated electropolishing characteristics of stainless steel through increasing the specimen size or electrode gap. In this study, we performed a set of experiment with the specimen size of $10cm{\times}10cm$ and the electrode gap of 1 cm or more. In the view of the electropolishing process, the electrolyte temperature and the polishing time were most important factors compared with the current density and the electrode gap. Especially, the electrolyte temperature most importantly affected surface roughness and current efficiency on electropolishing characteristics. For the industrial application of electropolishing process, it should be considered for important factors such as electrolyte temperature, polishing time, current density and electrode gap, etc.

Effect of Citric Acid in Cu Chemical Mechanical Planarization Slurry on Frictional Characteristics and Step Height Reduction of Cu Pattern

  • Lee, Hyunseop
    • Tribology and Lubricants
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    • v.34 no.6
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    • pp.226-234
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    • 2018
  • Copper chemical mechanical planarization (CMP) has become a key process in integrated circuit (IC) technology. The results of copper CMP depend not only on the mechanical abrasion, but also on the slurry chemistry. The slurry used for Cu CMP is known to have greater chemical reactivity than mechanical material removal. The Cu CMP slurry is composed of abrasive particles, an oxidizing agent, a complexing agent, and a corrosion inhibitor. Citric acid can be used as the complexing agent in Cu CMP slurries, and is widely used for post-CMP cleaning. Although many studies have investigated the effect of citric acid on Cu CMP, no studies have yet been conducted on the interfacial friction characteristics and step height reduction in CMP patterns. In this study, the effect of citric acid on the friction characteristics and step height reduction in a copper wafer with varying pattern densities during CMP are investigated. The prepared slurry consists of citric acid ($C_6H_8O_7$), hydrogen peroxide ($H_2O_2$), and colloidal silica. The friction force is found to depend on the concentration of citric acid in the copper CMP slurry. The step heights of the patterns decrease rapidly with decreasing citric acid concentration in the copper CMP slurry. The step height of the copper pattern decreases more slowly in high-density regions than in low-density regions.