• Title/Summary/Keyword: Chemical amendments

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Application of X-ray Absorption Spectroscopy (XAS) in the Field of Stabilization of As and Heavy Metal Contaminated Soil (비소 및 중금속 오염토양 안정화 분야에서의 X선 흡수분광법(XAS) 활용)

  • Lim, Jung Eun;Moon, Deok Hyun;Kim, Kwon-Rae;Ok, Yong Sik
    • Journal of Applied Biological Chemistry
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    • v.58 no.1
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    • pp.65-74
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    • 2015
  • X-ray absorption fine structure (XAFS) analysis using X-ray absorption spectroscopy is being applied as a state-of-the-art method in a wide range of disciplines. This review article summarizes the overall procedure of XAFS analysis from the preparation of soil samples to the analysis of data in X-ray absorption near edge structure (XANES) region and extended Xray absorption fine structure (EXAFS) region. The previous studies on application of XANES and EXAFS techniques in environmental soil science field are discussed and classified them according to metal(loid)s (As, Cd, Cu, Ni, Pb, and Zn). A significant number of previous studies of XAFS application in the environmental soil science field have focused on the identification of Pb chemical species in soil. Moreover, XANES and EXAFS techniques have been widely used to investigate the contamination source via identification of metal species. Similarly, these techniques were applied to identify the mechanisms of metal stabilization in soil after application of various amendments, phytoremediation, etc.

Improving Rice Productivity and Soil Quality by Coal Ash-Phosphogypsum Mixture Application (석탄회와 폐석고 혼합제재에 의한 벼 수량 증대 및 토양의 이화학성 개선)

  • Lee, Yong-Bok;Ha, Ho-Sung;Lee, Chang-Hoon;Lee, Hyub;Ha, Byung-Hyun;Kim, Pil-Joo
    • Korean Journal of Soil Science and Fertilizer
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    • v.38 no.1
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    • pp.45-51
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    • 2005
  • As a silicate source to rice, a coal ash (50%) was mixed with a phosphogypsum (hereafter, gypsum, 50%). Field experiments were carried out to evaluate rice (Oryza sativa) productivity in silt loam (SiL) to which 0, 20, 40 and $60Mg\;ha^{-1}$ of the mixture were added. The mixture increased rice yield and showed the highest yields following the addition of $30Mg\;ha^{-1}$. The mixture did not result in an excessive uptake of heavy metals by the rice grain. The mixture improved available silicate and phosphate and exchangeable calcium contents in soil. The available boron content in soil increased with the mixture application levels up to $1.42mg\;kg^{-1}$ following the application of $60Mg\;ha^{-1}$, but boron toxicity in rice was not found. It is concluded that the coal ash and gypsum mixture could be a good alternative to inorganic soil amendments to restore the soil nutrient balance in paddy soil.

The Effects of Inorganic Soil Amendment on Growth of Creeping Bentgrass(Agrostis palustris) in Golf Course (무기 토양개량제가 골프장 그린의 크리핑 벤트그래스 생육에 미치는 영향)

  • Lee, Jae-Pil
    • Asian Journal of Turfgrass Science
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    • v.26 no.2
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    • pp.110-115
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    • 2012
  • Soil amendments have been used to improve the physical and chemical condition of turf soil, which might optimize turfgrass growth in golf courses. This study was to investigate the effect of inorganic soil amendment (ZC) established in USGA root zone system on growth of creeping bentgrass, cv. 'Penncross' carried out from May to Dec. in 2005 at the nursery on Sinwon Golf Course. To analyze the effects of inorganic soil amendment on pH, specific gravity, infiltration rate, water content, soil hardness, root length, tiller density and dry weight were measured. pH was 6.7-6.8, specific gravity of sand (S) 100% was 1.48 heavier than the other treatments (1.28-1.38). Infiltration rate with ZC 15% + peat moss (P) 5% + S 80% and ZC 10% + S 90% was faster than S 100%. Soil hardness of S 100% was the highest. Root length of creeping bentgrass of P 10% + S 90% (8.6-12.0 cm) was the longest. Tiller density with P 5% + S 95% was more 4-7 ea than other treatments in summer season. In growing season, however, ZC 10% + P 5% + S 85% was more 2-3 ea than others. Dry weight of creeping bentgrass treated by ZC 10% + P 5% + S 85% in summer season and P 5% + S 95% in growing season were heavier than other treatments. It is recommended to combine 5-15% inorganic soil amendment and peat moss 5% with sand in order to sustain soil balance.

