• Proceedings of the IEEK Conference
• /
• 2008.06a
• /
• pp.487-488
• /
• 2008

SiOC films containing alkyl groups have a low dielectric constant because of the interaction between the C-H hydrogen bonds and the oxygen of high electro-negative atom. The Si-$CH_3$ in a void is broken by the $O_2$, therefore the strength of CH bond in Si-O-O-$CH_3$ bond increases. The Si-O-O-$CH_3$ bond is broken by nucleophilic attack due to Si atom, again. The elongation of C-H bond causes the red shift, and the compression of C-H bond causes the blue shift. Among these chemical shifts, the blue shift from $1000\;cm^{-1}$ to $1250\;cm^{-1}$ was related with the formation of pores. If the oxygen is deficient condition, the methylradicals of the electron-rich substitution group terminate easily the Si-O-Si cross-link, and the pore is originated from the cross-link breakdown due to much methyl radicals of Si-$CH_3$. The dielectric constant of the films decreases due to pore generation.

• Nuclear Engineering and Technology
• /
• v.41 no.1
• /
• pp.21-38
• /
• 2009

The use of multi scale modeling concepts and simulation techniques to study the destabilization of an ultrathin layer of oxide interface between a metal substrate and the surrounding environment is considered. Of particular interest are chemo-mechanical behavior of this interface in the context of a molecular-level description of stress corrosion cracking. Motivated by our previous molecular dynamics simulations of unit processes in materials strength and toughness, we examine the challenges of dealing with chemical reactivity on an equal footing with mechanical deformation, (a) understanding electron transfer processes using first-principles methods, (b) modeling cation transport and associated charged defect migration kinetics, and (c) simulation of pit nucleation and intergranular deformation to initiate the breakdown of the oxide interlayer. These problems illustrate a level of multi-scale complexity that would be practically impossible to attack by other means; they also point to a perspective framework that could guide future research in the broad computational science community.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2000.04a
• /
• pp.694-699
• /
• 2000

Recently, the degradation of reinforced concrete structures due to physical and chemical attack has been a major issue in construction engineering. One of the main causes of degradation of concrete structures can be ascribed to chloride-induced corrosion, i.e., the rapid penetration of chloride ions into concrete. To estimate durability of reinforced concrete structures exposed to marine environment, many different kinds of accelerated tests to evaluate the concrete diffusivity were proposed. In this study, present test methods are reviewed and a proper test method for concrete is selected. The diffusion coefficients of concrete with corrosion inhibitor are measured using the proposed method, and then, measured values are compared to those of concrete without corrosion inhibitor. It is found from experimental results that diffusion coefficient re decreased with curing ages.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2012.05a
• /
• pp.295-298
• /
• 2012

Repair and strengthening is necessary to extend the service life of existing buildings. Polymer-modified cement mortar (PCM) has been extensively used as a high performance material particularly for finishing and repairing works in concrete building because of itsexcellent adhesion, waterproofing, resistance to chemical attack, and workability. As PCM contains organic polymer, it is necessary to clarify its properties at high temperature under fire, on which sufficient data are not available. This paper evaluated the burn-up characteristics of polymer-modified cement mortar with cone calorimeter test, non-combustibility test and flammability test with experimental parameters such as the types of polymer, unit-polymer content, polymer-cement ratio and thickness of the specimen.

• 보존과학연구
• /
• s.13
• /
• pp.69-80
• /
• 1992

A great numbers of cultural properties destroyed though attack by insect pests and microorganisms. Biodeterioration damage is particularly serious in this country because many cultural propertiese are made of organic materials. Recently, there are various countermeasures of biodeterioration or alternative methods are reported, such as Gamma Radiation, Micro-wave Irridation, Freezing, Inert Atmosphere (Oxygen-less atmosphere), and Environmental Control. However its practical application are limited and some difficulties for treatment of large objects. Fumigation is one of the most useful and effective methods of control biodeterioration because it gives less damage of cultural properties but rapidly eradicate infesting organisms at one action. This paper evaluated selected fumigants and fumigation methods with emphasis on the following paragraph:1) Effectiveness of selected fumigants on insects and microbes involved inbiodeterioration.2) Physical and chemical characters of selected fumigants.3) Less toxic new alternative fumigant and its mixtures.4) Inert atmosphere (Oxygen-less atmosphere)5) Methods of fumigation : Sealed fumigation, Covered fumigation and Vacuum fumigation (Reduced-pressure fumigation)

• Journal of the Korean Graphic Arts Communication Society
• /
• v.24 no.2
• /
• pp.11-24
• /
• 2006

The Lithographic ink is composed of pigment, vehicle and additives. In especially, the vehicle is the most important element and consist of vegetable oils, mineral oils and resins. Varnishes have to resist certain forms of chemical and physical attack during ink manufacturing process and printing process So this varnish cooking is very important. In this paper, effects of cooking conditions of varnish using phenolic modified rosin ester on physical properties of the vehicle were studied. The varnish cooked according to temperature and time were compared in order of average molecular weight by the GPC method. and the rheological properties were found by rotational rheometer. And the emulsion behavior were compared by high speed emulsification tester which were set on 1200 rpm and $40^{\circ}C$ temperature (Novomatics Lithotronic). We displayed viscosity against tack(Inkometer Thwing-Albert M-106) by diagram.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2016.11a
• /
• pp.115.2-115.2
• /
• 2016

Al alloys are being used widely for automobile, aerospace and mechanical components because of their high strength ratio to weight. However, still they suffer from abrasion or corrosion owing to insufficient resistances to friction or mechanical impact and chemical attack. Plasma electrolytic oxidation (PEO) method is one of the promising surface treatment methods for Al alloys which can render better hardness than aluminum anodic oxide (AAO) films prepared by conventional anodizing method in acidic solutions. In this presentation, some basic nature of PEO film formation and growth process on Al alloys will be presented based on the experimental results obtained and discussed in view of dielectric breakdown and reformation and the role of various anions in film breakdown and reformation of PEO films.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2006.11a
• /
• pp.821-824
• /
• 2006

As this study is to estimate long term resistance of cement mortars using crushed sand under chemical attacks. Besides tests have been carried out with cement mortars by river sand and crushed sand by fine sand, cement mortars mix various proportions of silica fume and fly ash(up to 15% and 50% by weight for cement) were prepared and immersed in pure water, sodium sulfate solution, magnesium sulfate solution, seawater for 28days, 90days, 180days, 365days. Test on the change in the weight and compressive strength of cement mortars according to the duration of immersion time and the content of silica fume and fly ash was performed.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2006.11a
• /
• pp.933-936
• /
• 2006

Many non-destructive inspection methods have recently been developed for concrete structures. However, these methods can obtain only physical information of concrete, such as crack depth, delamination or position of reinforcement etc. near its surface. If chemical information is required, sampling and componential analyses may be earned out. Non-destructive method that can detect deterioration factors such as carbonation, chloride content or sulfate attack would be an outstanding innovation in inspection methodologies. In this research, near-infrared spectroscopy and X-ray fluorescence analysis were applied for componential analysis for concrete. These methods are very effective compared to traditional methods, therefore, working efficiency and maintenance cost will be improved.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2006.11a
• /
• pp.621-624
• /
• 2006

In this study, the repair method using PVA fiber reinforced mortar evaluated on durability performance. Test of salt injury, carbonation, freezing-thawing, chemical attack, permeability was performed As for the test results, it was found that durability performance of the repair method using PVA fiber mortar showed more better than the existing repair method. Therefore, appling on the repair method using PVA fiber reinforced mortar, the repaired concrete structures can be increased to service life.