• Proceedings of the Korea Concrete Institute Conference
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• 2000.10a
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• pp.155-160
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• 2000

In this paper, we investigated quality properties for the expansive of the CaO-$CaSO_4$ family which used to compensate dry-shrinkage in the floor mortar of On-Dol heating System. This experimental study established the mix condition with quantity of the expansive and is to investigate the relativity between the compress strength and the length change and the relativity between the chemical properties and the length change with the analysis of the physical and chemical properties. As a result of the study, the expansive is controlled by more the CaO than the $CaSO_4$. The relativity between the compress strength and the length change is expressed by exponential function, showing that if the expansive performance is increased, the compress strength is decreased. And the relativity between the chemical properties and the length change is only relative the quantity of the F-CaO among the chemical properties, is expressed by the second order function, showing that if the F-CaO is increased, the expansive performance is increased.

• Korean Journal of Chemical Engineering
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• v.35 no.11
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• pp.2321-2326
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• 2018

We evaluated the optimal conditions for fluidization of nickel oxide (NiO) and its reduction into high-purity Ni during hydrogen reduction in a laboratory-scale fluidized bed reactor. A comparative study was performed through structural shape analysis using scanning electron microscopy (SEM); variance in pressure drop, minimum fluidization velocity, terminal velocity, reduction rate, and mass loss were assessed at temperatures ranging from 400 to $600^{\circ}C$ and at 20, 40, and 60 min in reaction time. We estimated the sample weight with most active fluidization to be 200 g based on the bed diameter of the fluidized bed reactor and height of the stocked material. The optimal conditions for NiO hydrogen reduction were found to be height of sample H to the internal fluidized bed reactor diameter D was H/D=1, reaction temperature of $550^{\circ}C$, reaction time of 60 min, superficial gas velocity of 0.011 m/s, and pressure drop of 77 Pa during fluidization. We determined the best operating conditions for the NiO hydrogen reduction process based on these findings.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.37 no.1 s.109
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• pp.67-72
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• 2005

In the grade change operations inputs and outputs are highly correlated and application of conventional linear feedback control methods such as PID schemes might lead to poor control performance. In this study the neural networks model for the grade change operation is trained by using bilinear terms which can represent non-linear characteristics of grade change operations. The inverse model of the grade change operation is obtained from training and the optimal input variables are computed from the trained neural networks as well. The proposed bilinear inverse model predictive control scheme was found out to showlittle discrepancy between simulated outputs and setpoints.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2006.05a
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• pp.267-270
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• 2006

• Textile Coloration and Finishing
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• v.18 no.5 s.90
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• pp.53-60
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• 2006

The 1,3-bis(4-aminoaryl)squaraines showed color, change behavior, they were found to undergo reduction with sodium borohydride in solution to give colorless leuco compounds, which oxidized readily in air back to the colored squaraine dye. We have shown that initial observations indicated that the derivatives synthesized gave new donor-acceptor chromophores. It is also interesting to note than the oxidation of the leuco squaraines did initially produce a species absorbing about 630-680 wavelengths. The 1,3-squaraines have found many uses as near-infrared absorbers, laser dyes and photoconductive materials. Furthermore their color-change redox behavior has potential in the area of peroxidase-based bioassaysas oxidation sensitive indicator systems were investigated.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.04a
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• pp.407-410
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• 1999

The 5 types of cement mortar was immersed in the various chemical solutions for 400 days and then the compressive strength and the length change were measured to consider the chemical resistance at required ages. Due to the effect of flyashe and GGBF slag, the compressive strength of blended cement mortar was higher than that of portland cement mortar at long ages. According to the result of length change, the mineral admixture in blended cement had an indluence on reducing the amount of C3A, the cause of making concrete expand, and it made the formation of cements mortar denser so that the length change was much smaller than that of the portland cement mortar. However, the OPC mortar immersed in Na2SO4 solution for 180 days shows 4 times bigger length change chante than the blended cement mortar.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2000.04a
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• pp.150-151
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• 2000

Some chromophores that can undergo a pronouncend colour change when acted upon an extenal agency, such as light, heat, pH, or chemical agents, have many potential applicationa as functional dyes. They may be used as indicators, optical sensors, biochemical probes, optical and thermal recording materials. The results will investigate donor-acceptor chromophores which have the potential for such colour change processes. In particular, cross-conjugated donor-acceptor chormophores, analogous to indigo and squarylium-type chromophores, will be examined for pH sensitizing and for their oxidation-reduction colour change behaviour.

• Bulletin of the Korean Chemical Society
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• v.3 no.2
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• pp.60-66
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• 1982

In relation to denaturation of proteins, thermally induced conformational change of poly(D-glutamic acid) was studied in the presence of poly(vinyl alcohol) at low pH, where poly(D-glutamic acid) undergoes a helix-to-${\beta}$ transition without any other polymer. In a dilute solution, poly(vinyl alcohol) enhanced the ${\alpah}-to-{\beta}_1$ transition of poly(D-glutamic acid) due to intermolecular interaction between the two polymers. On the other hand, this conformational change was interrupted to a large extent in a concentrated solution, due to the interpenetration of poly(vinyl alcohol) chain into poly(D-glutamic acid) chain which prevented the intramolecular association of poly(D-glutamic acid) chain. A conformational change from ${\beta}_1\;to\;{\beta}_2$ of poly(D-glutamic acid) was observed for the films obtained by casting during annealing the mixture solutions. The ${\beta}_2$ content in the cast film increased with increasing poly(vinyl alcohol) content in the mixture.

• Bulletin of the Korean Chemical Society
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• v.32 no.9
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• pp.3433-3436
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• 2011

Some of metal nanoparticles have the potential for use as colorimetric assays for estimating solution properties, such as pH and temperature due to localized surface plasmon (LSP) phenomena. This report describes the use of silver nanoparticles (AgNP) conjugated with cytochrome c (Cyt c) for the colorimetric determination of solution pHs. When the pH of a solution decreases, the Cyt c immobilized on the AgNP undergoes a conformational change, leading to a decrease in the interparticle distance between Cyt c-AgNP probes and consequent red-shift in LSP. As a result, the color of the Cyt c-AgNP probe solution changes from yellow to red and finally to a grayish blue in the pH range from 11 to 3. This gradual color change can be used to determine the pH of a solution over a wide pH range, compared to other colorimetric methods that use gold nanoparticles.

• Korean Journal of Chemical Engineering
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• v.36 no.3
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• pp.356-367
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• 2019

This work presents an advanced and systematic approach to analytically design the optimal parameters of a two parameter second-order internal model control (IMC) filter that satisfies operational constraints on the output process, the manipulated variable as well as rate of change of the manipulated variable, for a first-order plus dead time (FOPDT) process. The IMC parameters are designed to minimize a control objective function composed of the weighted sum of the error between the process variable and the set point, and the rate of change of the manipulated variable, and to satisfy the desired constraints. The feasible region of the constrained IMC control parameters was graphically analyzed, as the process parameters and the constraints varied. The resulting constrained IMC control parameters were also used to find the corresponding industrial proportional-integral controller parameters of a Smith predictor structure.