Impacts of Flooding Depths on Weed Occurrence and Yield in No-tillage Paddy Field Covered with Chinese Milk Vetch (무경운 자운영 피복 논에서 담수 깊이가 잡초발생과 수량에 미치는 영향)

  • Hong, Kwang-Pyo;Lee, Young-Han
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.2
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    • pp.176-180
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    • 2011
  • Rice production depended on the weed control. The purpose of this study was conducted to evaluate the influence of tillage with chemical amendments + 5 cm flooded, no-tillage without Chinese milk vetch + 5 cm flooded (NTNT 5 cm), no-tillage amended with Chinese milk vetch + 5 cm flooded (NTCM 5 cm), and no-tillage amended with Chinese milk vetch + 10 cm flooded (NTCM 10 cm) on weed occurrence and yield of rice in paddy. Triplicate experimental plots were laid out in a randomized complete block design and compared by employing least significant difference. The dry weights of weeds in NTCM 5 cm and NTCM 10 cm were 11% and 4% level of NTNT 5 cm (p<0.05) and were 3.2 times and 1.2 times more than in conventional tillage system. In addition, the Aneilema keisak and Ludwigia prostrata were significantly increased in NTNT 5 cm (p<0.05). The yield of rice grain in NTCM 10 cm was 2.6 times more than in NTNT 5 cm and was 89% level of conventional tillage system. Our findings suggest that NTCM 10 cm should be enhance of weed control as well as improving of yield of rice in paddy.

Composting of Paper Mill Sludge by the Addition of Urea (제지슬러지 퇴비화를 위한 요소 첨가효과)

  • Lee, In-Bog;Chang, Ki-Woon
    • Korean Journal of Soil Science and Fertilizer
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    • v.33 no.6
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    • pp.453-462
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    • 2000
  • This study was carried out to know the effect of urea addition for composting of paper mill sludge(PMS). For the purpose. PMSs containing 0%, 1.5%, 3%, and 6% urea were composted at aerated static pile(ASP) for about 80day periods. During the composting, the basic physical, chemical, and biological parameters such as temperature, color. C/N ratio, cation exchange capacity, and phytotoxic test were investigated. From the measurement of the parameters, 0~3% urea-containing PMS except for 6% urea-containing PMS showed to be normally stabilized. Thus among these treatments, 0% and 3% urea-containing PMS were applied at agitated bed system(ABS), a pilot plant of a large scale, to evaluate the possibility of practical use. Considering to the changes of the parameters investigated during composting in ASP and ABS, PMS showed to be successfully stabilized in the two facilities. However, when composted with PMS and urea, even the final PMS compost stabilized for a period enough brought out the bright grayish color. So it may be necessary to add a subsidiary amendments such as animal manure to form brown-colored products.

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Assessment of Heavy Metal(loid)s Pollution in Arable Soils near Industrial Complex in Gyeongsang Provinces of South Korea

  • Kim, Yong Gyun;Lee, Hyun Ho;Park, Hye Jin;Hong, Chang Oh
    • Korean Journal of Soil Science and Fertilizer
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    • v.51 no.2
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    • pp.128-141
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    • 2018
  • Industrial complex releasing huge amounts of dusts, fumes and wastewater containing heavy metal(loid)s could be a source of heavy metal(loid)s pollution in arable soil. Heavy metal(loid)s pollution in arable soil adversely affect crops safety, subsequently human being. Hence, it is important to accurately assess the heavy metal(loid)s pollution in soil using pollution indices. The objectives of this study are 1) to compare assessment methods of heavy metal(loid)s pollution in arable soils located near industrial complex in Gyeongsang provinces and 2) to determine the relationship between concentration of plant available heavy metal(loid)s and chemical properties of soil. Soil samples were collected from 85 sites of arable lands nearby 10 industrial complex in Gyeongsang provinces. The average total concentration of all heavy metal(loid)s of the studied soils was higher than that of Korean arable soils but did not exceed the warning criteria established by the Soil Environmental Conservation Act of Korea. Only six sites of arable soils for the total concentration of As, Cu and Ni exceeded the warning criteria (As: $25mg\;kg^{-1}$, Cu: $150mg\;kg^{-1}$, Ni: $100mg\;kg^{-1}$). The contamination factor (CF) and geoaccumulation index ($I_{geo}$) of the heavy metal(loid)s in arable soils varied among the sampling sites, and the average values of As and Cd were relatively higher than that of other metals. Results of integrated indices of As and Cd in arable soils located near industrial complex indicated that some arable soils were moderately or heavily polluted. The plant available concentration of heavy metal(loid)s was negatively related to the soil pH and negative charge of soil. Available Cd, Pb, and Zn concentrations had relatively high correlation coefficient with pH and negative charge of soil when compared with other heavy metal(loid)s. Based on the above results, it might be a good soil management to control pH with soil amendments such as lime and compost to reduce phytoavailability of heavy metal(loid)s in arable soil located near industrial complex.

Rice Yield and Changes of Available Silicate in Paddy Soils from Long-term Application of Chemical Fertilizers and Soil Amendments (비료와 토양개량제가 장기 연용된 논토양에서의 유효규산 변동과 벼 수량)

  • Kim, Myung-Sook;Kim, Yoo-Hak;Hyun, Byung-Keun;Yang, Jae-E.;Zhang, Yong-Seon;Yun, Hong-Bae;Sonn, Yeon-Kyu;Lee, Ye-Jin;Ha, Sang-Keun
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.1118-1123
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    • 2011
  • The changes of available silicate (Avail. $SiO_2$) contents in paddy soils (sandy loam) were assessed from data of the 41 years fertilization plots in which the continuous rice cropping experiment started in 1954 at the National Academy of Agricultural Science. The treatments were no fertilization (O), inorganic fertilization (NPK), inorganic fertilizer plus rice straw compost (NPK+C), inorganic fertilizer plus silicate fertilizer as a soil amendment (NPK+S), inorganic fertilizer plus rice straw compost and silicate fertilizer (NPK+CS) and inorganic fertilizer plus rice straw compost, silicate fertilizer and lime (NPK+CSL). Available silicate contents in NPK+S, NPK+CS and NPK in surface soil reached at the highest content ($255{\sim}330mg\;kg^{-1}$) after 41 years and then levelled off. Available silicate contents in subsurface soil (25~30 cm) were higher in NPK+C and NPK+S treatments than those in other treatments. Continuous application of silicate fertilizer affected significantly on the levels of available silicate in surface and subsurface soils. Silicate uptake of top rice was more increased by 98% in NPK+CS and NPK+CSL over NPK. Grain yield also increased by 37~47% in NPK+CS and NPK+CSL as compared to NPK. The combined applications of inorganic fertilizers with silicate as a soil amendment are recommended as the best fertilization practice for fertilizer use efficiency, enhancement of soil fertility status in the continuous rice cropping system in Korea.

Transfer of Arsenic from Paddy Soils to Rice Plant under Different Cover Soil Thickness in Soil Amendments in Abandoned Coal Mine (폐탄광지역 비소오염 농경지(논) 개량 시 복토두께에 따른 비소의 벼 전이 및 토양용액 특성)

  • Koh, Il-Ha;Kwon, Yo Seb;Jeong, Mun-Ho;Ko, Ju In;Bak, Gwan-In;Ji, Won Hyun
    • Economic and Environmental Geology
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    • v.54 no.4
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    • pp.483-494
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    • 2021
  • This study was carried out to investigate the feasibility of reducing clean cover soil using a flooded column test in arsenic-contaminated farmland reclamation of abandoned coal mine area that shows generally low or about worrisome level (25 mg/kg) of Korea soil environment conservation act unlike abandoned metal mine. During the monitoring period of soil solution for 4 months, chemical properties (pH, EC, ORP, Fe, Mn, Ca, and As) in each layer (clean soil cover and contaminated/stabilized soil) showed different variation. This result revealed that soil solution in stabilized or contaminated soil rarely affected that in cover soil. Whether stabilized or not, arsenic concentrations in the rice roots grown in the soil covers with the thickness of 40 cm decreased by 98% in compared with the that grown in the control soil. In case of the soil covers with 20 cm thickness on stabilized soil, it decreased by 80% and this was 22 percentage point higher than when the soil of lower layer was not stabilized. Thus, reducing clean cover soil could be possible in contaminated farmland soil reclamation if appropriate stabilization of contaminated soil is carried.

Utilization of Wood by-product and Development of Horticultural Growing Media (임산부산물을 이용한 원예용 혼합상토 개발)

  • Jung, Ji Young;Lim, Ki-Byung;Kim, Ji Su;Park, Han Min;Yang, Jae-Kyung
    • Horticultural Science & Technology
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    • v.33 no.3
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    • pp.435-442
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    • 2015
  • The main objective of this work was to identify and evaluate possible substrate alternatives or amendments to peat moss. This study involves the physical and chemical characterization and growth test of wood sawdust and wood fiber in order to evaluate their use as components of horticultural media. The carbohydrate content, C/N ratio, pH, phenolic compound, total porosity and water holding capacity were 58.9%, 425.1, 4.8, 181.8 ($mg{\cdot}g^{-1}$), 82.5% and 47.1% in wood sawdust and 41.1%, 240.8, 5.9, 29.8 ($mg{\cdot}g^{-1}$), 90.6% and 56.2% in wood fiber, respectively. Wood sawdust (K, $998.0mg{\cdot}100g^{-1}$ ; Ca, $1196.0mg{\cdot}100g^{-1}$; Mg, $105.6mg{\cdot}100g^{-1}$) and wood fiber (K, $1250.1mg{\cdot}100g^{-1}$; Ca, $1982.6mg{\cdot}100g^{-1}$; Mg, $173.1mg{\cdot}100g^{-1}$) showed adequate mineral elements properties compared to peat moss (K, $0.02mg{\cdot}100g^{-1}$; Ca, $0.57mg{\cdot}100g^{-1}$; Mg, $0.13mg{\cdot}100g^{-1}$) for their use as growing media. The mixtures of the horticultural media were prepared using different substrate as wood sawdust and wood fiber to grow Chinese cabbage (Brassica campestris L.) in a greenhouse. The seed germination, leaf area and stem height were 75%, $0.50cm^2$ and 2.8 cm in PS substrate (containing 30% peat moss, 10% perlite and 60% wood sawdust) and 95%, $0.65cm^2$ and 3.3 cm in PF substrate (containing 30% peat moss, 10% perlite and 60% wood fiber), respectively. The seed germination and stem height of the PF substrate (containing 30% peat moss, 10% perlite and 60% wood fiber) was higher than those in peat moss (control). Utilization of wood by-product can be considered as an alternative media component to substitute the widely using expensive peat moss.

Effect of Soil Amendment Application on Yields and Effective Components of Chrysanthemum boreale M. (산국의 수량과 유효성분에 대한 토양개량제의 효과)

  • Lee, Kyung-Dong;Lee, Yong-Bok;Yang, Min-Suk;Kim, Pil-Joo
    • Korean Journal of Soil Science and Fertilizer
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    • v.35 no.1
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    • pp.27-37
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    • 2002
  • With increasing the concerns of health improving foods. the demands of C. boreale M., which is a perennial flower and has been historically used for a natural medicine, become higher, recently, However, wild C. boreale M. collected in a mountatinous area is limited and not enough to cover all demands. The cultivation system and fertilization strategy are required to produce much amount of C. boreale M. with a good quality. We investigated the effects of soil amendment application on plant growth and effective components of C. boreale M. to develop efficient cultivation system. C. boreale M. was cultivated in a pot scale, and lime, fly ash, poultry manure compost and swine manure compost as an amendment applied with rate of 2, 20, 150 and $150Mg\;ha^{-1}$, respectively. Here, chemical fertilizers were applied with the same level ($N-P_2O_5-K_2O=150-80-80kg\;ha^{-1}$) in all treatments. Flower yields of C. boreale M., edible part as a natural medicine, were increased to 37 and 27% by swine and poultry manure compost application, respectively. Poultry manure compost amending (NPK+PMC) increased 3.6 times of proline content and 58% of total amino acids in the flower part more than chemical fertilization (NPK). But the contents of amino acids did not increase with amending liming materials like lime and fly ash. Cumambrin A, which is a sesquiterpene compound and has the effect of blood-pressure reduction, increased to 34 and 19% by lime and fly ash applications, respectively. Cumambrin A was significantly correlated with calcium content in the flower part of C. boreale M. Conclusively, soil amendments like compost and liming materials might contribute to increase the yields and quality of C. boreale M.